http://www.sciencedirect.com/science/article/pii/S1674987113000595   总被引：11，自引：0，他引：11  

Mei-Fu Zhou  Wei Terry Chen  Christina Yan Wang  Stephen A.Prevec  Patricia Pingping Liu  Geoffrey H.Howarth 《地学前缘(英文版)》2013,4(5):481-502

Magmatic oxide deposits in the～260 Ma Emeishan Large Igneous Province(ELIP),SW China and northern Vietnam,are important sources of Fe,Ti and V.Some giant magmatic Fe-Ti-V oxide deposits, such as the Panzhihua,Hongge,and Baima deposits,are well described in the literature and are hosted in layered mafic-ultramafic intrusions in the Panxi region,the central ELIP.The same type of ELIP- related deposits also occur far to the south and include the Anyi deposit,about 130 km south of Panzhihua,and the Mianhuadi deposit in the Red River fault zone.The Anyi deposit is relatively small but is similarly hosted in a layered mafic intrusion.The Mianhuadi deposit has a zircon U-Pb age of～260 Ma and is thus contemporaneous with the ELIP.This deposit was variably metamorphosed during the Indosinian orogeny and Red River faulting.Compositionally,magnetite of the Mianhuadi deposit contains smaller amounts of Ti and V than that of the other deposits,possibly attributable to the later metamorphism.The distribution of the oxide ore deposits is not related to the domal structure of the ELIP.One major feature of all the oxide deposits in the ELIP is the spatial association of oxide-bearing gabbroic intrusions,syenitic plutons and high-Ti flood basalts.Thus,we propose that magmas from a mantle plume were emplaced into a shallow magma chamber where they were evolved into a field of liquid immiscibility to form two silicate liquids,one with an extremely Fe-Ti-rich gabbroic composition and the other syenitic.An immiscible Fe-Ti-(P) oxide melt may then separate from the mafic magmas to form oxide deposits.The parental magmas from which these deposits formed were likely Fe-Ti-rich picritic in composition and were derived from enriched asthenospheric mantle at a greater depth than the magmas that produced sulfide-bearing intrusions of the ELIP.  相似文献   

晚二叠世峨眉山地幔柱岩浆成矿作用     

汤庆艳  张铭杰  余明  王启立  尚慧 《岩石矿物学杂志》2013,32(5):680-692

晚二叠世峨眉山地幔柱岩浆作用同时形成了Cu-Ni-PGE硫化物矿床和V-Ti-Fe氧化物矿床等不同类型的岩浆矿床。从硫化物矿床的PGE富集型、Cu-Ni-PGE富集型到Cu-Ni富集型,再到钒钛磁铁矿矿床,成矿基性-超基性岩体中基性岩石比例逐渐增加,PGE含量降低。铜镍铂族硫化物矿床具Nb和Ta负异常,岩浆流体组分含量较高,含有较高的H₂;而钒钛磁铁矿矿床具Nb、Ta和Ti正异常,Zr和Hf负异常,岩浆流体组分含量较低,含有较高的H₂O、CO₂和H₂。两类矿床强不相容元素和轻稀土元素(LREE)富集,Sr-Nd同位素组成与峨眉山玄武岩的演化趋势一致。Sr-Nd-Os-C-He同位素组成揭示岩浆上升过程中经历了不同程度的地壳混染,高钛玄武岩和钒钛磁铁矿矿床成矿岩体的地壳混染程度较低,部分低钛玄武岩和铜镍硫化物矿床存在明显的地壳混染。这两类岩浆矿床的形成与峨眉山地幔柱玄武岩浆有关,岩浆介质环境中H₂含量较高,V-Ti-Fe 氧化物矿床的形成与分离结晶、高含量的水和氧逸度的升高有关,Cu-Ni-(PGE)硫化物矿床的形成与还原性流体介质、结晶分异和地壳混染作用有关。  相似文献   

