古新世—始新世最热事件对地球表层循环的影响及其触发机制   总被引：1，自引：0，他引：1  

赵玉龙  刘志飞 《地球科学进展》2007,22(4):341-349

古新世—始新世最热事件（PETM, Paleocene Eocene Thermal Maximum）是发生在古新世—始新世交界时的一次全球性的气候突变事件。它造成了大洋环流模式的突然倒转和海水盐度、大气湿度的迅速上升。海洋表层生态系统和陆地生态系统生产力迅速上升,许多属种的植物、动物、微生物生活范围向高纬区扩大;大洋底栖微生物发生集群灭绝。现代哺乳动物的主要属种（灵长类、奇蹄类及偶蹄类）产生,哺乳动物演化进程发生重大改变。地球表层碳循环系统发生不同程度的碳同位素负偏移,全球碳循环系统发生大规模搅动。对于PETM的触发机制,主流的观点认为是海底天然气水合物突然释放造成巨量甲烷迅速进入表层系统引发的碳循环系统内部反馈。而对于甲烷释放的原因,又存在着减压释放和热释放两种解释;此外还有科学家用岩浆作用和地外星体撞击来解释PETM的发生。  相似文献   

Gas generation and expulsion characteristics of Middle–Upper Triassic source rocks,eastern Kuqa Depression,Tarim Basin,China: implications for shale gas resource potential     

P. Wang  X. Chen  J. Li  H. Yang  F. Jiang 《Australian Journal of Earth Sciences》2013,60(7):1001-1013

Frontier exploration in the Kuqa Depression, western China, has identified the continuous tight-sand gas accumulation in the Lower Cretaceous and Lower Jurassic as a major unconventional gas pool. However, assessment of the shale gas resource in the Kuqa Depression is new. The shale succession in the Middle–Upper Triassic comprises the Taliqike Formation (T₃t), the Huangshanjie Formation (T₃h) and the middle–upper Karamay Formation (T_2–3k), with an average accumulated thickness of 260 m. The high-quality shale is dominated by type III kerogen with high maturity and an average original total organic carbon (TOC) of about 2.68 wt%. An improved hydrocarbon generation and expulsion model was applied to this self-contained source–reservoir system to reveal the gas generation and expulsion (intensity, efficiency and volume) characteristics of Middle–Upper Triassic source rocks. The maximum volume of shale gas in the source rocks was obtained by determining the difference between generation and expulsion volumes. The results indicate that source rocks reached the hydrocarbon expulsion threshold of 1.1% VR and the hydrocarbon generation and expulsion reached their peak at 1.0% VR and 1.28% VR, with the maximum rate of 56 mg HC/0.1% TOC and 62.8 mg HC/0.1% TOC, respectively. The volumes of gas generation and expulsion from Middle–Upper Triassic source rocks were 12.02 × 10¹² m³ and 5.98 × 10¹² m³, respectively, with the residual volume of 6.04 × 10¹² m³, giving an average gas expulsion efficiency of 44.38% and retention efficiency of 55.62%. Based on the gas generation and expulsion characteristics, the predicted shale gas potential volume is 6.04 × 10¹² m³, indicating a significant shale gas resource in the Middle–Upper Triassic in the eastern Kuqa Depression.  相似文献   

聚四氟乙烯平板型气态膜回收淡盐水中氯气          下载免费PDF全文

于伯杉 《盐湖研究》1993,1(4):75-79

本文以离子膜电解氯化钾制取碳酸钾工艺产生的淡盐水为原料,系统地研究了聚四氟乙烯平板型气态膜回收氯过程中膜性能和次氯酸钠水溶液的制备。初步研究表明,次氯酸钠含量大于100g/L,氢氧化钠有效利用率为90％;聚四氟乙烯膜有传质快、对离子截留性能好、使用寿命长等优点,在工业上有较好的应用前景。  相似文献   

