浙江桂凋落物中可溶性有机物对铜离子络合能力研究     

钱伟  曾宏达  郭剑芬  汪伟  林菲菲 《亚热带资源与环境学报》2007,2(1):49-53

采用单配位体模型对不同分解阶段浙江桂凋落物中溶解性有机物(DOM)与铜离子的络合进行了研究.结果表明,DOM中存在络合条件稳定常数较高但络合容量较小和络合条件稳定常数较低但络合容量较大的2种组分.各阶段条件稳定常数(K)和络合容量(L)各不相同,各阶段中1g K与L存在着显著的负相关性(r=0.88,P＜0.05);各组分对铜离子的络合能力排列顺序为:Ⅱa＞Ⅰa＞Ⅰb＞Ⅲa＞Ⅱb＞Ⅲb,半分解阶段中凋落物所释放的DOM对铜离子的络合条件稳定常数最大.这可能与其在分解不同阶段所释放物质不同有关.  相似文献   

含部分晶须的钛酸锂的制备及其性能表征     

邓昭平  倪师军  李思平  夏新蕊  王鹏威 《矿物岩石》2006,26(4):98-100

L i4T i5O12是一种循环性能好、有很好的充放电平台、理论比容量较大、不与电解液反应的新型负极材料,研究探索以偏钛酸和碳酸锂为主要原料制备含部分晶须的尖晶石型晶型L i4T i5O12的一种方法。通过此工艺在1 000℃煅烧8 h后在样品中约20%的晶须出现,晶须的直径≤0.5μm,晶须的长度约为7μm。  相似文献   

大洋调查中海山地磁测量的静日变化校正方法   总被引：2，自引：1，他引：1  

刘保华  刘晨光  裴彦良  阚光明 《海洋学报》2008,30(6):94-98

针对大洋调查中海山地磁测量时难以设立静日变化观测站的问题,提出了一种基于多项式拟合最小二乘算法的日变校正方法,即假设静日变化磁场可以用一个关于时间的高阶多项式来拟合,利用主测线和联络测线交点误差的最小二乘估计求得多项式的系数,从而得到静日变化曲线。从调查测得的磁场中减掉静日变化磁场即可得消除静日变化影响后的海山地磁异常。理论模型和实际资料处理都表明,这种方法不仅可以较好地消除静日变化的影响,而且用计算机实现也简单。为了提高静日变化校正结果,讨论了为提高静日变化校正效果,在大洋调查中测量海山地磁时应注意的几个问题。  相似文献   

Long-term stability of the fish assemblages in a warm-temperate South African estuary     

Nicola C. James  Alan K. Whitfield  Paul D. Cowley 《Estuarine, Coastal and Shelf Science》2008,76(4):723-738

Little is known about long-term changes in estuarine fish populations and related environmental variations. Fishes in the temporarily open/closed East Kleinemonde Estuary were sampled bi-annually, in summer and winter, using seine and gill nets between December 1994 and July 2005. A total of 18 families, represented by 33 species, were recorded. The 10 most abundant species caught were consistently recorded in catches each year, but CPUE of individual species varied on an annual basis and this can often be related to mouth state. Multivariate analyses of the annual marine fish community identified two distinct groups, with more species recorded during years that succeeded spring (September to November) mouth-opening events than in years following no mouth-opening events in spring. Interannual community stability (IMD) and seriation (IMS) also increased from the years following no opening events in spring to the years that succeeded spring opening events. These results highlight the importance of the timing of mouth opening to the marine fish community in a temporarily open/closed estuary. This study reinforces the importance of long-term studies to understanding community changes in estuaries caused by environmental variations over different time scales.  相似文献   

Inter-annual variability in phytoplankton summer blooms in the freshwater tidal reaches of the Schelde estuary (Belgium)   总被引：1，自引：1，他引：0  

Marie Lionard  Koenraad Muylaert  Abdel Hanoutti  Tom Maris  Michle Tackx  Wim Vyverman 《Estuarine, Coastal and Shelf Science》2008,79(4):694-700

The inter-annual variability in phytoplankton summer blooms in the upper reaches of the Schelde estuary was investigated between 1996 and 2005 by monthly sampling at 10 stations. The large inter-annual variations of the chlorophyll a concentration in the freshwater tidal reaches were independent from variations in chlorophyll a in the tributary river Schelde. Summer mean chlorophyll a concentrations were significantly negatively correlated with flushing rate (Spearman correlation: r = −0.67, p = 0.05, n = 9) but not with temperature, irradiance and suspended particulate matter or dissolved silica (DSi) concentrations. During dry summers, low flushing rates permitted the development of dense phytoplankton populations in the upper part of the estuary, while during wet summers high flushing rates prevented the development of dense phytoplankton blooms. Flushing rate was also found to be important for the phytoplankton community composition. At low flushing rates, the community was dominated by diatoms that developed within the upper estuary. At high flushing rates, chlorophytes imported from the tributary river Schelde became more important in the phytoplankton community. The position of the chlorophyll a maximum shifted from the head of the estuary when flushing rates were low, to more downstream when flushing rates were high. Although DSi concentrations tended to be lower during years of high phytoplankton (mainly diatom) biomass, the relation with flushing rate was not significant.  相似文献   