云南白马寨铜镍硫化物矿床铂族元素地球化学及其对矿床成因的制约   总被引：18，自引：3，他引：15  

王生伟  孙晓明  石贵勇  熊德信  翟伟 《地质学报》2006,80(9):1474-1486

采用镍硫火试金ICP-MS法分析了白马寨铜镍硫化物矿床矿石及其主要围岩铂族元素(PGE)含量,结果表明铂族元素总量(ΣPGE)普遍较低,且ΣPGE由矿床核部的块状矿石(78.15×10-9~555.92×10-9)向外围矿化橄榄岩(6.77×10-9~70.95×10-9)至辉长岩(3.02×10-9)逐步降低。煌斑岩脉岩的ΣPGE也较低,为6.86×10-9~17.03×10-9。ΣPGE与Ni含量呈明显的正相关。不同种类岩石和矿石的PGE原始地幔配分模式明显不同,块状矿石为Pt-Pd配分型,Ir较明显亏损;矿化橄榄岩配分曲线较平坦,IPGE和PPGE分异不明显,但均出现Ru正异常。辉长岩样品和煌斑岩PGE配分模式几乎一致,也均出现明显的Ru正异常。矿石和围岩的Cu/Pd值远高于原始地幔,表明原生岩浆发生了较强的硫化物熔离作用。块状富镍矿石的(Pt+Pd)/(Os+Ir+Ru)和Pd/Ir分别为138.24和24.7,指示其母岩浆为演化较为彻底的玄武质岩浆,而矿化橄榄岩的相应值分别为3.02和16.09,具有科马提质岩浆的特征参数,因此白马寨块状矿石和矿化橄榄岩之间可能没有成因联系。块状硫化物熔体侵位前,其母岩浆经历过长时间强烈的硫化物熔离作用,硫化物熔浆作为独立的侵入相而侵入于III号岩体核部。这个过程反映了峨眉山地幔柱尾部岩浆演化和成矿可能经历过高度的S饱和过程。白马寨矿床形成过程中可能受到地壳物质的混染。  相似文献   

峨眉山地幔柱上升的沉积响应及其地质意义   总被引：28，自引：0，他引：28  

何斌徐义刚  肖龙王雅玫  王康明沙绍礼 《地质论评》2006,52(1):30-37

研究表明西南地区峨眉山玄武岩下伏茅口组的部分缺失是峨眉山地幔柱的快速上升及其所形成的地壳穹状隆起造成的。对该地区中、晚二叠世沉积记录的研究也支持上述结论。通过野外实地地质考察和室内综合研究发现,西南地区峨眉山玄武岩之下零星发育一套碎屑岩系,其主要分布在穹状隆起的边缘。在隆起西缘盐源平川一带,为一岩性以砾岩、砂岩为主的低位水下扇;在隆起的东北缘普格、巧家、武定一带,峨眉山玄武岩之下发育一层砾石,主要为茅口组灰岩的灰岩质砾岩;昆明西山地区的灰岩质砾岩中灰岩砾石的磨圆较好,可能代表古河谷沉积。在茅口组顶部古剥蚀面上还零星可见一层厚几米至十几米残积相碎屑岩或底砾岩。上述碎屑岩系的厘定及对其空间分布和沉积环境的研究表明,上扬子西缘峨眉山玄武岩喷发前地壳发生快速穹状抬升,碎屑岩是峨眉山地幔柱上升造成的沉积响应;地幔柱的上升还造成上扬子中、晚二叠世区域岩相古地理的突变和隆起区古喀斯特的形成。这些为峨眉山大火成岩省地幔柱形成机制提供了进一步佐证,同时深化了对晚古生代上扬子西缘构造的认识。  相似文献   

Two magma series and associated ore deposit types in the Permian Emeishan large igneous province, SW China   总被引：29，自引：0，他引：29  

Mei-Fu Zhou  Nicolas T. Arndt  John Malpas  Christina Yan Wang  Allen K. Kennedy 《Lithos》2008,103(3-4):352-368

The Late Middle Permian ( 260 Ma) Emeishan large igneous province in SW China contains two magmatic series, one comprising high-Ti basalts and Fe-rich gabbroic and syenitic intrusions, the other low-Ti basalts and mafic–ultramafic intrusions. The Fe-rich gabbros are spatially and temporally associated with syenites. Each series is associated with a distinctive type of mineralization, the first with giant Fe–Ti–V oxide ore deposits such as Panzhihua and Baima, the second with Ni–Cu–(PGE) sulfide deposits such as Jinbaoshan, Limahe and Zhubu. New SHRIMP zircon U–Pb isotopic data yielded 263 ± 3 Ma for the Limahe intrusion, 261 ± 2 Ma for the Zhubu intrusion and 262 ± 2 Ma for a syenitic intrusion. These new age dates, together with previously reported SHRIMP zircon U–Pb ages, suggest that all these intrusions are contemporaneous with the Emeishan flood basalts and formed during a major igneous event at ca. 260 Ma.The oxide-bearing intrusions have higher Al₂O₃, FeO (as total iron) and total alkalis (Na₂O + K₂O) but lower MgO than the sulfide-bearing intrusions. All intrusions are variably enriched in LREE relative to HREE. The oxide-bearing intrusions display positive Nb- and Ti-anomalies and in certain cases negative Zr–Hf anomalies, whereas the sulfide-bearing intrusions have obvious negative Nb- and Ti-anomalies, a feature of crustal contamination. Individual intrusions have relatively small ranges of Nd(t) values. All the intrusions, however, have Nd(t) values ranging from − 3.9 to + 4.6, and initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7039 to 0.7105. The syenites have very low MgO (< 2 wt.%) but highly variable Fe₂O₃ (2.5 to 13 wt.%) with initial ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.7039 to 0.7089. Magmas from both series could have derived by melting of a heterogeneous mantle plume: the high-Ti series from a Fe-rich, more fertile source and the low-Ti series from a Fe-poor, more refractory source. In addition, the low-Ti series underwent significant crustal contamination. The two magma series evolved along different paths that led to distinct mineralization styles.  相似文献   

