泡沫塑料吸附分离富集-电感耦合等离子体质谱法测定稀土矿石中的镓   总被引：1，自引：1，他引：0  

董学林  何海洋 《岩矿测试》2016,35(1):42-47

采用电感耦合等离子体质谱法(ICP-MS)测定稀土矿石中的镓,高含量的稀土元素会造成严重的质谱干扰。本文采用聚氨酯泡沫塑料在6 mol/L盐酸介质中吸附样品溶液中的镓后,以0.5 mol/L氯化铵水浴加热解脱30 min,镓的吸附-解脱效率超过99%,稀土元素等干扰物质基本不进入解脱液中,即在富集镓的同时实现了镓与基体元素的高效分离,降低了质谱干扰。本方法检出限低(0.022μg/g),经土壤及水系沉积物标准物质验证,镓的测定值与标准值吻合(绝对偏差为0.38%~4.70%),实际稀土矿石样品的加标回收率为94.1%~100.6%,精密度(RSD)低于4%(n=12),可应用于分析一般地质样品以及稀土矿石中的镓。  相似文献   

X射线荧光光谱法分析不同类型岩石中10种主量元素的测试能力验证   总被引：4，自引：3，他引：1  

王建其  柳小明 《岩矿测试》2016,35(2):145-151

以28个不同类型岩石标样作外标,用玻璃熔片法制样,采用经验系数法进行基体校正,建立了X射线荧光光谱法(XRF)测定不同类型岩石中硅铝钙镁等10种主量元素的分析方法。该方法被用于参与GeoPT分析测试能力验证,15年来分析了23个不同类型的岩石验证样品。经验证该方法对SiO_2、Al_2O_3、K_2O和CaO具有非常好的分析效果(所有测定结果的|Z|2);对于MgO、MnO、TiO_2和Na_2O四个元素,尽管各有一个样品的分析结果的|Z|2,这主要是样品与标样的基体差异较大造成了低含量样品测定结果超差,但依然可获得好的分析效果;当TFe_2O_31.0%,P_2O_5含量在0.08%~0.80%区间时,分析结果的|Z|2,满足分析期望。总体上所建立的XRF分析方法稳定,可满足应用地球化学实验室测试不同类型岩石中10种主量元素的分析期望。  相似文献   

A Loop Current experiment: Field and remote measurements     

《Dynamics of Atmospheres and Oceans》2016

An overview of a new comprehensive observational study of the Loop Current (LC) in the eastern Gulf of Mexico that encompassed full-depth and near-bottom moorings, pressure-equipped inverted echo sounders (PIES) and remote sensing is presented. The study array was designed to encompass the LC from the Campeche Bank to the west Florida escarpment. This overview centers about principal findings as they pertain to mesoscale dynamics. Two companion papers provide in-depth analyses. Three LC anticyclonic eddy separation events were observed with good 3D spatial coverage over the 2½ year extent of the field study; the three separations exhibited similar processes after the LC had extended into the eastern Gulf. Large scale (∼300 km wavelength, 40–60 day periods) southward propagating meanders developed on the eastern side of the LC over deep (∼3000 m) water that were the result of baroclinic instability between the upper layer meandering jet and lower layer cyclones and anticyclones. The lower layer was only highly energetic during relatively short (∼2–3 months) intervals just prior to or during eddy detachments because of baroclinic instability. The steepening of the meanders lead to a pinch-off of LC eddies. The deep lower-layer eddies, constrained by the closed topography of the southeastern Gulf, propagated westward across the detachment zone and appear to assist in achieving separation. Small scale (∼50–100 km, periods ∼10 days) frontal eddies, observed on the western side of the LC along the Campeche Bank slope, decay over the deep water of the northern part of an extended LC, and have little influence on lower layer eddies, the east side meanders and the eddy detachment processes.  相似文献   