Meteorology and haze structure during AGASP-II,Part 1: Alaskan Arctic flights, 2–10 April 1986     

G. A. Herbert  R. C. Schnell  H. A. Bridgman  B. A. Bodhaine  S. J. Oltmans  G. E. Shaw 《Journal of Atmospheric Chemistry》1989,9(1-3):17-48

The second Arctic Gas and Aerosol Sampling Program (AGASP-II) was conducted across the Alaskan and Canadian Arctic in April 1986, to study the in situ aerosol, and the chemical and optical properties of Arctic haze. The NOAA WP-3D aircraft, with special instrumentation added, made six flights during AGASP-II. Measurements of wind, pressure, temperature, ozone, water vapor, condensation nuclei (CN) concentration, and aerosol scattering extinction (b_sp) were used to determine the location of significant haze layers. The measurements made on the first three flights, over the Arctic Ocean north of Barrow and over the Beaufort Sea north of Barter Island, Alaska are discussed in detail in this report of the first phase of AGASP II. In the Alaskan Arctic the WP-3D detected a large and persistent region of haze between 960 and 750 mb, in a thermally stable layer, on 2, 8, and 9 April 1986. At its most dense, the haze contained CN concentrations >10,000 cm^–3 and b_sp of 80×10^–6 m^–1 suggesting active SO₂ to H₂SO₄ gas-to-particle conversion. Calculations based upon observed SO₂ concentrations and ambient relative humidities suggest that 10⁴–10⁵ small H₂SO₄ droplets could have been produced in the haze layers. High concentrations of sub-micron H₂SO₄ droplets were collected in haze. Ozone concentrations were 5–10 ppb higher in the haze layers than in the surrounding troposphere. Outside the regions of haze, CN concentrations ranged from 100 to 400 cm^–3 and b_sp values were about (20–40)×10^–6 m^–1. Air mass trajectories were computed to depict the air flow upwind of regions in which haze was observed. In two cases the back trajectories and ground measurements suggested the source to be in central Europe.  相似文献   

Structures caused by repeated freezing and thawing in various loamy sediments: A comparison of active,fossil and experimental data     

Brigitte Van Vliet-Lanoë  Jean-Pierre Coutard  Albert Pissart 《地球表面变化过程与地形》1984,9(6):553-565

In this paper, the authors present the results of both macroscopic and microscopic investigations on structure development created by repeated ice lensing in various loamy experiments. Experimental data are compared with observations performed on active forms in High Arctic and Alpine Mountain environments. Those observations are also compared with phenomena observed in fossil periglacial formations of Western Europe. Platy and short prismatic structure formation is bonded to the hydraulic and thermal conditions during ice segregation. When a long series of alternating freezing and thawing affects platy structures, the fabric evolves, also being influenced by slope and drainage conditions: cryoturbations, frostcreep, and gelifluction can appear. They are characterized by specific microfabrics which are better developed with an increasing number of cycles: this is clear in experiments where hydraulic and thermal parameters are better controlled. Vesicles are also a prominent characteristic of the surface horizon in experiments and arctic soils. The genesis of vesicles is discussed on the basis of new observations and is related to the mechanical collapse of frost-created aggregates under the mechanical work of soil air escape during soil saturation by water at thaw.  相似文献   

Determination of nitrophenols,diaminotoluenes, and chloroaromatics in ammunition wastewater     

