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51.
The Gulf of Finland lies in the eastern part of the Baltic Sea. The surface area is 29,700 km2 and the average depth of the basin is 38 m. Groundwater discharge to the Gulf of Finland equals 0.6 km3/year and this discharge is composed of many different chemical compounds. Groundwater discharge into the Gulf of Finland is dispersal. The coastal area of the Gulf of Finland can be divided into four zones with different geological, hydrogeological and discharge properties. The amount of direct groundwater discharge to the sea may be estimated using several geological and hydrogeological methods.  相似文献   
52.
ABSTRACT

We have identified two contrasting styles of Paleoproterozoic metamorphism in the northern part of the Fennoscandian Shield. The Karelia and Lapland-Kola Provinces, comprising Archean and overlying Paleoproterozoic supracrustal rocks, show a typical medium pressure Barrovian-style metamorphism with commonly found kyanite-bearing mineral assemblages and ITD (isothermal decompression) PT paths. In the juxtaposed Svecofennia Province metamorphism represents low pressure-high temperature Buchan style with garnet-cordierite migmatites and intercalated andalusite-cordierite and andalusite-staurolite schists and sillimanite-muscovite gneisses. The retrograde PT paths show only a moderate uplift during cooling.

U-Pb age determinations on monazite were made using the LA-ICP-MS from more than 80 samples from metasedimentary rocks. The sampling covered most parts of the Paleoproterozoic bedrock in Finland. The analyses reveal three peaks at c. 1.91 Ga, 1.86–1.88 Ga and at 1.79–1.81 Ga. The oldest, c. 1.91 Ga monazites are mostly found in the Lapland-Kola Province which is located in the northernmost Finland. In the Karelia Province where the Paleoproterozoic is underlain by Archean bedrock monazite yielded ages of 1.76?1.81 Ga with only a few older exceptions in samples showing a spread of 207Pb/206Pb ages from c. 1.92–1.81 Ga. The Karelia Province underwent tectonic thickening, where monazite ages of around 1.80 Ga mostly represent exhumation near the temperature maximum.

In the Svecofennia Province monazite ages vary from c. 1.89 to 1.78 Ga. In the Western Finland Subprovince the monazite ages in high-grade migmatites are mostly 1.86?1.88 Ga but within the older migmatite areas there are lower grade zones where monazite yields ages of c. 1.80 Ga. Some samples also show a spread of 207Pb/206Pb ages from 1.89?1.86 Ga to c. 1.78 Ga. In the Southern Finland Subprovince most ages are either 1.80?1.78 Ga, especially in the andalusite grade schists, or the sample shows a spread of 207Pb/206Pb ages from c. 1.88 to 1.78 Ga. Only in the eastern part of the Southern Finland Subprovince there are rocks which yield merely 1.86?1.89 Ga ages. Low pressure-high temperature metamorphism and lack of high or medium P/T rocks in the Svecofennia Province refers rather to accretionary than collisional processes.  相似文献   
53.
During May 2003 a swarm of 16 earthquakes (ML = 0.6–2.1) occurred at Anjalankoski, south-eastern Finland. The activity lasted for three weeks, but additional two events were observed at the same location in October 2004. A comparison of the waveforms indicated that the source mechanisms and the hypocentres of the events were nearly identical.A relative earthquake location method was applied to better define the geometry of the cluster and to identify the fault plane associated with the earthquakes. The relocated earthquakes aligned along an ENE–WSW trending zone, with a lateral extent of about 1.0 km by 0.8 km. The relative location and the waveform-modelling of depth sensitive surface wave (Rg) and S-to-P converted body wave (sP) phases indicated that the events were unusually shallow, most likely occurring within the first 2 km of the surface. The revised historical earthquake data confirm that shallow swarm-type seismicity is characteristic to the area.The focal mechanism obtained as a composite solution of the five strongest events corresponds to dip-slip motion along a nearly vertical fault plane (strike = 250°, dip = 80°, rake = 90°). The dip and strike of this nodal plane as well as the relocated hypocentres coincide with an internal intrusion boundary of the Vyborg rapakivi batholith.The events occur under a compressive local stress field, which is explained by large gravitational potential energy differences and ridge-push forces. Pore-pressure changes caused by intrusion of ground water and/or radon gas into the fracture zones are suggested to govern the swarm-type earthquake activity.  相似文献   
54.
