Effect of ultraviolet and visible radiation on iron lability in boreal and artificial waters     

Nadia Kelton  Lewis A. Molot  Peter J. Dillon 《Aquatic Sciences - Research Across Boundaries》2007,69(1):86-95

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Regional-scale Proterozoic IOCG-mineralized breccia systems: examples from the Wernecke Mountains, Yukon, Canada   总被引：1，自引：0，他引：1  

Julie Hunt  Tim Baker  Derek Thorkelson 《Mineralium Deposita》2005,40(5):492-514

A large scale Proterozoic breccia system consisting of numerous individual breccia bodies, collectively known as Wernecke Breccia, occurs in north-central Yukon Territory, Canada. Breccias cut Early Proterozoic Wernecke Supergroup sedimentary rocks and occur throughout the approximately 13 km thick deformed and weakly metamorphosed sequence. Iron oxide–copper–gold ± uranium ± cobalt mineralization is associated with the breccia bodies and occurs as veins and disseminations within breccia and surrounding rocks and locally forms the breccia matrix. Extensive sodic and potassic metasomatic alteration occurs within and around breccia bodies and is overprinted by pervasive calcite and dolomite/ankerite, and locally siderite, alteration, respectively. Multiple phases of brecciation, alteration and mineralization are evident. Breccia bodies are spatially associated with regional-scale faults and breccia emplacement made use of pre-existing crustal weaknesses and permeable zones. New evidence indicates the presence of metaevaporitic rocks in lower WSG that may be intimately related to breccia formation. No evidence of breccia-age magmatism has been found to date.

Julie HuntEmail:

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Iron Diffusion in Single-Crystal Diopside     

F. Azough  R. Freer 《Physics and Chemistry of Minerals》2000,27(10):732-740

 Iron tracer diffusion experiments in diopside have been performed using natural and synthetic single crystals of diopside, and stable iron tracers enriched in ⁵⁴Fe, at temperatures in the range 950–1100 °C, total pressure 1 atm, for times up to 29 days. Iron isotope diffusion profiles were determined with an ion microprobe. For experiments performed at log pO₂ = −13, in directions parallel to the c axis and the b axis of two natural, low iron (Fe ∼ 1.8 at %) diopsides, the data obey a single Arrhenius relationship of the form D = 6.22_−5.9 ^+49.6×10⁻¹⁵ exp(−161.5 ± 35.0 kJ mol⁻¹/RT) m² s⁻¹. A single datum for iron diffusion in iron-free, single-crystal diopside at 1050 °C, is approximately 1 order of magnitude slower than in the natural crystals. The pO₂ dependence of iron diffusion in natural crystals at 1050 °C (power exponent = 0.229 ± 0.036) indicates a vacancy mechanism; this is consistent with the results of unpublished atomistic simulation studies. There is no evidence of anisotropy for iron diffusion in diopside. Received: 16 March 1999 / Accepted: 10 April 2000  相似文献   

铁(II)-5-Br-PADAP-乳化剂OP体系析相光度法测定微量铁的应用研究   总被引：5，自引：0，他引：5  

周发连  刘峙嵘  刘云海  张建梅 《华东地质学院学报》2000,23(4):356-358

研究了铁 (Ⅱ ) 5 Br PADAP 乳化剂OP体系中的析相、显色反应的条件及其吸收光谱的分析特征 ,拟定了直接测定不同种类样品中痕量铁的分析方法。在pH =5 .0的HAC NaAC缓冲溶液中 ,Fe(Ⅱ ) 5 Br PADAP络合物具有两个吸收峰 ,分别位于λ1 =5 6 1nm与λ2 =75 4nm处。本文选择λ =75 4nm进行测定 ,其摩尔吸光系数为 :ε75 4 =3.9× 10 4L·mol- 1 ·cm- 1 。铁含量在 0～ 2 4μg范围内服从比尔定律。此方法用于样品中痕量铁的测定 ,结果准确  相似文献   

