内蒙古温都尔庙和巴彦敖包-交其尔蛇绿岩的元素与同位素地球化学：对古亚洲洋东部地幔域特征的限制   总被引：2，自引：5，他引：2  

黄金香赵志丹  张宏飞侯青叶陈岳龙  张本仁DEPAOLO DJ 《岩石学报》2006,22(12):2889-2900

内蒙古中部发育的三条蛇绿岩带是华北板块和西伯利亚板块之间的缝合带。本文系统研究了其中的温都尔庙和巴彦敖包-交其尔两个蛇绿岩带中变质玄武岩的元素和 Sr、Nd、Pb 同位素地球化学。苏右旗温都尔庙碱性玄武岩为轻稀土富集型;岩石具有板内和大陆裂谷区玄武岩的特征,可能代表了600Ma 左右,温都尔庙地区开始发育的新洋盆。采自苏左旗的巴彦敖包-交其尔玄武岩分为两类,一类呈现轻稀土富集型,呈洋岛玄武岩特征;另一类具有明显的 Nb、Ta 负异常,显示大洋岛弧玄武岩特征,洋岛玄武岩的存在表明古亚洲洋曾经发育洋盆,大洋岛弧玄武岩的存在表明古亚洲洋内部有大洋岩石圈之间的俯冲。将本文的古亚洲洋洋岛玄武岩与中国西南地区的特提斯洋岛玄武岩进行系统的元素和同位素地球化学特征对比表明,古亚洲洋的洋岛玄武岩显示高 U/Pb(HU)和北大西洋和太平洋省的特征,而特提斯洋岛玄武岩属于印度洋省。这些说明古亚洲洋地幔域与特提斯地幔域是两个独立的构造域,它们代表了长期演化的两个不同的地幔地球化学域。  相似文献   

Galvanic interactions between galena–sphalerite and their reactivity     

G. Urbano  A.M. Meléndez  V.E. Reyes  M.A. Veloz  I. González 《International Journal of Mineral Processing》2007

The galvanic effect between the main associated mineralogical phases in a mineral sphalerite concentrate was evaluated using an alternative methodology. Comparative voltammetric studies were performed between high purity galena mineral (94.65%) and sphalerite concentrate (content of 78.11% sphalerite, ZnS; 13.64% galena, PbS; 0.57% chalcopyrite, CuFeS₂; 0.41% cadmium sulfide, CdS; and 0.11% arsenopyrite, FeAsS) using carbon paste electrodes (CPE) in order to identify galvanic interactions that affect their reactivity. The electrolyte was an aqueous solution of 0.1 M NaNO₃ (pH 6.5). The results showed that, in sphalerite concentrate, the electrochemical reactivity of the galena was diminished and displaced to more positive potentials with respect to the high purity galena mineral response. This behavior can be attributed to the galvanic protection offered by the sphalerite on the galena, thereby avoiding its free oxidation. On the other hand, sphalerite oxidation was diminished by the formation of a passive products film that is dissolved to more positive potentials which provokes oxidation of other minerals like CuFeS₂, (Zn,Cd)S and FeAsS present in a minor proportion in the sphalerite concentrate.  相似文献   

新疆库车凹陷侏罗系多粒级黏土矿物分析方法及其对沉积-成岩环境的指示     

吴朝东  王琪琪冯雪 顾萧 《岩石学报》2007,23(7):1655-1663

本文选取库车坳陷侏罗系阿合组—齐古组的碎屑岩样品,利用 Stokes 原理,通过同步跟进与离心分析相结合的多粒级提取的方式提取不同粒径的黏土矿物,包括>20μm;20μm～5μm;5μm～2μm;2μm～0.2μm和<0.2μm。不同粒径组分的黏土矿物呈现出不同的型貌特征,在20～2μm范围内的样品中,自生黏土矿物少见,大量可见碎屑来源的黏土矿物,由于经过了长期的机械搬运,难见完整的晶型。在<2μm的样品中大量存在自生黏土矿物,大量成集合体,同时也存在碎屑蚀变成因的黏土矿物。通过 XRD 方法定量分析了所分离出的不同粒径黏土矿物的相对含量,黏土粒径范围内的黏土矿物相对含量呈现些规律变化。碎屑伊利石含量有随着粒级的减小而减少的趋势,而自生伊利石和伊蒙混层只在2～0.2μm及0.2μm以下粒级才出现,并且集中在0.2μm以下粒级范围内;在古气候,沉积环境和母岩特性及分布基本一致的情况下,高岭石的分布有随着岩性的变粗呈现升高的趋势,而伊利石呈负相关关系。碎屑岩中黏土矿物的形貌特征表明,黏土矿物有陆源碎屑来源与自生两种成因,应用 Decoform 软件对0.2μm以下黏土矿物中不同成因的伊利石进行了计算,并就存在的比例与粒径的关系进行了讨论。黏土矿物组合揭示侏罗纪沉积环境由酸性环境向微碱性环境过渡,早侏罗世和中侏罗世早期为气候潮湿时期,高岭石的含量明显高于侏罗世晚期地层,恰克马克期到齐古期高岭石含量开始出现减小的趋势。从恰克马克期开始,气候缓慢向干旱变化,高龄石含量降低,而伊利石的平均含量明显增加,反映黏土矿物组合主要受沉积环境和成岩作用共同影响。  相似文献   