The concentrations of chlorophyll-a (chl-a), total suspended solids (TSS) and the absorption coefficient of colored dissolved organic matter (aCDOM(400)) are estimated in Case II waters using medium resolution imaging spectrometer (MERIS) satellite (full resolution [FR] level 1b, 300 m resolution) and AISA airborne spectrometer data acquired during a spring bloom in the Gulf of Finland, Baltic Sea on April 27, 2004. The accuracy of the estimation is analyzed using empirical band-ratio algorithms together with in situ observations that include water samples analyzed in a laboratory (variation ranges: 22–130 μg/l, 2.9–20 mg/l, and 1.29–2.61 m−1 for chl-a, TSS and aCDOM(400), respectively). Additional in situ estimates (transects) on these characteristics are available through absorption and scattering coefficients measured with an ac-9 absorption and attenuation meter installed in a flow-through system. The retrieval accuracy (R2) of all three water quality characteristics with MERIS data is close to or above 0.9, while the RMSE is 7.8 μg/l (22%), 0.74 mg/l (16%) and 0.08 m−1 (5%), for chl-a, TSS and aCDOM(400), respectively. The validity of the chl-a algorithm is tested using nine additional data points. The BIAS-error for these points is 5.2 μg/l and the RMSE is 10.6 μg/l. The effects of changes in the atmospheric characteristics on band-ratio algorithms in cases where no concurrent in situ reference data are available are analyzed using the MODerate spectral resolution atmospheric TRANSmittance algorithm and computer model (MODTRAN). The additional error due to these changes is estimated to be below 20% for the applied ratio algorithms. The water quality data available in the level 2 MERIS-product distributed by the European Space Agency did not include valid results for the date investigated here.  相似文献   
55.
成曦晖  徐九华  张辉 《地质通报》2015,34(6):1119-1132
马斯塔瓦纳磁铁矿-钛铁矿床位于芬兰北部,属于芬诺斯堪迪亚地盾,辉长岩是主要的含矿岩体。矿石类型主要为钛磁铁矿,含矿岩石为含钛磁铁矿、钒钛磁铁矿辉长岩。浸染状矿石金属矿物以钛磁铁矿为主,次为钛铁矿。地球化学特征研究表明,马斯塔瓦纳矿床的Zr、Hf、U、Th在含矿辉长岩中含量非常稳定,均小于10×10-6,反映了岩浆成因的特征。由于马斯塔瓦纳矿床形成时构造环境不稳定,原始岩浆来不及长期彻底地分异,导致岩石的地球化学参数等均具有过渡特征。芬兰马斯塔瓦纳矿床的成岩成矿过程主要分为2个期次:成岩期(形成辉长岩体)和主成矿期(岩浆期形成铁矿)。初步研究表明,芬兰马斯塔瓦纳铁-钛-钒矿床与国内的"大庙式"和"攀西式"铁矿有所不同,2个国内矿床处于相对稳定的板内构造环境,而芬兰马斯塔瓦纳矿床产于特殊的造山带而非稳定的克拉通构造环境。  相似文献   
56.