温度和电子传递体AQDS对铁还原细菌Shewanella putrefaciens CN32矿化产物的影响   总被引：2，自引：0，他引：2       下载免费PDF全文

李陛  吴文芳  李金华  潘永信 《地球物理学报》2011,54(10):2631-2638

微生物矿化产生的超顺磁性(SP)磁铁矿是沉积物和土壤中磁性矿物的重要来源.本文比较了三个不同温度下(20℃,30℃,37℃)纯培养铁还原细菌Shewanella putre aciens CN32还原水合氧化铁形成SP磁铁矿的矿化特征.在实验体系中加入细菌CN32后,体系的氧化还原电位Eh迅速下降,酸碱度pH和亚铁离子...  相似文献   

Experimental evidence for rapid biotic and abiotic reduction of Fe (III) at low temperatures in salt marsh sediments: a possible mechanism for formation of modern sedimentary siderite concretions     

ROBERT J. G. MORTIMER  AMANDA M. J. GALSWORTHY  SIMON H. BOTTRELL  LUCY E. WILMOT  ROBERT J. NEWTON 《Sedimentology》2011,58(6):1514-1529

Fe (III) reduction is a key component of the global iron cycle, and an important control on carbon mineralization. However, little is known about the relative roles and rates of microbial (biotic) iron reduction, which utilizes organic matter, versus abiotic iron reduction, which occurs without carbon mineralization. This paper reports on the capacity for salt marsh sediments, which typically are rich in iron, to support abiotic reduction of mineral Fe (III) driven by oxidation of sulphide. Sediment was reacted with amorphous FeS under strictly anaerobic conditions at a range of temperatures in biotic and abiotic microcosm experiments. Fe (III) reduction driven by sulphide oxidation occurs abiotically at all temperatures, leading to Fe (II) and elemental sulphur production in all abiotic experiments. In biotic experiments elemental sulphur is also the oxidized sulphur product but higher bicarbonate production leads to FeCO₃ precipitation. Abiotic reduction of Fe (III) occurs at rates that are significant compared with microbial Fe (III) reduction in salt marsh sediments. The solid phases produced by coupled abiotic and biotic reactions, namely elemental sulphur and FeCO₃, are comparable to those seen in nature at Warham, Norfolk, UK. Furthermore, the rates of these processes measured in the microcosm experiments are sufficient to generate siderite concretions on the rapid time scales observed in the field. This work highlights the importance of abiotic Fe (III) reduction alongside heterotrophic reduction, which has implications for iron cycling and carbon mineralization in modern and ancient sediments.  相似文献   

智利Rodados Negros铁矿床地质特征、成矿机理与找矿前景分析   总被引：2，自引：1，他引：1  

陈文林  刘良根 《矿产与地质》2011,25(3):208-210

通过对智利Rodados Negros铁矿床地质特征实地考察和对地质资料综合分析,阐明了智利海岸山脉成矿带铁氧化物-铜-金型矿床的成矿机理,对该类型矿床的找矿前景进行了初步探讨并提出找矿思路.  相似文献   

莱州市土山-东宋铁矿地质特征     

毕明光  孙亮亮  解英芳  马世君  赵顺红 《山东地质》2011,(2):8-11

通过近几年的地质找矿工作,莱州市土山—东宋地区发现了中型变质沉积铁矿床。矿床产于古元古代粉子山群小宋组二段底部的含铁岩系。矿石工业类型为需选弱磁性铁矿石,主要成因类型为磁铁黑云片岩型、磁铁变粒岩型。矿床范围内共划分了5个矿段40个矿体。该文以此为基础,对矿区地质特征进行分析研究,以期促进山东省铁矿地质勘查工作的开展。  相似文献   

Bacterioplankton responses to iron enrichment during the SAGE experiment     

J. Kuparinen  J. HallM. Ellwood  K. SafiJ. Peloquin  D. Katz 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(6):800-807

