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191.
Characterization of chromophoric dissolved organic matter (CDOM) in the Baltic Sea by excitation emission matrix fluorescence spectroscopy 总被引:11,自引:0,他引:11
Piotr Kowalczuk Joanna Sto-Egiert William J. Cooper Robert F. Whitehead Michael J. Durako 《Marine Chemistry》2005,96(3-4):273-292
Chromophoric dissolved organic matter (CDOM) is the major light absorber in the Baltic Sea. In this study, excitation emission matrix (EEM) fluorescence spectra and UV–visible absorption spectra of CDOM are reported as a function of salinity. Samples from different locations and over different seasons were collected during four cruises in 2002 and 2003 in the Baltic Sea in both Pomeranian Bay and the Gulf of Gdansk. Absorption by CDOM decreased with increased distance from the riverine source and reached a relatively stable absorption background in the open sea. Regression analysis showed that fluorescence intensity was linearly related to absorption by CDOM at 375 nm and aCDOM(375) absorption coefficients were inversely related to salinity. Analysis of CDOM-EEM spectra indicated that a change in composition of CDOM occurred along the salinity gradient in the Baltic Sea. Analysis of percent contribution of respective fluorophore groups to the total intensity of EEM spectra indicated that the fluorescence peaks associated with terrestrial humic components of the CDOM and total integrated fluorescence decreased with decreasing CDOM absorption. In contrast, the protein-like fraction of CDOM decreased to a lesser degree than the others. Analysis of the percent contribution of fluorescence peak intensities to the total fluorescence along the salinity gradient showed that the contribution of protein-like fluorophores increased from 2.6% to 5.1% in the high-salinity region of the transect. Fluorescence and absorption changes observed in the Baltic Sea were similar to those observed in similar transects that have been sampled elsewhere, e.g. in European estuaries, Gulf of Mexico, Mid-Atlantic Bight and the Cape Fear River plume in the South Atlantic Bight, although the changes in the Baltic Sea occurred over a much smaller salinity gradient. 相似文献
192.
K. K. Balachandran 《Estuarine, Coastal and Shelf Science》2004,59(4):589-598
Coastal waters off the southwest coast of India draw special attention because of the occurrence of mud banks at certain locations during southwest monsoon period. The present study puts forward a hypothesis of a subterranean flow, which could be a plausible mechanism to initiate the mud banks. The subterranean flow is believed to be coupled with activated trending faults and originate from the adjacent watershed (Vembanad Lake) separated from the sea by a narrow strip of land where submerged porous lime shell beds are present. When the lake water injection occurs through the fault, the mud/clay gets excited by its thixotrophic properties (as the overlying water looses its electrolyte) and transforms into a flowing fluid. The lowering of salinity due to the introduction of fresh water keeps the mud suspension in the water column for longer duration, leading to the formation of mud banks. The idea of subterranean flow through lime shell beds initiating formation of mud banks may apply globally to any coastal regions hugged by wetlands and of similar geological conditions. 相似文献
193.
渐新世/中新世分界的地层学事件 总被引:5,自引:1,他引:5
介绍渐新世/中新世分界面(即古近纪/新近纪分界面)附近的浮游有孔虫和钙质超微化石事件及其新年龄。2004年国际地层年代表确定该分界面位于第58长偏心率周期弱振幅处,古地磁事件C6Cn.2n底面,经天文调谐后的年龄为23.03 Ma。发生在该界面附近的生物地层学事件主要是浮游有孔虫Paragloborotalia kugleri的始现面(22.96 Ma)和钙质超微化石Sphenolithus delphix的末现面(23.11 Ma)。在南海北部东沙群岛附近的大洋钻探ODP1148站,渐新世/中新世界面以崩塌沉积物为特征,有明显沉积间断,标志南海当时有较大范围的构造运动。 相似文献
194.