Seasonal and spatial variation in abundance and egg production of Paracalanus parvus (Copepoda: Calanoida) in/out Jiaozhou Bay, China     

X.H. Sun  S. Sun  C.L. Li  G.T. Zhang 《Estuarine, Coastal and Shelf Science》2008,79(4):637-643

The spatial distribution of stage-specific abundance and reproduction of the copepod Paracalanus parvus were studied from October 2005 to September 2006 in the Jiaozhou Bay. This copepod occurred continuously in this bay throughout the year. The species reached the lowest abundance in April and peaked in June. From October to December, distribution center mainly occurred in offshore water and at the mouth of the bay. In winter, early copepodites and adults gradually decreased and till February, most of the population was only comprised of CIV–CV stages. Overwintering copepodites matured in March and males tended to mature before female. From May to September, each stage occurred in the population and gradually reached high abundance. Temperature and chlorophyll a (Chl-a) concentration in the three stations can't clearly explain the seasonal variation in stage-specific abundance, so we surmised the important effect of the Yellow Sea. Egg production rate (EPR) reached its lowest in winter and peaked in June at 60.8 eggs female⁻¹ day⁻¹ in nearshore water. In the warming period, EPR in nearshore water was statistically higher and EPR > 10 eggs female⁻¹ day⁻¹ lasted longer than that in offshore water, showing the importance of nearshore water for recruitment of P. parvus. Our study showed that EPR was positively related to temperature and total chlorophyll a in offshore water and mouth of the bay. In nearshore water, the relationships between EPR and temperature and Chl-a in three size fractions were not the same as those in offshore water, suggesting complicated ecosystem in such a eutrophic area in warming period.  相似文献   

广利港河道水位变化及河口拦门沙地形变化分析研究     

林维田  吴永亭  刘建立 《海岸工程》2008,27(3):9-14

根据1984年和2007年两次对广利港航道水深测量的结果,分析研究了广利港航道内的水位变化规律,以及河口拦门沙的地形特征。结果表明广利港航道内水位变化复杂,拦门沙形态改变,水深变浅,原有的航道已经消失。  相似文献   

钱塘江强潮河段江道缩窄治理研究   总被引：1，自引：0，他引：1  

陈来华  潘存鸿 《海洋工程》2008,26(2):96-102

对钱塘江强潮河段江道缩窄治理进行研究。首先,回顾治理方案的比选,江道全线缩窄时河轴线线路和河道宽度的确定原则,以及不同河段的指数放宽率。然后,介绍了在涌潮汹涌、滩涂淤坍变化剧烈的强潮河段,实施筑堤所采取的工程措施的步序与要点。最后,分析论证了大规模江道缩窄治理后河床、潮汐、洪水位及涌潮高度等特征值的变化。可供进一步深入理论研究和工程施工参考运用。  相似文献   

钢筋混凝土结构电渗阻锈技术研究   总被引：5，自引：0，他引：5  

唐军务  李森林  蔡伟成  胡明  朱雅仙 《海洋工程》2008,26(3)

通过测量电渗阻锈过程中阻锈剂渗入量、脱盐率以及钢筋极化电阻,研究了混凝土技术参数和电渗电量对电渗阻锈效果的影响.试验结果表明,电渗阻锈技术能在脱除盐污染混凝土中氯离子的同时,将有效阻锈基团快速迁移到钢筋表面,使已腐蚀的钢筋快速恢复钝化而达到防腐的目的.  相似文献   

Study on the isotherms of the interaction between suspended particles and Cu (II) in the Huanghe River   总被引：4，自引：0，他引：4  

Li Gai-zhi  Guo Bo-shu  Liu Ying  Hong Xia  Li Jing-feng  Li Bei-gang 《中国海洋湖沼学报》2000,18(2):178-182

The isotherms of the interaction between the suspended particles and Cu²⁺, and the effects of lysine and asparaginic acid on the isotherms in the Huanghe (Yellow) River were studied by applying the theory and method of interfacial stepwise ion/coordination particle exchange. We obtained a new stepped river isotherm, formed by two curves joined together with a “plateau” in the middle. The adsorption equilibrium constantsK ₁ andK ₂ were calculated by using the isothermal equation of surface stepwise ion exchange. Amino acid in small amount promotes exchange adsorption of the suspended particles with Cu²⁺. The degree of promotive action relates to the isoelectric point of amino acid. The promotive effect of lysine is bigger than that of asparaginic acid. Project 29361001 supported by NSFC.  相似文献