The consequences of a coastal upwelling event on physical and chemical patterns were studied in the central Gulf of Finland. Weekly mapping of hydrographical and -chemical fields were carried out across the Gulf between Tallinn and Helsinki in July–August 2006. In each survey, vertical profiles of temperature and salinity were recorded at 27 stations and water samples for chemical analyses (PO43−, NO2+NO3) were collected at 14 stations along the transect. An ordinary distribution of hydrophysical and -chemical variables with the seasonal thermocline at the depths of 10–20 m was observed in the beginning of the measurements in July. Nutrient concentrations in the upper mixed layer were below the detection limit and nutriclines were located just below or in the lower part of the thermocline. In the first half of August, a very intense upwelling event occurred near the southern coast of the Gulf when waters with low temperature and high salinity from the intermediate layer surfaced. High nutrient concentrations were measured in the upwelled water – 0.4 μmol l−1 of phosphates and 0.6 μmol l−1 of nitrates+nitrites. We estimated the amount of nutrients transported into the surface layer as 238–290 tons of phosphorus (P)-PO43− and 175–255 tons of N-NOx for a 12 m thick, 20 km wide and 100 km long coastal stretch. Taking into account a characteristic along-shore extension of the upwelling of 200 km, the phosphate-phosphorus amount is approximately equal to the average total monthly riverine load of phosphorus to the Gulf of Finland. It is shown that TS-characteristics of water masses and vertical distribution of nutrients along the study transect experienced drastic changes caused by the upwelling event in the entire studied water column. TS-analysis of profiles obtained before and during the upwelling event suggests that while welled up, the cold intermediate layer water was mixed with the water from the upper mixed layer with a share of 85% and 15%. We suggest that the coastal upwelling events contribute remarkably to the vertical mixing of waters in the Gulf of Finland. Intrusions of nutrient-rich waters along the inclined isopycnal surfaces in the vicinity of upwelling front were revealed. The upwelling event widened the separation of phosphocline and nitracline which in turn prevented surfacing of nitrate+nitrite-nitrogen during the next upwelling event observed a week after the upwelling relaxation. A suggestion is made that such widening of nutricline separation caused by similar upwelling events in early summer could create favourable conditions for late summer cyanobacterial blooms.  相似文献   
57.
When modelling is used for investigating estuarine systems, a choice generally has to be made between applying simple mass-balance considerations or using a process-resolving three-dimensional (3-D) numerical circulation model. In the present investigation of the Gulf of Finland, a gradually mixed estuary in the Baltic Sea, it is demonstrated how Lagrangian-trajectory analysis applied to the output from a 3-D model minimizes the disadvantages associated with both of the modelling techniques referred to above. This formalism made it possible to demonstrate that the main part of the Gulf is dominated by water originating from the Baltic proper, and that the most pronounced mixing with fresh water from the river Neva takes place over a limited zone in the inner part of the Gulf. Dynamical insights were furthermore obtained by using the Lagrangian formalism to construct overturning stream-functions for the two source waters.  相似文献   
58.
59.
Compositional zoning in biotite–garnet pairs in metamorphic rocks from eastern Finland has been studied. The Mg profiles in the garnet side of biotite–garnet crystal pairs have been interpreted by means of Lasaga's theory (geospeedometry). However, the binary interdiffusion equations are first reformulated by starting from a ternary system and using the lattice fixed frame of reference. This frame of reference gives the fluxes directly by means of the numbers of diffusing ions, which helps to check the 1-dimensionality of the analysis assumed in Lasaga's theory. It is also shown that the recently argued effect of the third cation Ca is negligible in our samples. We were able to investigate satisfactory profiles in three samples from different areas. The values for the cooling rate are a few degrees per million years if the diffusion data obtained by Freer are adopted. The cooling rates are in agreement with recent estimates based on the K–Ar ages on biotite in the same areas.  相似文献   
60.
The paragenetic relationships between sillimanite, andalusite, kyanite, chlorite, cordierite, biotite, garnet and staurolite in the Early Proterozoic Puolankajärvi Formation (PjF), together with mineral compositions, are used to construct a partial petrogenetic grid for metapelites with significant Mn content (MnO = 0.1–0.5%) by adding a six-phase invariant point over the garnet-absent invariant point for Mn-free AMF-phases.
The grid and textural relations of the PjF are used to construct part of the P–T –deformation path for the PjF. Relatively short deformation pulses and associated flow of oxidizing fluid along shear zones were responsible for the paragenetic and compositional changes during cooling and decompression at 600–500°C and 6.0–2.5 kbar. Oxidation led to decreased Fe2+ and further stressed the importance of Mn (increased Mn/divalent cations).
A tectonothermal evolution of the Kainuu Schist Belt is presented which includes crustal thinning and steepening of a previously established thermal gradient. This was followed by thrusting and folding of the isotherms into a thermal antiform on the western side of the belt.  相似文献   
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