Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?          下载免费PDF全文

Chongbin Zhao  B.E. Hobbs  A. Ord 《国际地质力学数值与分析法杂志》2017,41(15):1590-1602

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Towards a moral socio-environmental economy: A reconsideration of values     

《Geoforum》2015

In this intervention article I contribute to discussions of moral economy by arguing that scholars should reconsider the nature of value. Neoliberalism considers only exchange value. As a consequence neoliberal policies try to manage problems such as climate change with economic systems and instruments that are mis-calibrated to the material realities they are meant to represent. Value has spatial and temporal characteristics. Recognizing the spatial and temporal dynamics of value leads to new means of resource valuation, such as extending the time-frame of instruments and changing the nature of privatization. In conclusion, I argue for the need for new theories of use value.  相似文献   

A new approach to estimate canopy evaporation and canopy interception capacity from evapotranspiration and sap flow measurements during and following wetting          下载免费PDF全文

J. Uddin  J. P. Foley  R. J. Smith  N. H. Hancock 《水文研究》2016,30(11):1757-1767

Canopy interception and its evaporation into the atmosphere during irrigation or a rainfall event are important in irrigation scheduling, but are challenging to estimate using conventional methods. This study introduces a new approach to estimate the canopy interception from measurements of actual total evapotranspiration (ET) using eddy covariance and estimation of the transpiration from measurements of sap flow. The measurements were conducted over a small‐scale sprinkler‐irrigated cotton field before, during and after sprinkler irrigation. Evaporation and sap flow dynamics during irrigation show that the total ET during irrigation increased significantly because of the evaporation of free intercepted water while transpiration was suppressed almost completely. The difference between actual ET and transpiration (sap flow) during and immediately following irrigation (post irrigation) represents the total canopy evaporation while the canopy interception capacity was calculated as the difference between actual ET and transpiration (sap flow) during drying (post irrigation) following cessation of the irrigation. The canopy evaporation of cotton canopy was calculated as 0.8 mm, and the interception capacity was estimated to be 0.31 mm of water. The measurement uncertainty in both the non‐dimensional ET and non‐dimensional sap flow was shown to be very low. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Analysis of shaft resistance of jacked piles in sands     

Rodrigo Salgado 《国际地质力学数值与分析法杂志》2011,35(15):1605-1635

In recent years, pile jacking has become a viable alternative installation method for displacement piles. Pile jacking produces minimal noise, vibration and air pollution during installation. In addition, it is possible, at the end of jacking, to have a good estimate of the ultimate static capacity of the pile. In this paper, the shaft resistance of piles jacked into sand is studied using one‐dimensional finite element analysis. The finite element simulations, using a two‐surface plasticity model, demonstrate the effects of relative density and confinement on the unit shaft resistance of piles jacked in sand. The impact of the number of jacking strokes on the unit shaft capacity is also assessed. Based on the numerical results, we developed equations for shaft resistance quantifying the effects of relative density, initial confinement and number of jacking strokes. Predictions using these equations are compared with data obtained from centrifuge tests and field tests. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

War,by Conservation     

《Geoforum》2016

In this paper I argue that there has been a critical shift towards war by conservation in which conservation, security and counter insurgency (COIN) are becoming more closely integrated. In this new phase concerns about global security constitute important underlying drivers, while biodiversity conservation is of secondary importance. This is a significant break from earlier phases of fortress conservation and war for biodiversity. In order to develop a better understanding of these shifts, this paper analyzes the existing conceptual approaches, notably environmental security which seeks to understand how resources cause or shape conflict, and political ecology approaches that focus on the struggles over access to and control over resources. However, this paper indicates the limitations of these existing debates for understanding recent shifts, which require a fresh approach. I chart the rise of the narrative I call poachers-as-terrorists, which relies on the invocation of the idea that ivory is the white gold of Jihad, a phrase which is closely associated with an Elephant Action League (EAL) report in 2012 which claimed Al Shabaab used ivory to fund its operations. This narrative is being extended and deepened by a powerful alliance of states, conservation NGOs, Private Military Companies and international organizations, such that it is shaping policies, especially in areas of US geo-strategic interest in Sub-Saharan Africa. As a result conservation is becoming a core element of a global security project, with significant implications for conceptual debates and for conservation practice on the ground.  相似文献   

Public views on economic growth,the environment and prosperity: Results of a questionnaire survey     

