环境矿物材料基本性能：无机界矿物天然自净化功能   总被引：53，自引：23，他引：53       下载免费PDF全文

鲁安怀 《岩石矿物学杂志》2001,20(4):371-381

重点阐述环境矿物材料基本性能，包括矿物表面吸附、孔道过滤、结构调整、离子交换、化学活性、物理效应、纳米效应及与生物交互作用等，旨在发掘、凝炼并新提出物理方法和化学方法之后与有机界生物同效的无机界矿物天然自净化功能的基础理论与应用方法，以发展和完善无机矿物与有机生物所共同构筑的自然界中存在的天然自净化系统，并就目前笔者在黄铁矿、锰钾矿、金红石、蛭石、蒙脱石、苋铁铁钒等天然矿物方面已经完成和正在开展的一系列环境矿物材料研究工作进行了举例说明。  相似文献   

The heat capacity of two natural chlorite group minerals derived from differential scanning calorimetry     

C. Bertoldi  A. Benisek  L. Cemic✓  E. Dachs 《Physics and Chemistry of Minerals》2001,28(5):332-336

The heat capacity of natural chamosite (X_Fe=0.889) and clinochlore (X_Fe=0.116) were measured by differential scanning calorimetry (DSC). The samples were characterised by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy. DSC measurements between 143 and 623?K were made following the procedure of Bosenick et?al. (1996). The fitted data for natural chamosite (CA) in J?mol^?1?K^?1 give: C _p,CA = 1224.3–10.685?×?10³?×?T ^??0.5???6.4389?× 10⁶?×T ^??2?+?8.0279?×?10⁸?×?T ^??3 and for the natural clinochlore (CE): C _p,CE = 1200.5–10.908?×?10³?×T ^??0.5?? 5.6941?×?10⁶?×?T ^??2?+?7.1166?×?10⁸?×?T ^??3. The corrected C _p-polynomial for pure end-member chamosite (Fe₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CAcor = 1248.3–11.116?× 10³?×?T ^??0.5???5.1623?×?10⁶?×?T ^??2?+?7.1867?×?10⁸×T ^??3 and the corrected C _p-polynomial for pure end-member clinochlore (Mg₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CEcor = 1191.3–10.665?×?10³?×?T ^??0.5???6.5136?×?10⁶?×?T ^??2?+ 7.7206?×?10⁸?×?T ^??3. The corrected C _p-polynomial for clinochlore is in excellent agreement with that in the internally consistent data sets of Berman (1988) and Holland and Powell (1998). The derived C _p-polynomial for chamosite (C _p,CAcor) leads to a 4.4% higher heat capacity, at 300?K, compared to that estimated by Holland and Powell (1998) based on a summation method. The corrected C _p-polynomial (C _p,CAcor) is, however, in excellent agreement with the computed C _p-polynomial given by Saccocia and Seyfried (1993), thus supporting the reliability of Berman and Brown's (1985) estimation method of heat capacities.  相似文献   

Aragonite from Mulanshan Glaucophane Schist: Implications for Regional Evolution of Southwestern Dabie Mountains, Central China     

Zhao Wenyu Center of Material Research  Analysis  Wuhan University of Technology  Wuhan Liu Rong Wang QinyanFaculty of Earth Sciences  China University of Geosciences  Wuhan Peng Changqi Zhang QingjieCenter of Material Research  Anal 《中国地质大学学报(英文版)》2001,12(3)

ＩＮＴＲＯＤＵＣＴＩＯＮＩｔｉｓａｎａｃｋｎｏｗｌｅｄｇｅｄｆａｃｔｔｈａｔａｒａｇｏｎｉｔｅ,ａｈｉｇｈ ｐｒｅｓｓｕｒｅｐｏｌｙｍｏｒｐｈｏｆＣａＣＯ3 ,ｏｃｃｕｒｓｗｉｄｅｌｙａｓａｎｉｎｄｅｘｍｉｎｅｒａｌｏｆｈｉｇｈ ｐｒｅｓｓｕｒｅａｎｄｌｏｗ ｔｅｍｐｅｒａｔｕｒｅｍｅｔａｍｏｒｐｈｉｓｍ (ｇｌａｕｃｏｐｈａｎｅｓｃｈｉｓｔｆａｃｉｅｓ)ｗｉｔｈｉｎｔｈｅｇｅｏｄｙｎａｍｉｃｃｏｎｔｅｘｔｏｆｓｕｂｄｕｃｔｉｏｎ ｏｂｄｕｃｔｉｏｎａｎｄｃｏｎｔｉｎｅｎｔａｌｃｏｌｌｉｓｉｏｎ (Ｌｉｏｕ…  相似文献   

One-station estimates of seismic moments from the mantle magnitudeM m: The case of the regional field (1.5°≤Δ≤15°)     

Jacques Talandier  Emile A. Okal 《Pure and Applied Geophysics》1992,138(1):43-60

We extend to the regional field of distances the procedure of one-station estimation of seismic moments using the mantle magnitudeM _m, as introduced earlier in the case of teleseismic events. A theoretical analysis of the validity of the asymptotic expansion of normal modes in terms of surface waves, which was used in the development ofM _m, upholds the validity of the algorithm for distances as short as 1.5°. This is confirmed by the analysis of a dataset of 149 GEOSCOPE records obtained at distances ranging from 1.5 to 15°, from earthquakes with moments between 10²⁴ and 2.5×10²⁷ dyn-cm. The performance ofM _m as measured in terms of average residual with respect to published values ofM ₀, and standard deviation of the residuals, is not degraded in this distance range, with respect to the teleseismic case. This indicates that the mantle magnitudeM _mcan be reliably used at regional distances, notably for tsunami warning applications.  相似文献   

