环球海洋大气气溶胶化学研究

Ⅱ.来源示踪元素的特征   总被引：7，自引：0，他引：7       下载免费PDF全文

陈立奇  高鹏飞  杨绪林 《海洋与湖沼》1993,24(3):264-271

1986年11月—1987年5月,在中国第三次南极考察和环球科学考察期间,收集了58个海洋气溶胶样品,采用中子活化法分析了Al,V,Mn,I,Br,Mg,Na,Cl等元素。应用因子分析、回归分析和富集因子分析对气溶胶中元素进行分类、定量评估和来源判别,讨论不同来源元素的特征,计算各主要来源的贡献分量。结果表明,海洋气溶胶中Al的99.99％是来自陆源地壳风化物,Na的99.2％。和Cl的99.99％是来自海水,V的91.4％。来自陆源污染物。因此,Al可作为海洋气溶胶中陆源地壳风化物的示踪元素,Na和Cl可作为海水源示踪元素,非地壳源的V则可选择为陆源污染物的示踪元素。  相似文献   

大气垂直速度计算中校正方法的探讨     

沈雪龙 《海洋学研究》1997,15(4):24-28

本文对大气运动中垂直速度ｗ计算中的几种校正方法作了分析比较，并在前人工作的基础上，对校正方法作了改进，提出了进行低通滤波、散度校正和法线风分量校正的方法。通过这些校正，使计算出的平均散度和垂直速度的垂直廓线能维持原计算曲线的形式，并能满足整个气层连续方程积分为零的条件，也符合误差随高度增大的情况。  相似文献   

气溶胶的光学厚度与反射率比的处理方法   总被引：2，自引：0，他引：2  

高飞 《海洋技术学报》2003,22(1):25-28

气溶胶光学厚度与气溶胶反射率比都是大气校正所需的重要大气参数，同时也是海洋水色卫星主要的数据产品，它们的测量精度将直接到卫星数据产品正演的精度和卫星数据产品的应用。文章在简述气溶胶光学厚度与气溶胶反射率比的基本测量原理和处理方法的基础上，结合多次试验数据结果进行简要的评价。  相似文献   

沃克环流上升区赤道低空强西风带的分析     

李若钝  于惠苓  刘丽惠  孙瑞本  井传才  苏新锁 《热带海洋学报》1995,(1)

采用ＴＯＧＡ／ＣＯＡＲＥ国际合作考察期间（１９９２年１０月─１９９３年２月）获得的２６７次定点（２°Ｓ，１５５°Ｅ）定时高空大气探测资料，进行计算分析，发现１９９２年１２月─１９９３年２月低空存在一支西风急流，有两次分别持续半月之久，而１９９２年１１月的两次赤道西风急流，因无赤道高空急流配合，仅持续２ｄ便消失。本文还指出：（１）赤道低空西风急流是各种海－气指数产生ＥＮＳＯ异常的重要信息；（２）赤道高空急流有滞后赤道低空急流２ｄ左右的响应关系；（３）赤道低空急流是纬向水汽输送的狭窄通道。  相似文献   

白天工作条件下大气激光雷达探测的实验研究     

宋小全  刘智深  贺岩  刘金涛 《中国海洋大学学报(自然科学版)》2001,31(4):593-598

作者在已完成大气激光雷达系统夜间工作的基础上 ,对白天工作条件下的各种环境背景光的干扰进行了理论与实验分析 ,得出太阳直射光和天空光为白天工作的主要背景干扰。实验结果表明 ,经过激光发射与接收视场角严格匹配及使用干涉滤光器 (2 .6 nm和 0 .15nm)进行窄带滤波 ,背景干扰被明显地剔除 ,可进一步压低背景干扰约 2 0倍。证明采取视场匹配及干涉滤光器的措施可基本保证激光雷达系统在白天条件下工作。  相似文献   

南极中山站大气气溶胶的化学组成及其来源的判别   总被引：1，自引：1，他引：1  

黄自强  暨卫东  杨绪林  黄荣坦  汤荣坤  于涛  张功勋 《台湾海峡》2003,22(3):334-346

从1998年3月7日至1999年11月23日历时21个月，在南极中山站连续采集89个海洋气溶胶样品，本文提供全部样品的13种化学元素Cu、Pb、Zn、Cd、Fe、Al、Mn、Cr、V、K、Na、Ca、Mg含量的实测值．研究表明中山站气溶胶化学成份的含量具有季节性变化的特征．通过相关分析、因子分析、富集因子等方法判别不同时间段中山站气溶胶化学成份的来源。  相似文献   

