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91.
Abstract

A simplified method has been developed for solving leaky aquifer non-Darcian flow hydraulics. The principle of volumetric approach is combined with the confined-aquifer, time-dependent drawdown equation in an observation well. The groundwater flow in the leaky aquifer is assumed to obey a non-Darcian flow law of exponential type. The results are obtained in the form of type-curve expressions from which the necessary bundles of curves are drawn for a set of selective non-Darcian flow aquifer parameters. Although application of the methodology appears as rather limited but it provides a scientific contribution and extension of leaky aquifer theory towards nonlinear flow conditions. The methodology developed herein is applied to some actual field data from the eastern sedimentary basin in the Kingdom of Saudi Arabia.  相似文献   
92.
Abstract

Modelling of the rainfall–runoff transformation process and routing of river flows in the Kilombero River basin and its five sub-catchments within the Rufiji River basin in Tanzania was undertaken using three system (black-box) models—a simple linear model, a linear perturbation model and a linear varying gain factor model—in their linear transfer function forms. A lumped conceptual model—the soil moisture accounting and routing model—was also applied to the sub-catchments and the basin. The HEC-HMS model, which is a distributed model, was applied only to the entire Kilombero River basin. River discharge, rainfall and potential evaporation data were used as inputs to the appropriate models and it was observed that sometimes the system models performed better than complex hydrological models, especially in large catchments, illustrating the usefulness of using simple black-box models in datascarce situations.  相似文献   
93.
The Lanping basin is a significant Pb–Zn–Cu–Ag mineralization belt of the Sanjiang Tethyan metallogenic province in China. Over 100 thrust-controlled, sediment-hosted, Himalayan base metal deposits have been discovered in this basin, including the largest sandstone-hosted Pb–Zn deposit in the world (Jinding), and several Cu ± Ag ± Co deposits (Baiyangping, Baiyangchang and Jinman). These deposits, with total reserves of over 16.0 Mt Pb + Zn, 0.6 Mt Cu, and 7000 t Ag, are mainly hosted in Meso-Cenozoic mottled clastic rocks, and strictly controlled by two Cenozoic thrust systems developed in the western and eastern segments of the Lanping basin.To define the metallogenic history of the study area, we dated nine calcite samples associated with copper sulfides from the Jinman Cu deposit by the Sm–Nd method and five molybdenite samples from the Liancheng Cu–Mo deposit by the Re–Os method. The calcite Sm–Nd age for the Jinman deposit (58 ± 5 Ma) and the molybdenite Re–Os age for the Liancheng deposit (48 ± 2 Ma), together with previously published chronological data, demonstrate (1) the Cu–Ag mineralization in the western Lanping basin mainly occurred in three episodes (i.e., ∼56–54, 51–48, and 31–29 Ma), corresponding to the main- and late-collisional stages of the Indo–Asian orogeny; and (2) the Pb–Zn–Ag (±Cu) mineralization in the eastern Lanping basin lacked precise and direct dating, however, the apatite fission track ages of several representative deposits (21 ± 4 Ma to 32 ± 5 Ma) may offer some constraints on the mineralization age.  相似文献   
94.
The semi-Lagrangian procedure is widely used for updating the fully-nonlinear free surface in the time domain. However, this procedure is only available to cases when the body surface is vertical near the waterline. Present study introduces an improved semi-Lagrangian procedure which removes this ‘vertical-wall’ limitation. Coupling with the boundary element method, the improved semi-Lagrangian procedure is applied to the simulation of fully-nonlinear sloshing waves in non-wall-sided tanks. From the result comparison with the open source CFD software OpenFOAM, it is confirmed that this numerical scheme could guarantee a sufficient accuracy. Further series studies on 2D and 3D fully-nonlinear sloshing waves in wedged tanks are performed. Featured phenomena are observed which are distinct from those in wall-sided tanks.  相似文献   
95.
