Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

国产高分辨率遥感影像农村公路核查方法及其应用     

蔡红玥  袁胜古  阳柯  王芳  盛光晓 《测绘通报》2020,(3):91-95

传统的农村公路核查需要人工实地抽查或通过GNSS设备进行信息采集验核，存在成本高、效率低等问题。遥感影像具有成像范围广、时效性高、成本低、能客观反映现实情况等优点。相比于传统方法，将遥感影像引入农村公路核查，能客观、准确、高效地对农村公路相关信息进行核查。本文基于国产高分辨率遥感影像，结合农村公路遥感核查业务，采用遥感影像道路提取算法，设计并实现了一种农村公路核查方法。将本方法应用于某中部省份农村公路遥感核查业务，实际应用表明该方法能有效提高现有农村公路遥感核查的工作效率。  相似文献   

西部省会城市新型城镇化水平综合测度研究          下载免费PDF全文

邹亚锋  李亚静  袁志鸿 《干旱区地理》2020,43(6):1612-1621

新型城镇化是中国经济社会健康、稳定、可持续发展的根本途径，也是消除中国城乡社会经 济“二元结构”的根本出路。根据新型城镇化的内涵，从人口、经济发展、生活质量、基础设施、资源 环境、城乡统筹 6 个方面，构建了包含 24 项指标的新型城镇化水平综合测度指标体系，运用熵值 法，对西部 11 个省会城市 2005—2015 年的城镇化发展水平进行综合测度。研究表明：西部省会城 市的新型城镇化发展水平存在显著差异，总体上可分为“高等水平”、“中等水平”、“低等水平”3 个 级别，基础设施建设是造成差异的主要驱动力。各城市不同年间的城镇化单项水平影响因素呈现 多元化，在今后的发展中应有所侧重，同时兼顾城镇化质量，推动城乡协调发展。  相似文献   

中国省域尺度17部门资本存量的时空特征分析     

刘丽  李宁  张正涛  冯介玲  陈曦  白扣  黄承芳 《地理科学进展》2019,38(4):546-555

随着灾害强度、频率以及承灾体暴露的增加,自然灾害造成的损失日益严重。资本存量作为承灾体的经济暴露指标之一,是灾害损失评估的前提和基础。针对目前中国缺乏省域尺度长时间序列的经济部门分类的资本存量数据基础,论文通过永续盘存法,建立了2003—2015年中国大陆31省17部门的资本存量数据库,并分析其时空特征。结果显示：① 全国总资本存量与灾害直接损失的年际变化均呈增加趋势。省域尺度上,通过相关性分析显示,在99%置信度水平上,两者呈显著正相关(r=0.3)。② 时间上,各省17部门资本存量基本也呈增加趋势,但增速不同。在各部门增速最快的省份中,黑龙江省的居民服务、修理和其他服务业增速最快,增长约454.3倍;其次是青海省的租赁和商务服务业(398.3倍)、江苏省的金融业(295.1倍)、安徽省的科学研究和技术服务业(125.1倍)等。③ 空间上,2015年各省17部门资本存量最多的前4个部门分别是房地产业,工业,交通运输、仓储和邮政业,水利、环境和公共设施管理业,占比均在60%以上;且这4个部门资本存量暴露最多的省份是江苏省和广东省。该结果有助于从时空角度了解各省各部门资本存量暴露情况,为各省灾害风险管理者的防灾减灾工作提供重要的参考价值。  相似文献   

Post-earthquake economic resilience and recovery efficiency in the border areas of the Tibetan Plateau: A case study of areas affected by the Wenchuan Ms 8.0 Earthquake in Sichuan,China in 2008     

Zhou  Kan  Liu  Baoyin  Fan  Jie 《地理学报(英文版)》2020,30(8):1363-1381

Journal of Geographical Sciences - The border areas of the Tibetan Plateau and the neighboring mountainous areas have a high incidence of earthquakes with a magnitude greater than Ms 5.0, as well...  相似文献   

隧道工程地质评价的内容和方法   总被引：2，自引：0，他引：2  

陈新建  孙琳  李新星  孙巧银 《地球科学与环境学报》2004,26(1):41-45

结合工程隧道实际,首先阐述了隧道工程的基本地质环境和工程地质条件,然后针对隧道工程可能出现的不良地质现象和可采取的工程措施,从大气降水、围岩稳定、围岩压力、洞口稳定、隧道比选等角度探讨隧道工程地质评价的主要方法和一般内容,进行隧道工程地质评价,为隧道施工、支护提供了依据.  相似文献   

济宁市嘉祥县石灰岩矿山地质环境评价与治理   总被引：1，自引：0，他引：1       下载免费PDF全文

贾德旺  吕宝平  贺汉庭  王学森  范纯信 《山东国土资源》2006,22(5):54-57

在对嘉祥县石灰岩矿进行地质灾害危险性评估、矿山环境地质问题评价的基础上,建立了一套评价体系,其中地质灾害危险性评估分为2个评价指标,矿山环境地质问题评价分为2种要素3个指标,同时将矿山恢复治理难易程度也作为一个评价因子。评价过程中对各指标危害性大、中、小程度均单独赋值,然后将各指标的分值进行叠加,确定出矿山环境地质问题的等级,将概划出的13个评价单元分为极差、差、一般3个区。提出了强化矿山管理、植树造林、科学避让、修建拦水坝等保护与治理措施及建议。  相似文献   

基于蚁群算法的城市可持续发展综合评价   总被引：1，自引：0，他引：1  

徐婷婷  于扬  彭娇婷 《成都信息工程学院学报》2006,21(5):694-697

在可持续发展体系分类的基础上，应用蚁群算法对可持续发展各分类指数公式和综合指数公式进行优化，建立可持续发展评价模型。将该模型应用于乌鲁木齐市可持续发展水平评价，评价结果与现状分析一敛。结果表明该模型简单适用、有良好的通用性。  相似文献   

The Roche Limit     

I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2003,87(1-2):13-25

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.  相似文献   

板翅式换热器综合性能优化的设计方法     

高俊忠  陈维汉 《广东海洋大学学报》2003,23(6):45-49

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。  相似文献