Platinum-group minerals from the Jinbaoshan Pd–Pt deposit,SW China: evidence for magmatic origin and hydrothermal alteration     

Christina Yan Wang  Hazel M. Prichard  Mei-Fu Zhou  Peter C. Fisher 《Mineralium Deposita》2008,43(7):791-803

The Jinbaoshan Pt–Pd deposit in Yunnan, SW China, is hosted in a wehrlite body, which is a member of the Permian (∼260 Ma) Emeishan Large Igneous Province (ELIP). The deposit is reported to contain one million tonnes of Pt–Pd ore grading 0.21% Ni and 0.16% Cu with 3.0 g/t (Pd + Pt). Platinum-group minerals (PGM) mostly are ∼10 μm in diameter, and are commonly Te-, Sn- and As-bearing, including moncheite (PtTe₂), atokite (Pd₃Sn), kotulskite (PdTe), sperrylite (PtAs₂), irarsite (IrAsS), cooperite (PtS), sudburyite (PdSb), and Pt–Fe alloy. Primary rock-forming minerals are olivine and clinopyroxene, with clinopyroxene forming anhedral poikilitic crystals surrounding olivine. Primary chromite occurs either as euhedral grains enclosed within olivine or as an interstitial phase to the olivine. However, the intrusion has undergone extensive hydrothermal alteration. Most olivine grains have been altered to serpentine, and interstitial clinopyroxene is often altered to actinolite/tremolite and locally biotite. Interstitial chromite grains are either partially or totally replaced by secondary magnetite. Base-metal sulfides (BMS), such as pentlandite and chalcopyrite, are usually interstitial to the altered olivine. PGM are located with the BMS and are therefore also interstitial to the serpentinized olivine grains, occurring within altered interstitial clinopyroxene and chromite, or along the edges of these minerals, which predominantly altered to actinolite/tremolite, serpentine and magnetite. Hydrothermal fluids were responsible for the release of the platinum-group elements (PGE) from the BMS to precipitate the PGM at low temperature during pervasive alteration. A sequence of alteration of the PGM has been recognized. Initially moncheite and atokite have been corroded and recrystallized during the formation of actinolite/tremolite, and then, cooperite and moncheite were altered to Pt–Fe alloy where they are in contact with serpentine. Sudburyite occurs in veins indicating late Pd mobility. However, textural evidence shows that the PGM are still in close proximity to the BMS. They occur in PGE-rich layers located at specific igneous horizons in the intrusion, suggesting that PGE were originally magmatic concentrations that, within a PGE-rich horizon, crystallized with BMS late in the olivine/clinopyroxene crystallization sequence and have not been significantly transported during serpentinization and alteration.  相似文献   

Mineralogical,petrological, and geochemical studies of the Limahe mafic–ultramatic intrusion and associated Ni–Cu sulfide ores,SW China     

Yan Tao  Chusi Li  Xie-Yan Song  Edward M. Ripley 《Mineralium Deposita》2008,43(8):849-872