陕北鄂尔多斯盆地埋藏变质作用研究   总被引：11，自引：2，他引：11  

张立飞 《地质学报》1992,66(4):339-349

本文系统地研究了陕北鄂尔多斯盆地的埋藏变质作用。砂岩胶结物在成岩到变质作用转化过程中经历了如下4个阶段:1.粘土胶结阶段;2.压溶长石、石英再生长阶段;3.碳酸盐胶结阶段;4.生成浊沸石阶段。泥岩中粘土矿物组合在埋藏变质过程中出现如下转化:早期蒙皂石、高岭石组合,随埋深的增加转化为伊利石和镁铝蛇纹石混合阶段;进一步埋深出现了伊利石和绿泥石混层阶段;最后转化为分散状的伊利石和绿泥石。  相似文献   

EXTRACTION OF THE STANDARD ENTHALPY OF FORMATION OF MINERALS FROM REVERSED EXPERIMENTAL DATA WITH INS     

Yin Huian Han Wenxi Lu Cheng Wang Yunliang 《矿物岩石》1992,(4)

An improvement on the new method of Intervalhalving-Scanning (INS) proposed by the senior author for derivation of thermodynamic properties of minerals from reversed experiment (REP) data has been made in the present work. The treatment of the REP data of 6 reactions in the system MgO-SiO_2-H_2O and the derivation of △_(?)H(?) (298. 15K) for minerals Talc,Forsterite and Anthophyllite are chosen as an example for demonstration of the application of the method.INS is quite different from all the methods for the derivation in the literature and throughout based on thermodynamic principles and equations so that its thermodynamical validity is thoroughgoing.  相似文献   

我国一些铜镍硫化物矿床主要金属矿物的特征   总被引：7，自引：0，他引：7  

陈殿芬 《岩石矿物学杂志》1995,14(4):345-354

镍、铜共生的铜镍硫化物矿床是镍矿也是铜矿的重要矿床类型。磁黄铁矿，镍黄铁矿、黄铜矿是这类矿床的主要金属矿物。它们的某些矿物学特征，特别是微量元素Ｃｏ／Ｎｉ比值，与其他铜矿类型明显不同，这三种矿物组成不同于任何其他铜矿类型的典型矿物共生组合， 形成特殊的海绵损铁状、球滴状构造。  相似文献   

瑞典硫化物矿山尾矿淋滤水的控制     

Axel.  CL 乔永胜 《煤田地质与勘探》1993,21(1):49-53

在瑞典,硫化物矿尾矿污染水的淋滤造成巨大的环境污染问题。本文概述一项利用天然土覆盖尾矿、最大限度地减少淋滤水的调查报告。研究表明,天然土渗水性是如此之高,以致于起不到明显的隔水效果。天然土盖层只能减少高降雨量期或迅速化雪期的渗水量,而且只对淋滤水峰值有作用。但是,作为一种蓄水体,位于尾矿顶部的密封盖层具有重要意义,它可以增加蒸腾损失。  相似文献   

祁连山蛇绿岩型超镁铁岩铬铁矿床成矿的主要特征   总被引：4，自引：0，他引：4  

苟国朝  田培昭等 《甘肃地质》1993,2(1):35-45

祁连山造山带目前已发现不同规模的超镁铁岩体（群）1000余个,产有铬铁矿床（点）和矿化点80余处,这些岩体及其矿产主要产在北祁连优地斜增生地体边部的海沟带中,少数产在祁连中间地块的边部。岩体成因类型为蛇绿岩组合中的超镁铁质单元,铬铁矿的富集部位是地幔橄榄岩和堆积杂岩带底部的纯橄榄岩。岩石多为铝过饱和系列,岩体的平均化学成分接近于斜辉橄榄岩;Cr₂0₃的平均含量大于0.40％,Al₂0₃的平均含量近于或者大于1％。铬尖晶石的化学参数特征反映出低铁富镁的介质对形成富铬尖晶石是有利的。富铬岩体中Cr、Co、Ti、V的含量较高。  相似文献   

Weathering of sulfidic shale and copper mine waste: secondary minerals and metal cycling in Great Smoky Mountains National Park,Tennessee, and North Carolina,USA   总被引：6，自引：0，他引：6  

Jane?M.?HammarstromEmail author  Robert?R.?SealII  Allen?L.?Meier  John?C.?Jackson 《Environmental Geology》2003,45(1):35-57

Metal cycling via physical and chemical weathering of discrete sources (copper mines) and regional (non-point) sources (sulfide-rich shale) is evaluated by examining the mineralogy and chemistry of weathering products in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA. The elements in copper mine waste, secondary minerals, stream sediments, and waters that are most likely to have negative impacts on aquatic ecosystems are aluminum, copper, zinc, and arsenic because these elements locally exceed toxicity guidelines for surface waters or for stream sediments. Acid-mine drainage has not developed in streams draining inactive copper mines. Acid-rock drainage and chemical weathering processes that accompany debris flows or human disturbances of sulfidic rocks are comparable to processes that develop acid-mine drainage elsewhere. Despite the high rainfall in the mountain range, sheltered areas and intermittent dry spells provide local venues for development of secondary weathering products that can impact aquatic ecosystems.Electronic Supplementary Material  Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.

Jane M. HammarstromEmail: Phone: +1-703-6486165Fax: +1-703-6486252

  相似文献