铵(氮)在岩石和矿物中地球化学行为研究进展          下载免费PDF全文

谢建成  杨晓勇 《地质找矿论丛》2007,22(1):1-8

地壳中的氮大都以NH4 储存在矿物中.由于成岩时含氮有机物质的分解作用,氮广泛分布在沉积岩和低级变质岩中;在岩浆岩和变质岩中,氮主要以NH4 存在于含钾硅酸盐(长石和云母类)中;岩浆岩的δ(15N)值和氮浓度明显地不同于沉积物和变沉积岩,主要是由于有机物的缺乏.具有明显铵含量的火成岩主要是含钾矿物的深成岩.因而NH4 可以作为一个"示踪元素"而用于成矿作用等方面的研究.文章还提出了未来的研究方向.  相似文献   

Using magnetic susceptibility to find Precambrian impact ejecta: A proposal     

Dallas Abbott  Rajat Mazumder 《Gondwana Research》2007,12(4):571-575

Layers with high magnetic susceptibility contain heavy minerals that are the most likely to preserve signatures of impact in metamorphosed Precambrian rocks. The following impact indicators are resistant to alteration and metamorphism and are likely to be found in heavy mineral layers: impact diamond, SiC, shocked zircon, high-pressure TiO₂ phases, reidite, and high-pressure chromite. Coesite and stishovite could also be present but are not likely to be preserved in rocks metamorphosed above the greenschist facies. Looking for layers with high magnetic susceptibility will also identify layers that might contain concentrations of zircon for dating.  相似文献   

Modification of the subcontinental mantle beneath East Serbia: Evidence from orthopyroxene-rich xenoliths     

Vladica Cvetkovi&#x;  Marina Lazarov  Hilary Downes  Dejan Prelevi&#x; 《Lithos》2007,94(1-4):90-110

Orthopyroxene-rich olivine websterite xenoliths (OWB₂) in Palaeogene basanites in East Serbia are mostly composed of tabular low-Al₂O₃ orthopyroxene (> 70 vol.%, Mg# 85–87) containing tiny Cr spinel inclusions. Orthopyroxene shows a slightly U-shaped primitive mantle-normalized trace element pattern with strong peaks at U and Pb, similar to that of orthopyroxene from normal regional peridotitic mantle. In between the orthopyroxenes are interstitial spaces composed of partially altered olivine (Mg# 85–87), clinopyroxene, Ti-rich spinel, Mg-bearing calcite, K-feldspar, apatite, ilmenite and relicts of a hydrous mineral. Clinopyroxene appears as selvages around orthopyroxene and as coarser euhedral crystals. Trace element patterns of the clinopyroxene selvages resemble those of adjacent orthopyroxene, whereas the coarser ones have flatter and more LREE- and LILE-enriched patterns, similar to that of metasomatic clinopyroxene. The OWB₂ xenoliths are interpreted as having formed in two stages. During Stage I orthopyroxene crystallized, along with some spinel, olivine and probably hydrous phase(s). This original OWB₂ lithology was a hydrous olivine-bearing orthopyroxenite that crystallised from subduction-related SiO₂-saturated, boninite-like magmas. During Stage II the interstitial minerals formed due to infiltration of a low-SiO₂, high-CaO and CO₂-rich external melt, accompanied by decomposition of original H₂O-bearing minerals. The calculated composition of the infiltrating liquid corresponds to a mafic alkaline melt similar to the basanitic host but more enriched in CO₂, LREE and LILE. Metasomatism is interpreted in terms of small degree melts related to the Palaeogene mafic alkaline magmatism.  相似文献   

Metasomatism and sulfide mobility in lithospheric mantle beneath eastern Australia: Implications for mantle Re–Os chronology     

William Powell  Suzanne O''Reilly 《Lithos》2007,94(1-4):132-147

Spinel lherzolite xenoliths from Tertiary basaltic host magmas at Allyn River, eastern Australia reveal two distinct petrographic and geochemical types. One group is distinguished by xenoliths with undeformed, equilibrated microstructures and interstitial melt patches; The second group shows deformation and contains abundant fluid inclusions but no melt patches. Trace-element signatures of clinopyroxene in these xenoliths provide evidence for metasomatism by a silicate agent with hydrous component and by a carbonate-rich agent respectively.