P. Mußmann  R. Eisert  K. Levsen  G. Wünsch 《洁净——土壤、空气、水》1995,23(1):13-19

Methods for the determination of three compound classes, i. e. diaminotoluenes, nitrophenols, and chloroaromatics in groundwater of a former ammunition plant are reported. Diaminotoluenes were extracted by discontinuous liquid/liquid-, nitrophenols by continuous liquid/liquid-extraction using dichloromethane, and chloroaromatics by solid-phase extraction. These compound classes may be analyzed by gas chromatography (GC) or gas chromatography coupled to mass spectrometry (GC/MS) without derivatization or after derivatization with N-methyl-bis(trifluoroacetamide) (MBTFA) or heptafluorobutyric anhydride (HFBA) in the case of diaminotoluenes and HFBA or acetic anhydride in the case of nitrophenols. An atomic emission detector (AED) coupled to a gas chromatograph may be employed for the analysis of chloroaromatics. High selectivity can be achieved using the characteristic wavelengths of chlorine. A variety of these compounds were identified and quantified in a groundwater sample from the former ammunition plant Elsnig (Saxony, Germany). Concentrations were in the lower ppb range. Thus, dichlorobenzenes which may have been used as substituents at the end of World War II could be identified in groundwater samples at this site.  相似文献   

Direct and Indirect pCO2 Measurements in a Wide Range of pCO2 and Salinity Values (The Scheldt Estuary)     

Michel Frankignoulle  Alberto Vieira Borges 《Aquatic Geochemistry》2001,7(4):267-273

Recent improvements in both Infra-red spectroscopy and equilibrator techniqueshave allowed to determine, for the first time, pCO₂using simultaneously and continuously both the direct and indirect methods in an estuary where pCO₂ values range from 500 to 8500 atm and salinity from 0 to 30. Our results show that both methods are in excellent agreement in the wholeestuary (r² = 0.999, n = 1075, p < 0.0001). Thus, the NBS (US National Bureau of Standards) scale, although inadequate for seawater samples, is appropriate for estuarine waters and can be applied with confidence to calculate pCO₂.  相似文献   

加油站的雷电防护设计   总被引：7，自引：1，他引：7  

王伟良何灏  毛传泰 《广西气象》2005,26(4):40-42,62

通过对加油站所处环境特点、系统特点中雷电灾害各因素的分析，对加油棚、油罐及附属建筑的直击雷防护和接地，加油站电源、信号系统的雷电系统防护和静电防护等，依据GB50057、IEC61312、GB50156—2002标准对雷电防护的要求，提出了系统的解决方案。  相似文献   

沉积物粒度对水合物形成的制约：来自IODP 311航次证据   总被引：1，自引：0，他引：1  

王家生  高钰涯  李清  杨翠萍  陈祈  魏清  王晓芹  胡高伟 《地球科学进展》2007,22(7):659-665

对取自IODP 311航次（东北太平洋Cascadia大陆边缘）所有5个站位、采样间距约为1.5 m的614件沉积物样品，利用Beckman Coulter LS 230激光粒度仪进行了沉积物粒度分析，获得了沉积物粒度随深度变化特征，进而与水合物层位的替代指标进行了位置对比，这些指标包括特殊沉积构造（soupy和mousse like构造）、测井数据（LWD）推算出来的水合物饱和度（Sh）、岩芯红外图像和实际钻取的含水合物沉积物等。发现沉积物粒度分别为31~63 μm和63~125 μm的2组较粗粒径的沉积物数量变化增多的位置与水合物出现层位之间存在较好的位置对应关系。如在U1326站位海底以下5~8 m、21~26 m、50~123 m、132~140 m、167~180 m、195~206 m、220~240 m深度位置出现了沉积物粒度明显偏向粗粒的趋势，而这些位置正好对应于大多数特殊沉积构造出现的深度，也对应于水合物饱和度（Sh）值相对较高的深度，并与一些实际钻取的赋含水合物的浊积沙层观察结果一致。因此，初步研究后认为，沉积物粒度在水合物形成过程中扮演了重要角色，天然气水合物可能偏向形成于粒度大于31 μm的粗粒沉积物中。    相似文献   

Slab dehydration and fluid migration at the base of the upper mantle: implications for deep earthquake mechanisms     

Guillaume Richard  Marc Monnereau  Michel Rabinowicz 《Geophysical Journal International》2007,168(3):1291-1304

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