Primary cracking of kerogens. Experimenting and modelling C₁, C₂–C₅, C₆–C₁₅ and C₁₅₊ classes of hydrocarbons formed     

J. Espitali  P. Ungerer  I. Irwin  F. Marquis 《Organic Geochemistry》1988,13(4-6)

Mathematical models of hydrocarbon formation can be used to simulate the natural evolution of different types of organic matter and to make an overall calculation of the amounts of oil and/or gas produced during this evolution. However, such models do not provide any information on the composition of the hydrocarbons formed or on how they evolve during catagenesis.From the kinetic standpoint, the composition of the hydrocarbons formed can be considered to result from the effect of “primary cracking” reactions having a direct effect on kerogen during its evolution as well as from the effect of “secondary cracking” acting on the hydrocarbons formed.This report gives experimental results concerning the “primary cracking” of Types II and III kerogens and their modelling. For this, the hydrocarbons produced have been grouped into four classes (C₁, C₂–C₅, C₆–C₁₅ and C₁₅₊). Experimental data corresponding to these different classes were obtained by the pyrolysis of kerogens with temperature programming of 4°C/min with continuous analysis, during heating, of the amount of hydrocarbons corresponding to each of these classes.The kinetic parameters of the model were optimized on the basis of the results obtained. This model represents the first step in the creation of a more sophisticated mathematical model to be capable of simulating the formation of different hydrocarbon classes during the thermal history of sediments. The second step being the adjustment of the kinetic parameters of “secondary cracking”.  相似文献   

海城震区深地震测深资料A/D转换方法及其效果的研究     

杨茜  赵国敏  白云  李志生 《东北地震研究》1993,(4)

介绍深地震测深模拟磁带资料在CROMEMCO型微机上实现A/D转换的方法及其效果。在实现A/D转换研究中,进行了时标信号采集方式、六响信号处理、模拟回放电路改进等方法的试验,从而提高了A/D转换精度与效果。经对海城震区实际资料分析可知:该系统A/D转换精度达到了规范要求。  相似文献   

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究     

王东进  谢增鸿  樊祺泉  蔡文进  黄炳俊  张振欣 《岩矿测试》1990,(2)

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。  相似文献   

银催化HDEA电化学发光法测定矿样中的痕量银     

林金明  安镜如 《岩矿测试》1991,10(1):13-16

在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。  相似文献   

The New Meteorite Fall of Yanzhuang—A Severely Shocked H6 Chondrite with Black Molten Materials     

Xiande Xie  Zhaohui Li  Daode Wang  Jingfa Liu  Ruiying Hu  Ming Chen 《中国地球化学学报》1994,13(1):39-46

At 21:45 hr (Beijing time) on Oct. 31, 1990 the Yanzhuang meteorite hit the ground at the Yanzhuang village, Wenyuan County, Guangdong Province. Several fragments, totalling 3.5 kg, were recovered during the field survey. This meteorite is a rare one of its kind due to its heavily shocked features and thick veins made up of black molten materials. Olivine and low-calcium pyroxene are compositionally homogeneous with Fa=18.59, Fs=16.35 and Wo=1.29. The chemical composition (total Fe=28.0%) and recrystallized texture of the chondritic mass show that the Yanzhuang is an H6 chondrite. The black molten materials occur in the form of blocks (up to 2×3×4 cm in size) and veins (0.1–15 mm in width), and contain a lot of rounded and elliptic FeNi-FeS blobs (up to 6–10 mm in length). The metal in these blobs exhibits distinct dendritic structure characteristic of rapid cooling. Unmolten and molten samples are very similar in chemical composition, fitting well with the average H-chondrites. Partial melting and FeNi/FeS-silicate separation have not been observed in the molten materials of the Yanzhuang. This project was financially supported by the Science Foundation of Guangdong Province.  相似文献   

庐山变质核杂岩构造的初步研究   总被引：12，自引：2，他引：12  

项新葵  许建华 《华东地质学院学报》1994,17(1):11-17

  相似文献   

地震信号内插与噪音剔除（一）   总被引：3，自引：0，他引：3       下载免费PDF全文

李庆忠 《地球物理学报》1987,30(5):514-531

信号内插与噪音剔除是相互有着有机联系的两个方面。首先讨论地震信号的内插方法,提出了一种“最佳内插算子”,从而导出了另一种“检噪算子”,它可以有效地把干扰波从记录中识别出来,并将其“剔除”出去。进而讨论空间域数据的内插问题--道内插问题。在一定的条件下,空间域数据内插与时间域内插是完全等效的,因此道内插也可以采用与时间域相同的“最佳内插算子”。地震记录上的干扰波其绝大部分表现为空间域的脉冲式干扰,所以用“检噪算子”在空间域作褶积,便能识别干扰,从而对干扰加以剔除。本文解决了一种迭代的剔除方法,取得了好的效果。  相似文献   

High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave   总被引：1，自引：0，他引：1  

Li TingYong  Yuan DaoXian  Li HongChun  Yang Yan  Wang JianLi  Wang XinYa  Li JunYun  Qin JiaMing  Zhang MeiLiang  Lin YuShi 《中国科学D辑(英文版)》2007,50(8):1202-1208

A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS ²³⁰Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ ¹⁸O and δ ¹³C, mostly in the 2.3–26 cm part. The δ ¹⁸O and δ ¹³C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ ¹⁸O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ ¹⁸O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ ¹⁸O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ ¹⁸O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ ¹⁸O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology. The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having climatic significance. Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician Special Project of Chongqing Science Committee (Grant No. 2003-7835)  相似文献   

印尼苏门答腊MW9.0级地震对全球及中国大陆地震趋势影响研究的反思     

韩渭宾  蒋国芳 《四川地震》2007,(4):1-4

本文对2004年12月26日印尼苏门答腊以西发生MW9.0级地震后所做的地震趋势预测做了反思,指出:关于全球特大地震近年可能连发,特大地震对几年内世界7级以上地震年频度没有明显影响,但未来几年内7级以上强震可能集中在这次特大地震附近或相关构造上的预测意见是正确的;而有关近年中国大陆及川滇地区可能发生7级强震的预测是错误的;并认为,2001年昆仑山口西8.1级地震释放了已积累的应变可能是这次特大地震不能触发中国大陆及川滇地区发生强震的重要原因。  相似文献   

岩石矿物及粉尘中游离二氧化硅的测定     

席进萍  沈燕君等 《岩矿测试》2002,21(1):71-73

改进了游离二氧化硅（fSiO2)测定中试样的分解方法，采用硫－磷混酸替代单独使用磷酸分解试样，防止了焦磷酸盐的形成，同时，氟硼酸对fSiO2的溶解率符合测定要求。改进的方法用于标准物质中fSiO2的测定，结果与标准值或磷酸溶矿重量法相符。对于ω(fSiO2)=3.26%的标样10次测定的RSD为2．4％。  相似文献