冰盖下矩形河道的综合糙率          下载免费PDF全文

陈刚  张玉蓉  周密  顾世祥 《水科学进展》2016,27(2):290-298

综合糙率是采用曼宁公式确定河道水位和流量关系的关键参数。在河道冰封期,冰盖的出现增加了流动的阻力,明流条件下确定的综合糙率不再适用,需要重新估算。基于Einstein阻力划分过流断面的原理,冰盖下矩形河道的过水断面可划分为冰盖区、河床区和边壁区。根据总流的连续性方程,在确定各分区糙率系数、水力半径和断面面积的基础上,提出了冰盖下矩形河道综合糙率的计算公式。采用已有的试验水槽测量数据和天然河道实测资料对公式进行了验证,结果表明:公式计算的综合糙率与实测值吻合较好,与Einstein公式和Sabaneev公式相比,计算精度更高;对于冰封水流,宽浅河道采用分区水深代替水力半径进行简化计算的条件有别于明渠水流,在宽深比大于20时,计算结果才满足精度要求。  相似文献   

Interaction of cnoidal waves with an array of vertical concentric porous cylinders     

《Applied Ocean Research》2016

An array of large concentric porous cylinder arrays is mounted in shallow water exposed to cnoidal waves. The interactions between waves and cylinders are studied theoretically using an eigenfunction expansion approach. Semi-analytical solutions of hydrodynamic loads and wave run-up on each cylinder are obtained using first approximation to cnoidal waves. The square array configuration of four-legged identical concentric porous cylinder is investigated in present study. Numerical results reveal the variation of dimensionless wave force and wave run-up on individual cylinder with angle of incidence, porosity parameter, spacing between outer and inner cylinders, spacing between concentric porous cylinders and wave parameter. Different mechanism of wave force is found under different range of scattering parameter.  相似文献   

南极低温降解菌Shewanella sp. NJ49羟化酶分离纯化及最适产酶条件研究     

刘芳明  王以斌  曲长凤  梁强  郑洲  缪锦来  肖天 《海洋科学》2016,40(5):1-8

羟化酶是细菌降解烷烃的关键酶,本文以南极低温降解菌Shewanella sp.NJ49为研究对象,通过硫酸铵沉淀、超滤浓缩及葡聚糖凝胶Sephadex G-75柱层析方法,分离纯化NJ49的羟化酶,获得了单一羟化酶组分,研究了温度、p H、表面活性剂和盐度等环境因素对NJ49羟化酶酶活活性影响。结果表明,羟化酶组分由α、β、γ三个亚基组成,分子质量分别为56,45和36 k D。NJ49最适产酶条件为:温度15℃、p H7.2、盐度55;不同类型表面活性剂对酶的活性影响效应不一,两性离子表面活性剂、阳离子表面活性剂、非离子表面活性剂对酶活没有作用,阴离子表面活性剂+非离子表面活性剂混和剂和阳离子表面活性剂+非离子表面活性剂混和剂能提高羟化酶的活性。  相似文献   

酉阳河流域典型年汛期的基流分割研究   总被引：2，自引：0，他引：2  

雷宇宽 《水文》2021,41(1):35-41

基流分割是水文学研究中的重难点问题之一,目前基流分割也存在许多方法。基于酉阳河典型年汛期实测日平均流量资料,分别采用Chapman-Maxwell改进方程数字滤波法一次滤波(参数N=1)以及二次滤波(参数N=2)、BFI(f)法、HYSEP固定步长法、HYSEP滑动步长法、HYSEP局部最小值法进行基流分割并对其结果进行分析对比。研究结果表明:不同方法下得到的基流分割线各不相同,各年份基流指数的统计特征也存在一定差异,采用Chapman-Maxwell改进方程数字滤波法二次滤波得到的基流成果更符合基流的一般特征以及酉阳河流域的降水径流关系特点。  相似文献   

Impact of precipitation characteristics on soil hydrology in tile‐drained landscapes     