厦门湾有色溶解有机物的光吸收特性研究 总被引:3,自引:0,他引:3
研究了厦门湾九龙江河口区、西海域、同安湾及东侧水道海水中有色溶解有机物(CDOM)的光吸收特性,分析了CDOM的河口行为,并讨论了CDOM光吸收特性与其荧光性质之间的关系。结果表明,厦门湾表层海水CDOM光吸收系数a(355)的水平分布表现为河口区最高、东侧水道最低、西海域和同安湾介于两者之间,底层水a(355)的分布与表层基本相似,表明陆源河流输入是厦门湾CDOM的主要来源;a(355)的垂直分布为表层高于底层,主要受水文和生物因素控制。厦门湾表层水CDOM光谱斜率S的平均值介于0.014—0.018nm-1,但河口低盐度区S值较小,反映陆源腐殖质的影响。a(355)在河口混合中呈保守行为,表明CDOM具有良好的保守性质。CDOM的吸收系数a(355)与其荧光强度之间表现为较好的相关关系,指示可以用灵敏度更高的荧光方法来研究CDOM的分布和行为。 相似文献
195.
1 .IntroductionFor Lakes near the middle andlower reaches of the Yangtze River ,theformationof lake basinsisgreatly affected by geological structures ,andthe interaction betweenrivers and seas .The Taihu Lakeis locatedinthelow-lying plain nearthe east coa… 相似文献
196.
197.
某港口堆场地基上部5.0m系吹填而成,地表下18m范围均属软土,经真空预压初级加固后地基承载力仅在80—90kPa,局部区域上部淤泥土层土性指标较差,含水量大于50%,地基承载力不足60kPa。为了使地基达到230kPa的承载要求,设计采用深层搅拌法加固超软弱地基。通过现场成桩工艺试验和检测表明,桩身水泥土强度在90d龄期时大于1.80MPa,单桩承载力标准值大于150kN,以φ600桩径、桩长13.5m、置换率为0.308和φ500桩径、桩长13.5m、置换率为0.267两种方案布置的复合地基承载力标准值均超过了230kPa的设计要求。试验结果表明,深层搅拌法在港口超软弱地基土应用只要施工工艺适当,完全可以使地基承载力提高2—3.5倍以土,从而节省大量的工程投资。 相似文献
198.
199.
The steady response of the ventilated thermocline to an increase in Ekman pumping is investigated, focusing on the effect
of the mixed layer depth distribution on the subsurface density anomaly. We consider only the subtropical gyre, and the mixed
layer is assumed to be deep in the northwest and shallow elsewhere with a narrow transition zone separating the deep and shallow
mixed layer regions. At the intersection of this narrow transition zone and the outcrop line, low potential vorticity fluid
is subducted into and ventilates the thermocline. In such a situation, an enhancement of the Ekman pumping confined to the
northern subtropical gyre leads to pronounced subsurface cold anomalies in the southern subtropics, which is free of anomalous
forcing. These density anomalies are much greater than those that occur when either the mixed layer depth is zonally uniform
or the Ekman pumping is enhanced in the whole subtropical gyre. They are caused by anomalous changes in the trajectory of
the low potential vorticity fluid in response to anomalous Sverdrup flow.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
200.
Abstract. This paper describes the quantitative inventory of stony corals on a Maldivian reef after the bleaching event of 1998. The detailed data, collected in March 1999 and March 2000, comprise survival, new recruitment and regenerates. They were obtained in 6 transects laid out randomly on the reef flat, on 22 Acropora tables on 6 sites at the reef edge and on 39 Porites lobata blocks and 1 Diploastrea heliopora colony. The present cover of living zooxanthellate corals is reduced to ca. 2 – 5 % of its previous state. Acroporidae and Pocilloporidae were practically wiped out, while Poritidae survived partly and Agariciidae (esp. Pavona) are now the dominant group. New settlements on dead Acropora tables were mainly Agariciidae, followed by Acroporidae and Pocilloporidae. Regenerates on Porites were pronounced and the apparent yearly increase in mass was about threefold that of Diploastrea, which is 3 – 4 mm per year. The influence on reef ecology in terms of coral substrate and species, possible sources of larvae, change of guilds in reef builders, other species and the prospect for further development of the reef, with respect to growth versus erosion, is discussed. 相似文献