气相色谱法测试土壤中分段石油烃的标准化定量方法初探   总被引：2，自引：1，他引：1  

刘玉龙  黄燕高  刘菲 《岩矿测试》2019,38(1):102-111

目前土壤样品中分段石油烃的分析方法中石油烃包括的碳原子数范围和采用的校准物质不统一,造成不同实验室的量值不具有可比性。为保证不同实验室之间结果的可比性,本文尝试建立一种石油烃相邻碳原子数标准化定量方法。该方法主要包括:(1)规定了石油烃包括的碳原子数范围为气相色谱峰中正己烷和正四十碳烷之间所有的烃(含正己烷);(2)总石油烃(TPH)分为挥发性石油烃(VPH)和半挥发性石油烃(SPH),分别选取碳原子数为6～10的5个正构烷烃作为VPH校准物质,选取碳原子数为10～40的31个正构烷烃作为SPH校准物质。采用平均响应因子法或一次线性回归法,建立校准物质的峰面积-浓度的校准关系;(3)采用相邻峰标准化校准方法,逐一定量所有的目标色谱峰;(4)计算正构烷烃含量、总石油烃含量和任意分段的石油烃含量。该方法为环境样品中石油烃分析方法的标准化建设提供了数据基础。  相似文献   

气袋采样法对还原硫化物测定的影响因素分析及机理研究     

孟洁  翟增秀  刘英会  张君  韩萌 《岩矿测试》2019,38(2):179-185

还原硫化物是一Z类典型的恶臭物质,其特点是活性高、不易储存,因此适宜的储存条件对还原硫化物的准确测定具有重要意义。本文使用气相色谱-质谱联用技术,从气袋材质、还原硫化物初始浓度、还原硫化物性质和储存时间四个因素探究袋采样法储存还原硫化物过程的损失情况。以Tedlar~? PVF和Teflon~? FEP为目标采样袋,使用5个初始浓度(0. 001、0. 010、0. 100、1. 000和10. 000μg/m L)的混合还原硫化物,选择0、2、6、12、24、48以及72h的储存时间,以响应因子和相对回收率作为评价因子,并使用配对t检验法和吸附动力学,研究影响储存效果的主要因素、物质损失机理以及两种采样袋的储存能力。结果表明,储存时间越长、物质初始浓度越高,物质活性越强,损失情况越严重;在环境温度达到60℃时,Tedlar~? PVF的基质背景较Teflon~? FEP更复杂;相同条件下,还原硫化物在Teflon~? FEP储存过程中损失更严重。依据研究结果建议:(1)样品采集后避光保存;(2)低浓度含硫样品的测定在采样后8h内完成,高浓度含硫样品的测定在2h内完成;(3)若待测样品气体温度较高,优先选择Teflon~? FEP采样袋,气体温度较低条件下选择Tedlar~? PVF采样袋,可最大限度保持样品的原始状态。本研究成果有利于确保还原硫化物样品的储存稳定性,最大限度还原恶臭污染现场情况,为恶臭污染的分析测试以及后续的恶臭污染控制与治理提供技术支持。  相似文献   

奥陶系岩溶古地貌恢复及对气藏分布的控制作用——以鄂尔多斯盆地苏里格东区41-33区块为例     

刘逍  王静  金大权  陈海涌  段新国  曹晶晶  刘正元 《矿物岩石》2019,39(3):95-110

苏东41-33区块位于鄂尔多斯盆地中央古隆起的北部南缘,长期沉积间断的风化壳不整合面形成复杂的岩溶古地貌,属苏里格气田东部奥陶系碳酸盐岩气藏的重要勘探区。研究基于钻井、测井、地震及生产动态资料分析,综合运用地球物理法、残厚法和印模法,优选本溪组顶9号煤层和马家沟组马五5灰岩为标志层,深入探讨古地貌单元的恢复依据和划分标准,精细恢复岩溶古地貌形态,并明确岩溶古地貌特征及其对气藏分布的影响。研究表明:苏东41-33区块整体处于二级地貌单元岩溶斜坡之上,奥陶系古风化壳上下地层厚度可划分出上薄下薄、上薄下厚、上厚下薄等5种组合类型,细分古坡地、残丘和沟槽3个三级地貌单元;古地貌总体趋势走向为北高南低,出露层位展布由马五4过渡到马五1。中南部发育连片残丘,北部见小型零星残丘,恢复厚度低于15m,残留厚度超过85m;北部发育2条侵蚀沟槽带,充填厚度大于20m,残留厚度小于45m;古坡地分布范围广泛,周围被古残丘与沟槽所分割,残留厚度介于45m^85m之间,恢复厚度大于10m。古地貌类型对风化壳气藏分布具有明显的控制作用,岩溶残丘及残丘边缘带的古坡地储层叠合厚度增大,溶蚀孔洞充填程度低,主力含气层保存完整且连通性较好,是寻找高产井的目标区,而岩溶古沟槽相对不利于天然气富集,所钻遇气井多为低产或无产能。  相似文献   