P. Vidon  P. E. Cuadra 《水文研究》2010,24(13):1821-1833

Understanding the variables regulating tile‐flow response to precipitation in the US Midwest is critical for water quality management. This study (1) investigates the relationship between precipitation characteristics, antecedent water table depth and tile‐flow response at a high temporal resolution during storms; and (2) determines the relative importance of macropore flow versus matrix flow in tile flow in a tile‐drained soya bean field in Indiana. In spring, although variations in antecedent water table depth imparted some variation in tile‐flow response to precipitation, bulk precipitation was the best predictor of mean tile flow, maximum tile flow, time to peak, and run‐off ratio. The contribution of macropore flow to total flow significantly increased with precipitation amount, and macropore flow represented between 11 and 50% of total drain flow, with peak contributions between 15 and 74% of flow. For large storms (>6 cm bulk precipitation), cations data indicated a dilution of groundwater with new water as discharge peaked. Although no clear dilution or concentration patterns for Mg²⁺ or K⁺ were observed for smaller tile flow generating events (<3 cm bulk precipitation), macropore flow still contributed between 11 and 17% of the total flow for these moderate size storms. Inter‐drain comparison stressed the need to use triplicate or duplicate tile drain experiments when investigating tile drainage impact on water and N losses at the plot scale. These results significantly increase our understanding of the hydrological functioning of tile‐drained fields in spring, when most N losses to streams occur in the US Midwest. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Groundwater–surface water interactions in a lowland watershed: source contribution to stream flow     

Vijay M. Vulava  Timothy J. Callahan  Martin L. Jones 《水文研究》2012,26(21):3195-3206

The lower coastal plain of the Southeast USA is undergoing rapid urbanisation as a result of population growth. Land use change has been shown to affect watershed hydrology by altering stream flow and, ultimately, impairing water quality and ecologic health. However, because few long‐term studies have focused on groundwater–surface water interactions in lowland watersheds, it is difficult to establish what the effect of development might be in the coastal plain region. The objective of this study was to use an innovative improvement to end‐member mixing analysis (EMMA) to identify time sequences of hydrologic processes affecting storm flow. Hydrologic and major ion chemical data from groundwater, soil water, precipitation and stream sites were collected over a 2‐year period at a watershed located in USDA Forest Service's Santee Experimental Forest near Charleston, South Carolina, USA. Stream flow was ephemeral and highly dependent on evapotranspiration rates and rainfall amount and intensity. Hydrograph separation for a series of storm events using EMMA allowed us to identify precipitation, riparian groundwater and streambed groundwater as main sources to stream flow, although source contribution varied as a function of antecedent soil moisture condition. Precipitation, as runoff, dominated stream flow during all storm events while riparian and streambed groundwater contributions varied and were mainly dependent on antecedent soil moisture condition. Sensitivity analyses examined the influence of 10% and 50% increases in analyte concentration on EMMA calculations and found that contribution estimates were very sensitive to changes in chemistry. This study has implications on the type of methodology used in traditional forms of EMMA research, particularly in the recognition and use of median end‐member water chemistry in hydrograph separation techniques. Potential effects of urban development on important hydrologic processes (groundwater recharge, interflow, runoff, etc.) that influence stream flow in these lowland watersheds were qualitatively examined. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Versuch der Geschlechtsbestimmung beim Wels,Silurus glanis L., mit Hilfe der Diskriminanzanalyse von Brustflossendaten     

Wiesław Wiśniewolski  Janusz Górczyński  Wiesław Madry 《Aquatic Sciences - Research Across Boundaries》1989,51(3):249-259

Width of the first ray of the pectoral fin has been measured in two places for 154 young and 89 adult wels. Statistical relationships between the above characters and fish length as well as its maturity and sex have been proved. Three models of discriminant function for identification of adult fish sex have been derived and verified. The accuracy of sex separation has been 89,5% in a standard sample of wels, and 90,6% in a routine sample, after an adjustment in the procedure.  相似文献