短波红外光谱、X射线荧光光谱、黄铁矿热电性分析在胶东新城金矿田深部找矿中的应用     

邵雪维  彭永明  王功文  赵显勇  唐佳洋  黄蕾蕾  刘晓宁  赵宪东 《地学前缘》2021,28(3):236-251

胶东半岛是我国最重要的金矿集区之一,其矿床是典型受北东向断裂构造(焦家断裂带、三山岛断裂带和招平断裂带),以及次生断裂构造(如望儿山断裂和灵北断裂等)控制的矿床类型。前人在该区域做了大量研究,但主要集中在地表和浅层成矿段,对于深部成矿规律与预测的研究相对较少。新城金矿田是胶东半岛的特大型金矿之一,由新城矿床、曲家矿床和招贤矿床三部分组成。由于受到焦家断裂带控制,在招贤矿区中的科研深钻达到2 500 m以下,为我们研究深部成矿规律提供了良好的样品。本文通过该地区蚀变矿物的短波红外光谱特征(short-wave infrared spectroscopy,SWIR),并结合X 射线荧光光谱(X-ray fluorescence spectrometry,XRF)法和黄铁矿热电性法,选取该地的不同成矿阶段的蚀变岩石和典型载金矿物黄铁矿,并在三维环境中,定量化分析了主要的蚀变矿物——白云母族的短波红外光谱的特征值,揭示其找矿规律与指示意义,进一步提取矿床中蚀变矿物的找矿标志。研究结果表明:(1)在靠近焦家主断裂构造蚀变岩型矿体的位置,伊利石结晶度(≥1.2)和绢云母Al—OH吸收位置(≥2 205 nm)偏高,而在远离焦家主断裂构造蚀变岩型矿体的位置伊利石结晶度和绢云母Al—OH吸收位置偏低,分别为0.2~1.2和2 198~2 205 nm。(2)X 射线荧光光谱结果提取了该地区20种元素含量,通过对元素的主成分分析和聚类分析, Al—OH吸收峰位置偏移与Al、K、Si含量变化有一定相关性。(3)黄铁矿热电性导型在近焦家主断裂构造蚀变岩主要为P型,远离主断裂的主要为N型。在新城矿区的Ⅰ号和Ⅴ号矿体的顶部到底部整体呈现N-P→P→P-N→N→N-P→P-N和P-N→N-P的规律;在招贤矿区中绝大部分是P型。剥蚀度整体处于在25%~50%,因此在新城矿区约-800 m以下和招贤矿区约-1 500 m以下,仍有较好的深部找矿前景。整体上P型黄铁矿成矿温度主要为180~250 ℃,N型成矿温度主要区间值在380~460 ℃;利用温度场进行三维插值建模,其与三维矿体品位模型空间展布趋势一致。本文综合研究方法为深部矿产资源评价提供新的研究思路,将光谱数据、地化数据等多维度信息集成整合,同时使用三维模型可视化功能,对于矿产模型定量化构建具有重要参考价值。  相似文献   

Three-dimensional graphic display of disconnected bodies     

J. L. Mallet 《Mathematical Geology》1988,20(8):977-990

Lett= (x, y, z) be an ore grade function sampled at the nodes of a three dimensional regular grid. Ift ₀ is a given cut-off, the ore deposit may be considered to be constituted by all the points (x, y, z) such that (x, y, z)>t ₀. In fact, the ore deposit may be constituted by one or several disconnected bodies and two algorithms to display these bodies may be considered. The first consists in drawing intersections of the bodies with a series of equidistant parallel planes. The second consists in covering their surface with painted triangles. In both cases, how to remove hidden parts of the drawing is shown. An interactive approach of the problem also is considered.This paper presented at Emerging Concepts, MGUS-87 conference, Redwood City, California, 13–15 April 1987.  相似文献   

微型活性碳柱富集比色法测定金     

丁耀伟 《华东地质学院学报》1989,(4)

本文探讨了用微型活性碳柱富集痕量金的方法。研究了富集金和TMK—Au—Twee 85显色反应的条件,用本法测定了地质试样中痕量金,其测定限为2 ppbAu,本法操作简便、快速,灵敏度高,结果较为满意。  相似文献   

波伏棱（Povlen）型羟基纤蛇纹石的谱学研究     

朱和宝  江绍英  邵涵如  吴卫芳 《岩石矿物学杂志》1989,8(1):43-53

波伏棱型羟基纤蛇纹石是波伏棱型纤蛇纹石矿物的新变种,本文报导它的吸收光谱、红外光谱、穆斯堡尔谱、电子顺磁共振谱和核磁共振谱。 研究表明,吸收光谱是Fe~(3 )和Fe~(2 )的晶场跃迁以及Fe~(2 )→Fe~(3 )的荷移跃迁引起的;红外光谱是OH和Si-O的伸缩振动、OH转动以及Mg-O和Si-O的弯曲振动引起的;穆斯堡尔谱是Fe~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;电子顺磁共振谱是Mn~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;核磁共振谱是管道水,镁八面体和硅氧四面体上的OH引起的;矿物加热到825℃时,结构开始破坏并出现镁橄榄石相。 此外,本文还解释了该蛇纹石颜色的本质,阐明了上述过渡金属离子和OH在该矿物中的结构环境。  相似文献   