《Global Environmental Change》2016

The long-standing academic and public debate on economic growth, prosperity and environmental sustainability has recently gained new momentum. It lacks, however, a broad perspective on public opinion. Prior opinion surveys typically offered a simple dichotomous choice between growth and environmental protection. This study examines public beliefs and attitudes about a wider range of aspects of the growth debate. To this end, we conducted an online questionnaire survey including a country-wide, representative sample of 1008 Spanish citizens. Using factor analysis, we identify six distinct dimensions of public attitudes, referred to as: prosperity with growth; environmental limits to growth; general optimism; wrong priority; overrated GDP; and governmental control. We further analyze several specific questions associated with the growth debate, such as those concerning the desired GDP growth rate, the preferred growth-environment position, and beliefs about, as well as reasons for, a possible end or continuation of growth. We find that most respondents favor GDP growth rates of more than 3%. A majority views growth and environmental sustainability as compatible (green growth), while about one-third prefers either ignoring growth as a policy aim (agrowth), or stopping it altogether (degrowth). Only very few people want growth unconditionally (growth-at-all-costs). About one-third of the respondents believe that growth may be never-ending. We examine how support for or disagreement with different statements on growth are related to each other, as well as how they are influenced by socio-demographic, knowledge and ideology/values variables. Overall, our findings can inform public debates about the growth paradigm and its potential alternatives by providing a more nuanced understanding of public opinion. We make suggestions for future research, including modifying poll questions on growth and environment through offering a more diverse set of response options.  相似文献   

Modelling complex systems of heterogeneous agents to better design sustainability transitions policy     

《Global Environmental Change》2016

This article proposes a fundamental methodological shift in the modelling of policy interventions for sustainability transitions in order to account for complexity (e.g. self-reinforcing mechanisms, such as technology lock-ins, arising from multi-agent interactions) and agent heterogeneity (e.g. differences in consumer and investment behaviour arising from income stratification). We first characterise the uncertainty faced by climate policy-makers and its implications for investment decision-makers. We then identify five shortcomings in the equilibrium and optimisation-based approaches most frequently used to inform sustainability policy: (i) their normative, optimisation-based nature, (ii) their unrealistic reliance on the full-rationality of agents, (iii) their inability to account for mutual influences among agents (multi-agent interactions) and capture related self-reinforcing (positive feedback) processes, (iv) their inability to represent multiple solutions and path-dependency, and (v) their inability to properly account for agent heterogeneity. The aim of this article is to introduce an alternative modelling approach based on complexity dynamics and agent heterogeneity, and explore its use in four key areas of sustainability policy, namely (1) technology adoption and diffusion, (2) macroeconomic impacts of low-carbon policies, (3) interactions between the socio-economic system and the natural environment, and (4) the anticipation of policy outcomes. The practical relevance of the proposed methodology is subsequently discussed by reference to four specific applications relating to each of the above areas: the diffusion of transport technology, the impact of low-carbon investment on income and employment, the management of cascading uncertainties, and the cross-sectoral impact of biofuels policies. In conclusion, the article calls for a fundamental methodological shift aligning the modelling of the socio-economic system with that of the climatic system, for a combined and realistic understanding of the impact of sustainability policies.  相似文献   

附有物理量和气象条件约束的光学卫星国土观测有效覆盖率评估     

巫兆聪  巫远  张熠  杨帆 《测绘学报》2016,45(7):841-849

传统光学卫星国土观测覆盖评估建立在卫星对地理想覆盖的基础上,并未考虑卫星存储、星地数据传输、观测时长等物理量及观测区域气象因素对于覆盖性能的影响。本文针对光学遥感卫星的国土观测需求.建立国土观测有效覆盖能力评估指标体系,根据卫星数据存储能力、星地数据传输能力、卫星单圈最大观测时长、卫星观测太阳高度角等性能参数,提出了基于物理性能约束下的有效覆盖计算方法。根据气象台站历年气象数据,提出了气象约束因子的计算方法。综合考虑卫星物理性能约束与观测区域气象约束,计算光学遥感卫星对地观测有效覆盖能力。最后根据专家设计的光学遥感卫星国土观测有效覆盖能力评估指标权重,利用层次分析法(AHP)评估光学遥感卫星系统对于国土观测的需求满足程度。试验结果表明,本文方法对于国土观测有效覆盖的估算和评价结果更加精确,更接近于国土观测的实际应用需求,为对地观测有效覆盖能力评估提供了一种更为精确的可行方案。  相似文献   

Origin and evolution of geothermal fluids from Las Tres Vírgenes and Cerro Prieto fields,Mexico – Co-genetic volcanic activity and paleoclimatic constraints     