We studied the microbial food web in the upper 100 m of the water column in iron-limited sub-Antarctic HNLC waters south-east of New Zealand in the SAGE experiment in 2004, with focus on bacterioplankton. Samples were collected daily from inside and outside the iron enriched patch. Short term enrichment experiments were conducted on board in 4 L polycarbonate bottles with water outside the iron enriched patch to study single and combined effects of micronutrient additions on microbial food web. Low bacterial growth was recorded in the study area with community turnover times of 50 h or more during the study period. Measurements of bacterial standing stocks and production rates in the study show minor responses to the large scale iron enrichment, with increase in rates and stocks after the first enrichment and at the end of the study period after the third iron enrichment when solar radiation increased and wind mixing decreased. The average daily bacterial production rates were 31.5 and 33.7 mgCm⁻² d⁻¹ for the OUT and IN stations, respectively; thus overall there was not a significant difference between the control and the iron-enriched patch. In the bottle experiments bacterial thymidine incorporation showed responses to single iron and silicic acid enrichments and a major growth response to the combined iron and sucrose enrichments. Phytoplankton chlorophyll-a showed clear stimulation by single additions of iron and silicic acid and silicic acid enhanced the iron impact. Cobalt additions had no effect on bacteria growth and a negative effect on phytoplankton growth. Low bacterial in situ growth rates and the enrichment experiments suggest that bacteria are co-limited by iron and carbon, and that bacterial iron uptake is dependent on carbon supply by the food web. With the high iron quota (??mol Fe mol C⁻¹) bacteria may scavenge considerable amounts of the excess iron, and thus influence the relative importance of the microbial food web as a carbon sink.  相似文献   

The response of phytoplankton to iron enrichment in Sub-Antarctic HNLCLSi waters: Results from the SAGE experiment     

Jill Peloquin  Julie HallKarl Safi  Walker O. Smith Jr.Simon Wright  Rick van den Enden 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(6):808-823

Areas of high nutrients and low chlorophyll a comprise nearly a third of the world’s oceans, including the equatorial Pacific, the Southern Ocean and the Sub-Arctic Pacific. The SOLAS Sea-Air Gas Exchange (SAGE) experiment was conducted in late summer, 2004, off the east coast of the South Island of New Zealand. The objective was to assess the response of phytoplankton in waters with low iron and silicic acid concentrations to iron enrichment. We monitored the quantum yield of photochemistry (F_v/F_m) with pulse amplitude modulated fluorometry, chlorophyll a, primary productivity, and taxonomic composition. Measurements of F_v/F_m indicated that the phytoplankton within the amended patch were relieved from iron stress (F_v/F_m approached 0.65). Although there was no significant difference between IN and OUT stations at points during the experiment, the eventual enhancement in chlorophyll a and primary productivity was twofold by the end of the 15-day patch occupation. However, no change in particulate carbon or nitrogen pools was detected. Enhancement in primary productivity and chlorophyll a were approximately equal for all phytoplankton size classes, resulting in a stable phytoplankton size distribution. Initial seed stocks of diatoms were extremely low, <1% of the assemblage based on HPLC pigment analysis, and did not respond to iron enrichment. The most dominant groups before and after iron enrichment were type 8 haptophytes and prasinophytes that were associated with ∼75% of chlorophyll a. Twofold enhancement of biomass estimated by flow cytometry was detected only in eukaryotic picoplankton, likely prasinophytes, type 8 haptophytes and/or pelagophytes. These results suggest that factors other than iron, such as silicic acid, light or physical disturbance limited the phytoplankton assemblage during the SAGE experiment. Furthermore, these results suggest that additional iron supply to the Sub-Antarctic under similar seasonal conditions and seed stock will most likely favor phytoplankton <2 ??m. This implies that any iron-mediated gain of fixed carbon will most likely be remineralized in shallow water rather than sink and be sequestered in the deep ocean.  相似文献