海水中溶解态铁的伏安极谱法与液芯波导光纤法测定     

龙爱民  党爱翠  程远月  陈绍勇 《海洋学报》2009,31(1):152-158

尽管铁为地壳中丰度位居第4的元素,但它在海水中的浓度却很低,浓度一般为0.05~2.0 nmd/dm3[1]。近年来,国内外的海洋科学家在进行海洋生态系统初级生产力、碳循环等重要生态过程及其对全球气候变化影响的研究中发现,海洋中的铁对浮游植物的生长、初级生产力的水平有着十分重要的影响甚至成为了“限制性因子”,在多个“高营养盐、低叶绿素(HNLC)”海区所实施的富铁实验的结果很好地印证了铁元素在海洋生态系统中的重要作用[2]。最新的研究成果表明近岸海水中的铁可能对浮游植物的种类组成起到决定性的作用,进而对包括氮、磷、硅在内的其他元素的生物地球化学行为产生深远的影响[3]。  相似文献   

液相色谱法测定湖泊沉积物中单质硫   总被引：2，自引：0，他引：2  

赵由之  梁小兵  安宁  魏中青  王明义 《矿物学报》2006,26(1):29-32

研究了液相色谱法测定湖泊沉积物中单质硫的可行性。以甲醇作为溶剂,将沉积物中单质硫转入甲醇相中,利用液相色谱C18柱分离,254 nm紫外检测,得到了很好的结果:单质硫标准曲线的线性相关系数r=0.9999,样品的回收率为94.8%~104.1%,单质硫溶液的检出限0.07 mg/L,测定下限0.3 mg/L,平行样品相对标准偏差6.5‰。该方法的优点是样品的前处理简单,检测方便、快捷,干扰少,重复性好。  相似文献   

飞机试飞的自然结冰潜势预测及检验评估          下载免费PDF全文

倪洪波  李佰平  闫文辉  李静  张莹  张华  倪萍 《气象科技》2022,50(2):254-266

自然结冰试飞是运输类飞机合格审定必须实施的高难度、高风险试飞科目，需要在环境温度、云中液态水含量（LWC）和云滴中值体积直径（MVD）满足条件，含有大量过冷水的环境中完成规定的飞行动作。利用2020年3月16日、26日及27日阎良机场国产某大型运输机自然结冰试飞的地面、高空、卫星、雷达和机载探测等多源观测资料，对3次自然结冰试飞气象条件进行了对比分析，并验证了李佰平等改进的自然结冰潜势算法有效性。结果表明：改进的自然结冰潜势算法对于结冰区域的预报较为准确，但在结冰强度预报上需进一步优化。西风系统因水汽条件不足，结冰气象条件较南支系统要差。高空冷空气未到达试飞区域前，云中环境温度偏高，结冰强度较弱；冷暖空气交汇的区域，LWC较高，MVD较为合适，结冰较强。研究结果对未来在阎良机场开展运输类飞机自然结冰试飞的窗口期和空域选择、协同指挥保障均具有参考意义。  相似文献   

钙钛矿及类钙钛矿结构物相的若干规律性 第三部分:钾冰晶石型化合物的结晶化学规律          下载免费PDF全文

陆文聪  刘亮  包新华  陈念贻 《盐湖研究》2003,11(1):1-3

钾冰晶石结构的三元卤化物包括一大批三元熔盐相图的中间相 ,是功能材料的开发对象。我们用原子参数—模式识别方法建立钾冰晶石结构形成条件和晶胞常数计算的数学模型。除容许因子t外 ,阴阳离子半径比和电负性差也是决定钾冰晶石结构形成的必要条件。  相似文献   

Chronology of Early to Mid-Pleistocene sediments in the northern North Sea: New evidence from amino acid and strontium isotope analyses     

《Quaternary Geochronology》2022

Sediments deposited during glacial-interglacial cycles through the Early to Mid-Pleistocene in the North Sea are chronologically poorly constrained. To contribute to the chronology of these units, amino acid racemization (AAR) and strontium (Sr) isotope analyses have been performed on samples from four shallow borings and one oil well along a transect in the northern North Sea. D/L Asp (aspartic acid) values obtained through reverse-phase liquid chromatography in the benthic foraminiferal species Elphidium excavatum is focused on because of consistent results and a good stratigraphic distribution of this benthic species. For the Early Pleistocene, an age model for the well 16/1–8, from the central part of the northern North Sea based on Sr ages allows for dating of the prograding wedges filling the pre-Quaternary central basin. A regional calibration curve for the racemization of Asp in Elphidium excavatum is developed using published ages of radiocarbon-dated samples and samples associated with the previously identified Bruhnes/Matuyama (B/M) paleomagnetic boundary and a Sr age from this study. Based on all the available geochronological evidence, samples were assigned to marine oxygen isotope stages (MIS) with uncertainties on the order of 10–70 ka.Sr ages suggest a hiatus of <2 million years (Ma) possibly due to non-deposition or low sedimentation between the Utsira Formation (Pliocene) and the Early Pleistocene. An increase in sedimentation rates around 1.5 ± 0.07 Ma (∼MIS 51) may partly be due to sediment supply from rivers from the south-east and partly due to the extension of ice sheet around 1.36 ± 0.07 Ma from the Norwegian coast to the central North Sea. A possible basin-wide glaciation occurred around 1.1 Ma (∼ MIS 32) (upper regional unconformity/top of unit Q4 in this study), resulting in erosion and regional unconformity. Two interglacials in the Norwegian Channel have been dated: the Radøy Interglacial to 1.07 ± 0.01 Ma (possibly MIS 31, the ‘super interglacial’), and the Norwegian Trench Interglacial to 0.50 ± 0.02 Ma (possibly MIS 13). A massive till unit identified at the same stratigraphic level in all shallow borings may partly represent an extensive MIS 12 glaciation. This study shows that the combined use of amino acid racemization data and Sr isotope chronology can refine the chronological ambiguities of Quaternary North Sea sediments related partly to the impact of glacial processes.  相似文献