《Applied Geochemistry》2016

Major and trace elements, noble gases, and stable (δD, δ¹⁸O) and cosmogenic (³H, ¹⁴C) isotopes were measured from geothermal fluids in two adjacent geothermal areas in NW-Mexico, Las Tres Vírgenes (LTV) and Cerro Prieto (CP). The goal is to trace the origin of reservoir fluids and to place paleoclimate and structural-volcanic constraints in the region. Measured ³He/⁴He (R) ratios normalized to the atmospheric value (R_a = 1.386 × 10⁻⁶) vary between 2.73 and 4.77 and are compatible with mixing between a mantle component varying between 42 and 77% of mantle helium and a crustal, radiogenic He component with contributions varying between 23% and 58%. Apparent U–Th/⁴He ages for CP fluids (0.7–7 Ma) suggest the presence of a sustained ⁴He flux from a granitic basement or from mixing with connate brines, deposited during the Colorado River delta formation (1.5–3 Ma). Radiogenic in situ ⁴He production age modeling at LTV, combined with the presence of radiogenic carbon (1.89 ± 0.11 pmC – 35.61 ± 0.28 pmC) and the absence of tritium strongly suggest the Quaternary infiltration of meteoric water into the LTV geothermal reservoir, ranging between 4 and 31 ka BP. The present geochemical heterogeneity of LTV fluids can be reconstructed by mixing Late Pleistocene – Early Holocene meteoric water (58–75%) with a fossil seawater component (25–42%), as evidenced by Br/Cl and stable isotope trends. CP geothermal water is composed of infiltrated Colorado River water with a minor impact by halite dissolution, whereas a vapor-dominated sample is composed of Colorado River water and vapor from deeper levels. δD values for the LTV meteoric end-member, which are 20‰–44‰ depleted with respect to present-day precipitation, as well as calculated annual paleotemperatures 6.9–13.6 °C lower than present average temperatures in Baja California point to the presence of humid and cooler climatic conditions in the Baja California peninsula during the final stage of the Last Glacial Pluvial period. Quaternary recharge of the LTV geothermal reservoir is related to elevated precipitation rates during cooler-humid climate intervals in the Late Pleistocene and Early Holocene. The probable replacement of connate water or pore fluids by infiltrating surface water might have been triggered by enhanced fracture and fault permeability through contemporaneous tectonic–volcanic activity in the Las Tres Vírgenes region. Fast hydrothermal alteration processes caused a secondary, positive δ¹⁸O-shift from 4‰ to 6‰ for LTV and from 2‰ to 4‰ for CP geothermal fluids since the Late Glacial infiltration.  相似文献   

Development and Utilization of the World’s and China’s Bulk Mineral Resources and their Supply and Demand Situation in the Next Twenty Years   总被引：1，自引：0，他引：1  

ZHANG Zhaozhi  JIANG Guangyu  WANG Xianwei  ZHANG Jianfeng 《《地质学报》英文版》2016,90(4):1370-1417