The Limahe Ni–Cu sulfide deposit is hosted by a small mafic–ultramafic intrusion (800 × 200 × 300 m) that is temporally associated with the voluminous Permian flood basalts in SW China. The objective of this study is to better understand the origin of the deposit in the context of regional magmatism which is important for the ongoing mineral exploration in the region. The Limahe intrusion is a multiphase intrusion with an ultramafic unit at the base and a mafic unit at the top. The two rock units have intrusive contacts and exhibit similar mantle-normalized trace element patterns and Sr–Nd isotopic compositions but significantly different cumulus mineralogy and major element compositions. The similarities suggest that they are related to a common parental liquid, whereas the differences point to magma differentiation by olivine crystallization at depth. Sulfide mineralization is restricted to the ultramafic unit. The abundances of sulfides in the ultramafic unit generally increase towards the basal contacts with sedimentary footwall. The δ ³⁴S values of sulfide minerals from the Limahe deposit are elevated, ranging from +2.4 to +5.4‰. These values suggest the involvement of external S with elevated δ ³⁴S values. The mantle-normalized platinum-group element (PGE) patterns of bulk sulfide ores are similar to those of picrites associated with flood basalts in the region. The abundances of PGE in the sulfide ores, however, are significantly lower than that of sulfide liquid expected to segregate from undepleted picrite magma. Cr-spinel and olivine are present in the Limahe ultramafic rocks as well as in the picrites. Mantle-normalized trace element patterns of the Limahe intrusion generally resemble those of the picrites. However, negative Nb–Ta anomalies, common features of contamination with the lower or middle crust, are present in the intrusion but absent in the picrites. Sr–Nd isotopes suggest that the Limahe intrusion experienced higher degrees of contamination with the upper crust than did the picrites. The results of this study permit us to suggest that the parental magma of the Limahe intrusion was derived from picritic magma by olivine fractionation and contamination in a staging chamber at mid-crustal levels. Depletion of PGE in the sulfide ores in the Limahe intrusion is likely due to previous sulfide segregation of the parental magmas in the staging chamber. Sulfide mineralization in the Limahe intrusion is related to second-stage sulfide segregation after the fractionated magmas acquired external S from pyrite-bearing country rocks during magma ascent to the Limahe chamber. The abrupt change in mineralogical and chemical compositions between the ultramafic unit and the overlying unit suggests that at least two separate pulses of magma were involved in the development of the Limahe intrusion. We propose that the Limahe intrusion was once a wider part of a dynamic conduit that fed magma to the overlying subvolcanic dykes/sills or lavas. The ultramafic unit formed by the first, relatively more primitive magma, and the mafic unit formed by the second, relatively more fractionated magma. Immiscible sulfide droplets that segregated from the first magma settled down with olivine crystals to form the sulfide-bearing, olivine-rich rocks in the base of the intrusion. The overlying residual liquids were then pushed out of the chamber by the second magma. Critical factors for the formation of an economic Ni–Cu sulfide deposit in such a small intrusion include the dynamic petrologic processes involved and the availability of external sulfur. The Limahe deposit reminds us that small, multiphase, mafic–ultramafic intrusions in the region should not be overlooked for the potential of economic Ni–Cu sulfide deposits.  相似文献   

四川西南部周公山及邻区“峨眉山玄武岩”特征及储集性能研究   总被引：1，自引：0，他引：1  

冯仁蔚  王兴志  张帆  杨跃明  李跃纲  庞艳君  张若祥 《沉积学报》2008,26(6):913-924

川西南部周公山及邻区上二叠统“峨眉山玄武岩”厚40～500 m,由12个旋回性玄武质火山岩构成。每一旋回底部的火山角砾岩和上部的气孔—杏仁状玄武岩常具有一定的储渗能力,储渗空间以气孔、柱状节理缝、构造裂缝为主,属于低孔、中渗或低孔、高渗型储层;其余层段如无构造作用的叠加,多构成非储集岩类。在该套储层的形成与演化过程中,岩浆的冷凝收缩、构造断裂和大气淡水、地层水溶蚀作用和有机质成熟过程都促进了储渗空间的形成,而热液蚀变作用、四期胶结作用和三期充填作用对储集空间起着明显的破坏作用。  相似文献   

四川广元地区朝天剖面上二叠统吴家坪组凝灰岩成因及其地质意义     

张晗  黄虎  侯明才 《地球科学与环境学报》2020,(1):36-48

四川广元地区朝天剖面上二叠统吴家坪组凝灰岩位于茅口组顶部王坡层黏土岩之上,其成因可能对认识峨眉山大火成岩省火山活动时限具有重要意义。对朝天剖面吴家坪组2个凝灰岩样品进行全岩矿物含量、地球化学特征、锆石U-Pb定年、锆石微量元素和Hf同位素分析,探讨凝灰岩的成因,进而讨论其对峨眉山大火成岩省火山活动时限的启示。结果表明:广元地区朝天剖面上二叠统吴家坪组凝灰岩主要由黏土矿物组成,锆石U-Pb年龄为(260.1±2.8)Ma,并具有较高的Al2O3/TiO2值(分别为37.90和31.49)、明显的Eu负异常(Eu/Eu*值分别为0.13和0.06)及缺失Nb、Ta负异常;凝灰岩样品中,锆石具有较高的εHf(t)值(7.8~11.4)和较低的Th/Nb值(5.4~14.9),与宾川剖面峨眉山火山序列酸性熔结凝灰岩及上寺剖面上二叠统下部凝灰岩基本一致,而明显不同于清音阁王坡层黏土岩锆石εHf(t)值和Th/Nb值。综上所述,四川广元地区朝天剖面上二叠统吴家坪组凝灰岩的形成与峨眉山大火成岩省酸性火山活动有关,且峨眉山大火成岩省的火山活动时限可能一直持续到晚二叠世早期。  相似文献   

对四川乐山地区二叠纪—侏罗纪多个含铜层位铜矿找矿工作的思考     

文俊 《地质论评》2022,68(6):2022112024-2022112024

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