Ultraviolet absorption cross-sections of chloro and chlorofluoro-methanes at stratospheric temperatures     

P. C. Simon  D. Gillotay  N. Vanlaethem-Meuree  J. Wisemberg 《Journal of Atmospheric Chemistry》1988,7(2):107-135

Absorption cross-sections of nine halomethanes (CCl₄, CHCl₃, CH₂Cl₂, CH₃Cl, CFCl₃, CF₂Cl₂, CF₃Cl, CHFCl₂, and CHF₂Cl), measured between 174 and 250 nm for temperatures ranging from 225 to 295 K, are presented with uncertainties ranging from 2 to 4% and compared with previous determinations made for comparable temperature ranges.The largest temperature effect which takes place near the absorption threshold, decreases the absorption cross-section up to 50% for highly chlorinated methanes, but is negligible for molecules highly stabilized by hydrogen and/or fluorine. Extrapolated values for temperatures of aeronomical interest are presented, as well as parametrical formulas which give absorption cross-section values for given wavelength and temperature ranges.  相似文献   

自然金—银类质同象系列矿物晶胞参数变化规律及其表述方程     

姜跃先 《矿物学报》1993,13(3):250-253

本文提出了自然金-银类质同象系列矿物的晶胞参数与金、银原子数百分比成二次函数关系,推导出了表示二者之间函数关系的方程式。利用该方程式,可以用金原子数百分比计算出晶胞参数,反之亦然。并且从金、银二者的电负性出发,对a值的变化作了解释。  相似文献   

微波等离子体炬原子发射光谱法测定铁和铝的研究   总被引：2，自引：0，他引：2  

董德凡  叶冬梅 《岩矿测试》1994,13(1):41-44

研究了低功率微波等离子体炬原子发射光谱法（ＭＰＴ－ＡＥＳ）对Ｆｅ，Ａｌ的测定。样品经气动雾化后，分别以流动注射与连续式两种方式引入ＭＰＴ。考察了用这两种进样方式时ＭＰＴ－ＡＥＳ的分析性能，证明低功率ＭＰＴ－ＡＥＳ具有良好的分析特性。  相似文献   

矿石中金的在线固相萃取及缝管火焰原子吸收测定   总被引：3，自引：0，他引：3  

徐淑坤  孙励敬 《岩矿测试》1994,13(3):203-206

介绍了将流动注射在线因相萃取预浓集与石英缝管火焰原子吸收相结合测定矿石中金的方法，用ＸＡＤ－８吸附树脂填充的微型柱（１００μｌ）在６ｍｌ／ｍｉｎ的流速下，从０．５ｍｏｌ／ＬＨＣｌ介质的试样溶液中浓集金氯络合物，再用乙醇洗脱，最后由火焰原子吸收检测，在采样频率为１０３样／ｈ的流速下灵敏度提高４７倍，分析精度为１．３％，检出限为１．０μｇ／Ｌ；在６５样／ｈ的采样频率下灵敏度提高９５倍，检出限可达０．７  相似文献   

Determination of part-per-trillion levels of atmospheric dimethyl sulfide by isotope dilution gas chromatography/mass spectrometry     

Donald C. Thornton  Alan R. Bandy  Robert G. Ridgeway  Arthur R. Driedger III  Marija Lalevic 《Journal of Atmospheric Chemistry》1990,11(4):299-308

Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min.  相似文献   

Time domain solution for multiple scattering and the coda envelopes     

Long-Sheng Gao  Song Lin Li 《Pure and Applied Geophysics》1990,132(1-2):123-150

This article summarizes work on multiple scattering based on models of media with randomly distributed scatterers. The scatterers are isotropic and statistically uniform. Measuring distance in terms of mean-free pathL _s and time in terms of the mean-free timesL _s/V, whereV is the velocity of scattered waves, we have more convenient dimensionless distance and time. It can be shown that after the dimensionless time equals 0.65 energy contributed from multiple scattering becomes predominant. Thus the later coda reflects the effect of multiple scattering rather than single scattering. Treating the seismic record, including starting and tail parts, as a whole, the diffusion theory predicts that at a dense distribution of scatterers and a small distance between source and receiver, codas reflect mainly intrinsicQ _i. Of course, this conclusion is coincident with the presumption of the diffusion theory,Q _s>Q _i. However, from a new integral equation of multiple scattering, which deals with the scattered waves and primary waves separately, the conclusion is similar but clearer. This article quotes the new expression for coda energy in two-dimensional space. It shows that if the receiver is close to the source, the coda decay reflects only intrinsicQ _i, then as the distance increases, effects of scatteringQ _s, are involved in the decay feature. The theoretical plots of coda decay show that it seems in most cases in the earthQ _i should not be smaller than one tenth ofQ _s.Project Sponsored by the Joint Earthquake Science Foundation of China.  相似文献