扬子地块北缘新元古代望江山层状岩体矿物成分和铂族元素特征:对岩浆演化过程和构造环境的制约   总被引：1，自引：1，他引：0  

王岩  王梦玺  焦建刚 《地质力学学报》2019,25(2):267-285

望江山层状岩体位于扬子地块北缘新元古代汉南杂岩带中,岩体从底部到顶部由超镁铁质岩过渡为中性岩:底部主要由辉石岩和橄长岩组成;中部为辉长苏长岩和辉长岩;上部为辉长岩和闪长岩。研究以中部岩相带橄榄辉长苏长岩、辉长苏长岩和辉长岩为对象,通过主要矿物的主微量元素和全岩主微量元素的分析,查明望江山岩体来源于尖晶石二辉橄榄岩组成的大陆下岩石圈地幔,并且地幔源区受到了来自俯冲板片流体的交代,岩体中部带的母岩浆为拉斑玄武质岩浆。钛铁矿—磁铁矿矿物对成分计算表明,母岩浆在形成时具有较高氧逸度。通过单斜辉石压力计得到岩体的侵位深度约为12.9~18 km。对岩体母岩浆橄榄石分离结晶过程的模拟计算表明,中部带橄榄石为母岩浆经过~28%分离结晶的产物。此外,铂族元素（PGE）组成暗示岩体并未经历过大规模的硫化物熔离,可能与缺乏地壳物质混染有关。岩体中单斜辉石与岛弧环境堆晶岩中单斜辉石成分相似,不同于裂谷环境中堆晶单斜辉石的成分;同时,全岩Th/Yb和Nb/Yb比值也与岛弧玄武岩比值相似,因此矿物和全岩成分均说明望江山层状岩体应形成于岛弧环境。研究认为扬子北缘在新元古代长期的俯冲过程中,大洋板片断离导致软流圈上涌,提供热源使交代大陆下岩石圈地幔部分熔融形成具有岛弧特征的镁铁质岩浆,在局部伸展环境中上升侵位形成汉南杂岩带中镁铁—超镁铁质层状岩体。   相似文献   

Unraveling the multi-scalar residential segregation and socio-spatial differentiation in China: A comparative study based on Nanjing and Hangzhou   总被引：1，自引：0，他引：1  

SONG Weixuan  HUANG Qinshi  GU Yue  HE Ge 《地理学报(英文版)》2021,31(12):1757-1774

Residential segregation is a dual process of socio-spatial differentiation in residents and spatio-temporal heterogeneity in dwelling.However,most of the existing studies are es-tablished from the single perspective of urban residents based on demographic data,which is difficult to reveal the dynamics and complex spatial reconstruction within and between cities.With the characteristics of both stability and timeliness,the rapidly changing housing market is one of the processes and results of socio-spatial reconfiguration,and it is undoubtedly a better lens to observe residential segregation.This paper adopts methods such as multi-group segregation index,multi-scalar segregation profiles,and decomposition of segregation index,with Nanjing and Hangzhou as case cities,and establishes multi-scalar segregation profiles and comparative models based on three geographical scales of census tract,block and grid,and different residential types.A quantitative study was conducted on the degree and pattern of multi-scalar residential segregation in Nanjing and Hangzhou from 2009 to 2018.The pa-per found that the spatial segregation index is an improvement of the non-spatial segregation index.There are differences between Nanjing and Hangzhou in the evolution process of residential segregation.Nanjing has a higher degree of spatial differentiation as a whole,among which spatial components have a more significant impact.  相似文献   

非户籍与户籍人口居住空间分异的多维度解析——以深圳为例   总被引：4，自引：3，他引：1  

张瑜  仝德  IanMacLACHLAN 《地理研究》2018,37(12):2567-2575

在居住空间相异指数基础上,构建了集聚—分散度、中心—边缘度和极化—均质度指数,进一步挖掘由于人口聚居形态、居住区位和居住质量等方面差异导致的居住空间分异的多维内涵,及其所揭示出的社会经济空间现象、成因及空间治理重点。利用全国第六次人口普查数据开展深圳实证研究,在计算全市及各区分维指数的基础上,分析深圳人口居住空间相异指数特征及空间尺度差异,多维居住空间分异格局特征及成因,并通过聚类分析将深圳非户籍与户籍人口居住空间分异类型划分为三类,分类提出空间治理政策建议。从而为深入理解中国大城市日益出现的居住分异现象及机制提供新鲜视角和多样化测度方法,为解决其带来的社会及空间治理问题提供更有针对性的政策建议。  相似文献   

What can we learn about changing ethnic diversity from the distributions of mixed-race individuals?     

