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重金属锌,铅对菲律宾蛤仔的急性毒性试验 总被引:14,自引:1,他引:14
本文研究了必需元素Zn及非必需元素Pb对菲律宾蛤仔的急性毒性作用,得到Zn对其的48hLD50和96hLD50分别为147.91、16.40mg/dm^3;Pb对其的48hLD50和96hLD50分别为31.62、14.28mg/dm^3。估算得到Zn、Pb对菲律宾蛤仔的安全浓度分别为0.82、0.71mg/dm^3。 相似文献
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Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins 总被引:1,自引:0,他引:1
Raffaela Biesuz Giancarla Alberti Girolamo D'Agostino Emanuele Magi Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189
The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log αM(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 1020 M− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log αM(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations. 相似文献
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由吡喹酮和克螨特组成的复配制剂对小球藻、轮虫、蚤状溞、水蚯蚓和卤虫的毒性实验结果显示:复配制剂对轮虫的半致死浓度(LC50)为13.9mg/dm^3(24h)和3.03mg/dm^3(48h).安全浓度(SC)为0.0432mg/dm^3;对蚤状溞的LC50为345.14mg/dm^3(24h)和17.5mg/dm^3(48h),SC为0.0135mg/dm^3;对水蚯蚓的LC50为636.80mg/dm^3(24h)和79.07mg/dm^3(48h),SC为0.366mg/dm^3;对卤虫无节幼虫的LC50为201.84mg/dm^3(24h)和8.91mg/dm^3(48h).SC为0.00519mg/dm^3,复配制剂对水环境生物的破坏作用小. 相似文献
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Alessandro Buccolieri Giovanni Buccolieri Nicola Cardellicchio Angelo Dell'Atti Antonella Di Leo Antonella Maci 《Marine Chemistry》2006,99(1-4):227
Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments. 相似文献
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Previous studies have shown that metal partitioned to a subcellular compartment containing trophically available metal (TAM) is readily available to predators and may be enhanced by increased binding of metal to heat-stable proteins (HSP - e.g., metallothioneins). The aim of the current investigation was to determine the influence of TAM on the trophic transfer of Cd along an experimental, three-level food chain: Artemia franciscana (brine shrimp)-->Palaemonetes pugio (grass shrimp)-->Fundulus heteroclitus (mummichog). P. pugio were fed for 7 days on A. franciscana exposed to Cd in solution (including (109)Cd as radiotracer) and subjected to subcellular fractionation or fed to F. heteroclitus. An HSP-driven increase in the percentage of Cd associated with TAM (TAM-Cd%) in A. franciscana exposed to 1 muM Cd resulted in a bioenhancement (i.e., a greater than linear increase with respect to A. franciscana exposure) of Cd trophic transfer to P. pugio. Increased dietary Cd exposure did not affect TAM-Cd% in P. pugio nor trophic transfer to F. heteroclitus. 相似文献
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山西能源重化工基地建设关系到全国四个现代化的实现,被列为国家重点建设工程,制定了《山西能源重化工基地综合规划》。本文分析了80年代山西省经济建设的成就与问题。提出了“整体创新,综合开发”,把山西能源重化工基地建设成内陆经济开放区的战略大思路,为此,90年代应完成11项大型经济战略工程,同时展望了经济发展改革前景。 相似文献