Melt patches in the undeformed xenoliths contain secondary minerals including clinopyroxene, olivine, feldspar, Mg- and Ca-rich carbonate, apatite, ilmenite and spinel. They are interpreted to represent volatile-rich melt captured shortly prior to entrainment in the host basalt. Sulfide globules, now recrystallised to discrete sulfide phases but inferred to be molten at lithospheric mantle T and P, are closely associated with the melt patches. The close association between sulfide and highly mobile, volatile-bearing fluid has important implications for the mobility of Re and Os, the use of their isotopes in dating mantle events, and the possible effect of volatile-bearing metasomatic agents on their composition.  相似文献   

Calcio-carbonatite melts and metasomatism in the mantle beneath Mt. Vulture (Southern Italy)     

Gianluigi Rosatelli  Frances Wall  Francesco Stoppa 《Lithos》2007,99(3-4):229-248

At Mt. Vulture volcano (Basilicata, Italy) calcite globules (5–150 μm) are hosted by silicate glass pools or veins cross-cutting amphibole-bearing, or more common spinel-bearing mantle xenoliths and xenocrysts. The carbonate globules are rounded or elongated and are composed of a mosaic of 2–20 μm crystals, with varying optical orientation. These features are consistent with formation from a quenched calciocarbonatite melt. Where in contact with carbonate amphibole has reacted to form fassaitic pyroxene. Some of these globules contain liquid/gaseous CO₂ bubbles and sulphide inclusions, and are pierced by quench microphenocrysts of silicate phases. The carbonate composition varies from calcite to Mg-calcite (3.8–5.0 wt.% MgO) both within the carbonate globules and from globule to globule. Trace element contents of the carbonate, determined by LAICPMS, are similar to those of carbonatites worldwide including ΣREE up to 123 ppm. The Sr–Nd isotope ratios of the xenolith carbonate are similar to the extrusive carbonatite and silicate rocks of Mt. Vulture testifying to derivation from the same mantle source. Formation of immiscibile silicate–carbonatite liquids within mantle xenoliths occurred via disequilibrium immiscibility during their exhumation.  相似文献   

North-south transfer zones and paleo-morphological reconstruction of the Xylokastro area (Corinth Gulf, Greece)     

Joachim Place  Yves Graud  Marc Diraison  Laurence Warr 《Tectonophysics》2007,440(1-4):121-139

A large number of studies have documented the structural and sedimentary architecture of the Corinth Gulf, especially the major E–W trending normal faults important in accommodating the main extensional strain and associated growth of the Gilbert fan deltas. However, the role of several N–S oriented structures that crop out at the surface and are detectable at depth by seismic reflection and gravity surveys are not clearly understood. Based on new geological data, collected near Xylokastro, we describe the N–S oriented tectonic activity of this area. The mapped inland faults correspond to off-shore structures identified in re-interpreted seismic lines and appear to have acted as a major transfer zone during the opening of the Corinth Gulf. Reconstruction of the paleo-topography based on sedimentary facies and the environment of clay mineral formation suggest these transfer zones played an important role in controlling both local structural relief and depositional conditions of the Gilbert fan deltas.  相似文献   

对橄榄石相变形核率的估算          下载免费PDF全文

王曙光  宁杰远  叶国扬  楼小挺  刘平江 《地球物理学报》2007,50(1):122-125

地幔主要矿物橄榄石［(Mg089Fe011)2SiO4］的相变与深源地震的解释以及俯冲带和周围地幔的相互作用相关. 其中，形核率和长大率是刻画其相变动力学的两个重要参数. 因为实验技术的原因，目前人们还没有基于实验数据给出橄榄石的形核率. 本文首先通过对挤碰物理图像的分析，对边界形核情形的相变动力学理论中表征挤碰程度的无量纲参数进行了修正. 在此基础上，根据已有的实验资料，首次对橄榄石相变的形核率进行了估计. 通过对形核率数据的拟合，可以得到形核率参数K0和γ1/3. 得到两个形核率参数的变化范围分别为K0=55×1021～87×1027s-1·m-2·K-1，γ1/3=0～020 J·m-2，最佳拟合值为：K0=69×1024s-1·m-2·K-1，γ1/3=016 J·m-2.  相似文献