William A. V. Clark  Eva K. Andersson  Bo Malmberg 《Urban geography》2018,39(2):263-281

It is hypothesized that self-defined mixed-race persons live in residentially mixed areas in the largest metropolitan areas in California. The hypothesis is tested by examining the distribution of mixed-race persons among ethnically and racially diverse and nondiverse neighborhoods in the San Francisco and Los Angeles Metropolitan Areas. The research confirmed that mixed-race individuals are more likely to live in areas with ethnic diversity and that the tendency is greater for the mixed-race population in the San Francisco–Oakland Metropolitan Areas than in the Los Angeles Metropolitan Area. Mixed-race individuals live in neighborhoods which are diverse with mixes of all four major ethnic and racial groups, and in “well-off” (but not the most affluent) neighborhoods. The study also shows that the mixed-race population is youthful. The association of mixed-race individuals and racially integrated neighborhoods will have important implications for the evolving nature of spatial integration in California specifically, and the United States more generally.  相似文献   

Subterranean microorganisms and radioactive waste disposal in Sweden   总被引：2，自引：0，他引：2  

Karsten Pedersen   《Engineering Geology》1999,52(3-4):163-176

In 1987, microbiology became a part of the Swedish scientific program for the safe disposal of high level nuclear waste (HLW). The goal of the microbiology program is to understand how subterranean microorganisms will interact with the performance of a future HLW repository. The Swedish research program on subterranean microbiology has mainly been performed at two sites in granitic rock aquifers at depths ranging from 70 m down to 1240 m, the Stripa research mine in the middle of Sweden and the Äspö Hard Rock Laboratory (HRL) situated on the south eastern coast of Sweden. Some work has also been performed in cooperation with other national or international research groups in Sweden, Canada and at the natural analogue sites Oklo in Gabon and Maqarin in Jordan. The following conclusions are drawn. There is a very high probability of the existence of a deep subterranean biosphere in granitic rock. The documented presence of a deep biosphere implies that relevant microbial reactions should be included in the performance assessment for a HLW repository. A HLW repository will be situated in a subterranean biosphere that is independent of solar energy and photosynthetically produced organic carbon. The ultimate limitation for an active microbial life will be the availability of hydrogen as energy source over time, and hydrogen has indeed been found in most deep groundwaters. Sulphide producing microorganisms are active in environments typical for a Swedish HLW repository, and the potential for microbial corrosion of the copper canisters must be considered. The bentonite buffer around the copper canisters will be a hostile environment for most microbes due to the combination of radiation, heat and low water availability. Discrete microbial species can cope with each of these constraints, and it is theoretically possible that sulphide producing microbes may be active inside a buffer, although the experiments conducted thus far have shown the opposite. Microorganisms have the capability to enzymatically recombine radiolysis oxidants formed by radiation of water. It has earlier been concluded that the migration of radionuclides due to sorption on microorganisms can be neglected. The influence of microbially produced complexing agents remains to be studied at realistic conditions in deep groundwater. Microorganisms have been found in natural alkaline groundwaters, but it could not be conclusively demonstrated that they were in situ viable and growing, rather than just transported there from neutral groundwater. A possible hypothesis based on the obtained results from investigations of natural alkaline groundwaters is that fresh concrete may be a bit too extreme for active life even for the most adaptable microbe – but this remains to be demonstrated.  相似文献   

岩浆型Cu-Ni-PGE硫化物矿床研究的几个问题探讨   总被引：10，自引：3，他引：7  

柴凤梅  张招崇  毛景文  董连慧  张作衡 《矿床地质》2005,24(3):325-335

文章简述了岩浆型Cu—Ni—PGE硫化物矿床的主要特点和研究现状,探讨了矿床的成矿机制,认为其成矿的首要条件是岩浆中硫达到饱和而使硅酸盐岩浆与硫化物熔体发生熔离。综述了如何利用同位素方法确定其成矿物质来源,介绍了如何判别硫饱和度的方法。  相似文献   

南海北部琼东南海域活动冷泉特征及形成模式   总被引：3，自引：0，他引：3       下载免费PDF全文

杨力  刘斌  徐梦婕  刘胜旋  关永贤  顾元 《地球物理学报》2018,61(7):2905-2914

近年来,活动冷泉的研究越来越受到关注.本文利用多波束数据、多道地震数据以及底质取样结果研究琼东南海域活动冷泉系统,分析活动冷泉的羽状流特征、海底地貌与底质特征以及流体活动构造特征.多波束水体数据上,观测到多个延伸高度超过750 m的气泡羽状流,海底流体活动非常强烈;多道地震上识别出麻坑、流体运移通道、气烟囱等流体渗漏相关的构造,与其他海域观测到的反射特征不同,羽状流的下方流体运移通道呈强振幅"串珠"反射;重力活塞取样在两个站位上获得浅表层块状天然气水合物.其中一个站位位于活动冷泉附近,天然气水合物赋存于海底以下8 m左右.基于以上三方面的数据,笔者提出了一个用于描述活动冷泉系统的形成模式,游离气通过气烟囱向上运移到达浅层,一部分在天然气水合物稳定带内形成天然气水合物,另一部分穿透天然气水合物稳定带到达海底,形成活动冷泉的羽状流.  相似文献