Seasonal variations of atmospheric sulfur dioxide and dimethylsulfide concentrations at Amsterdam Island in the southern Indian Ocean     

J. P. Putaud  N. Mihalopoulos  B. C. Nguyen  J. M. Campin  S. Belviso 《Journal of Atmospheric Chemistry》1992,15(2):117-131

Daily measurements of atmospheric sulfur dioxide (SO₂) concentrations were performed from March 1989 to January 1991 at Amsterdam Island (37°50 S–77°30 E), a remote site located in the southern Indian Ocean. Long-range transport of continental air masses was studied using Radon (²²²Rn) as continental tracer. Average monthly SO₂ concentrations range from less than 0.2 to 3.9 nmol m^-3 (annual average = 0.7 nmol m^-3) and present a seasonal cycle with a minimum in winter and a maximum in summer, similar to that described for atmospheric DMS concentrations measured during the same period. Clear diel correlation between atmospheric DMS and SO₂ concentrations is also observed during summer. A photochemical box model using measured atmospheric DMS concentrations as input data reproduces the seasonal variations in the measured atmospheric SO₂ concentrations within ±30%. Comparing between computed and measured SO₂ concentrations allowed us to estimate a yield of SO₂ from DMS oxidation of about 70%.  相似文献   

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S     

A. Hofzumahaus  T. Brauers  U. Platt  J. Callies 《Journal of Atmospheric Chemistry》1992,15(3-4):283-298

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.  相似文献   

中国大气本底观测发展概述   总被引：1，自引：0，他引：1  

李伟 孙扬程根伟  王可琴李同阳 刘发蓉 《山地学报》2006,24(B10):324-329

中国早期的大气本底观测网建设起步于上世纪80年代初，并于10a后基本建成。目前，中国气象局、中国科学院在原有观测站的基础上各自建设和发展着自己下属的大气本底观测网络。全球大气观测网给出了一整套开展大气本底观测的技术标准，各国均予以严格遵循。20多年来，中国大气本底观测工作在基础数据积累以及观测标准制定等方面取得了较大进展，与此相关的科学研究也取得了长足进步。最后对中国大气本底观测发展过程中存在的一些问题进行了探讨。  相似文献   

Isothermal annealing of partially metamict zircon: evidence for a three-stage recovery process     

T. Geisler 《Physics and Chemistry of Minerals》2002,29(6):420-429

 Raman spectroscopy and the powder diffraction technique have been used to monitor the recovery process of two partially metamict zircons (2.6 and 4.8 × 10¹⁸ α-decays g⁻¹) from Sri Lanka during a series of isothermal annealing experiments in the temperature range from 870 to 1622 K. These experiments show for the first time that structural recovery in partially metamict zircon proceeds via three distinct recovery stages, each of which occurs within a distinct time-temperature regime. Whereas the first two stages have previously been recognized (recovery of damaged crystalline remnants and epitaxial recrystallization), the third stage has not yet been identified as a single activated process. It is suggested that anisotropic defect annealing during the first stage at low temperatures, where the structure recovers preferentially along the a(b) plane, produces a geometrical situation where large structural rearrangements are necessary to remove the remaining defects inside the crystalline material. This situation is approximately reached when the amorphous domains start to recrystallize. The reason for anisotropic annealing can be found in a different connectivity between polyhedral linkages in both directions of the zircon lattice. High apparent activation energies, in the range of 6.4 to 7.9 eV, were determined for the third recovery stage from the Raman data, which are interpreted to reflect large structural rearrangements (i.e. polyhedral tilting) associated with the final recovery of the c axis. This explains the occurrence of a distinct recrystallization stage without defect annealing. Finally, it should be mentioned that the first recovery stage is not necessarily expected to occur in less damaged zircon crystals (<∼2 × 10¹⁸ α-decays g⁻¹), since less stable defects along the basal plane might have already been self-annealed during radiation damage accumulation under ambient temperatures. Received: 6 September 2001 / Accepted: 25 February 2002  相似文献