Bulk mineral resources of iron ores, copper ores, bauxite, lead ores, zinc ores and potassium salt play a pivotal role on the world’s and China’s economic development. This study analyzed and predicted their resources base and potential, development and utilization and their world’s and China’s supply and demand situation in the future 20 years. The supply and demand of these six bulk mineral products are generally balanced, with a slight surplus, which will guarantee the stability of the international mineral commodity market supply. The six mineral resources(especially iron ores and copper ores) are abundant and have a great potential, and their development and utilization scale will gradually increase. Till the end of 2014, the reserveproduction ratio of iron, copper, bauxite, lead, zinc ores and potassium salt was 95 years, 42 years, 100 years, 17 years, 37 years and 170 years, respectively. Except lead ores, the other five types all have reserve-production ratio exceeding 20 years, indicative of a high resources guarantee degree. If the utilization of recycled metals is counted in, the supply of the world’s six mineral products will exceed the demand in the future twenty years. In 2015–2035, the supply of iron ores, refined copper, primary aluminum, refined lead, zinc and potassium salt will exceed their demand by 0.4–0.7 billion tons(Gt), 5.0–6.0 million tons(Mt), 1.1–8.9 Mt, 1.0–2.0 Mt, 1.2–2.0 Mt and 4.8–5.6 Mt, respectively. It is predicted that there is no problem with the supply side of bulk mineral products such as iron ores, but local or structural shortage may occur because of geopolitics, monopoly control, resources nationalism and trade friction. Affected by China’s compressed industrialized development model, the demand of iron ores(crude steel), potassium salt, refined lead, refined copper, bauxite(primary aluminum) and zinc will gradually reach their peak in advance. The demand peak of iron ores(crude steel) will reach around 2015, 2016 for potassium salt, 2020 for refined lead, 2021 for bauxite(primary aluminum), 2022 for refined copper and 2023 for zinc. China’s demand for iron ores(crude steel), bauxite(primary aluminum) and zinc in the future 20 years will decline among the world’s demand, while that for refined copper, refined lead and potassium salt will slightly increase. The demand for bulk mineral products still remains high. In 2015–2035, China’s accumulative demand for iron ores(crude steel) will be 20.313 Gt(13.429 Gt), 0.304 Gt for refined copper, 2.466 Gt(0.616 Gt) of bauxite(primary aluminum), 0.102 Gt of refined lead, 0.138 Gt of zinc and 0.157 Gt of potassium salt, and they account for the world’s YOY(YOY) accumulative demand of 35.17%, 51.09%, 48.47%, 46.62%, 43.95% and 21.84%, respectively. This proportion is 49.40%, 102.52%, 87.44%, 105.65%, 93.62% and 106.49% of that in 2014, respectively. From the supply side of China’s bulk mineral resources, it is forecasted that the accumulative supply of primary(mine) mineral products in 2015–2035 is 4.046 Gt of iron ores, 0.591 Gt of copper,1.129 Gt of bauxite, 63.661 Mt of(mine) lead, 0.109 Gt of(mine) zinc and 0.128 Gt of potassium salt, which accounts for 8.82%, 13.92%, 26.67%, 47.09%, 33.04% and 15.56% of the world’s predicted YOY production, respectively. With the rapid increase in the smelting capacity of iron and steel and alumina, the rate of capacity utilization for crude steel, refined copper, alumina, primary aluminum and refined lead in 2014 was 72.13%, 83.63%, 74.45%, 70.76% and 72.22%, respectively. During 2000–2014, the rate of capacity utilization for China’s crude steel and refined copper showed a generally fluctuating decrease, which leads to an insufficient supply of primary mineral products. It is forecasted that the supply insufficiency of iron ores in 2015–2035 is 17.44 Gt, 0.245 Gt of copper in copper concentrates, 1.337 Gt of bauxite, 38.44 Mt of lead in lead concentrates and 29.19 Mt of zinc in zinc concentrates. China has gradually raised the utilization of recycled metals, which has mitigated the insufficient supply of primary metal products to some extent. It is forecasted that in 2015–2035 the accumulative utilization amount of steel scrap(iron ores) is 3.27 Gt(5.08 Gt), 70.312 Mt of recycled copper, 0.2 Gt of recycled aluminum, 48 Mt of recycled lead and 7.7 Mt of recycled zinc. The analysis on the supply and demand situation of China’s bulk mineral resources in 2015–2035 suggests that the supply-demand contradiction for these six types of mineral products will decrease, indicative of a generally declining external dependency. If the use of recycled metal amount is counted in, the external dependency of China’s iron, copper, bauxite, lead, zinc and potassium salt will be 79%, 65%, 26%, 8%, 16% and 18% in 2014, respectively. It is predicted that this external dependency will decrease to 62%, 64%, 20%,-0.93%, 16% and 14% in 2020, respectively, showing an overall decreasing trend. We propose the following suggestions correspondingly.(1) The demand peak of China’s crude steel and potassium salt will reach during 2015–2023 in succession. Mining transformation should be planned and deployed in advance to deal with the arrival of this demand peak.(2) The supply-demand contradiction of China’s bulk mineral resources will mitigate in the future 20 years, and the external dependency will decrease accordingly. It is suggested to adjust the mineral resources management policies according to different minerals and regions, and regulate the exploration and development activities.(3) China should further establish and improve the forced mechanism of resolving the smelting overcapacity of steel, refined copper, primary aluminum, lead and zinc to really achieve the goal of "reducing excess production capacity".(4) In accordance with the national strategic deployment of "One Belt One Road", China should encourage the excess capacity of steel, copper, alumina and primary aluminum enterprises to transfer to those countries or areas with abundant resources, high energy matching degree and relatively excellent infrastructure. Based on the national conditions, mining condition and geopolitics of the resources countries, we will gradually build steel, copper, aluminum and lead-zinc smelting bases, and potash processing and production bases, which will promote the excess capacity to transfer to the overseas orderly.(5) It is proposed to strengthen the planning and management of renewable resources recycling and to construct industrial base of renewable metal recycling.(6) China should promote the comprehensive development and utilization of paragenetic and associated mineral species to further improve the comprehensive utilization of bulk mineral resources.  相似文献