The Basque–Cantabrian Basin (NE Spain) has been considered one of the most interesting areas for hydrocarbon exploration in the Iberian Peninsula since the 60th to 70th of last century. This basin is characterized by the presence of numerous outcrops of tar sands closely associated with fractures and Triassic diapirs. The aims of this work is to establish the diagenetic evolution of the Upper Cretaceous reservoir rocks with special emphasis in the emplacement of oil and their impact on reservoir quality. The studied rocks are constituted of carbonates and sandstones that contain massive quantities of bitumen filling vugs and fractures.Petrographic results indicate that the carbonate rocks from Maestu outcrops are bioclastic grainstones and wackestones, whereas the tar sandstones from Atauri and Loza outcrops are dominated by quartzarenites and subordinated subarkoses. The paragenetic sequence of the main diagenetic phases and processes include, pyrite, bladed and drusy calcite cement, calcite overgrowths, silicification of bioclasts and microcrystalline rhombic dolomite cement, and first stage of oil emplacement, blocky calcite cement, coarse crystalline calcite cement, calcitized dolomite, calcite veins, saddle dolomite and stylolites filled by the second phase of oil entrance. Together with the above mentioned diagenetic alterations, the arenites are affected by early kaolinitization of feldspars and the scarce formation of clay rim and epimatrix of illite. All sandstones and dolomitized carbonate rocks show high intercrystalline and intergranular porosity which is full by biodegraded hydrocarbons (solid bitumen). The biodegradation affects alkanes, isoprenoids and partially hopanes and steranes saturated hydrocarbons. Aromatics hydrocarbons, like naphthalenes, phenanthrenes, dibenzothiophenes and triaromatics are also affected by biodegradation. Results indicate that the first HC emplacement corresponds to early stage of calcite and dolomite cementation, and the second and more important emplacement is related to fracturation processes resulting in the formation of excellent reservoirs.  相似文献   
96.
The development and transfer of clean energy technologies to achieve universal energy access is challenging due to the inherent complexities of the energy sector, and the energy governance and financial systems in developing economies. Innovation is an essential part of successfully addressing these difficulties. Duplicating the energy infrastructure models of developed countries will not be sufficient to meet the needs of poor consumers. To the extent that innovation can accelerate energy access, it is important to understand the specific types of innovations that are necessary and how they might be facilitated. The general features of existing international clean energy innovation systems, which are predominantly driven by the markets and emissions reduction mechanisms of developed and rapidly growing emerging economies, are reviewed and the alignment of these systems to the innovation processes required to extend energy access globally is evaluated. Drawing on the innovation policy literature, the attributes of effective international and domestic energy innovation systems that are pro-poor and the associated policy approaches are identified.  相似文献   
97.
Scientists’ ideas, beliefs, and discourses form the frames that shape their choices about which research to pursue, their approaches to collaboration and communicating results, and how they evaluate research outputs and outcomes. To achieve ocean sustainability, there are increasing calls for new levels of engagement and collaboration between scientists and policy-makers; scientists’ willingness to engage depends on their current and evolving frames. Here, I present results about how scientists involved in diverse fields of ocean research perceived their role as scientists working at or near the ocean science–policy interface and how this related to their perceptions regarding ocean research priorities. The survey of 2187 physical, ecological and social scientists from 94 countries showed that scientists held different perspectives about their appropriate level of engagement at the ocean science–policy interface and the relative primacy of science versus politics in formulating ocean policy. Six clusters of scientists varied in their frames; three clusters accounted for 94% of the sample. Of 67 research questions identified from 22 research prioritization and horizon scanning exercises, the top eight were shared among all three clusters, showing consistency in research priorities across scientists with different framings of their role at the science–policy interface. Five focused on the mechanisms and effects of global change on oceans, two focused on data collection and management for long-term ocean monitoring, and one focused on the links between biodiversity and ecological function at different scales. The results from this survey demonstrated that scientists’ framings of the role of ocean science at the science–policy interface can be quantified in surveys, that framing varies among scientists, and that research priorities vary according to the framings.  相似文献   
98.
Tadao  Nishiyama  Aiko  Tominaga  Hiroshi  Isobe 《Island Arc》2007,16(1):16-27
Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H2O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /LCaOCaO and b = /LMgOMgO) but also on the relative rate P = (−2ξ1ξ2)/(–ξ1 − 2ξ2) of competing reactions: Dol + 2Qtz = Di + 2CO2 (ξ1) and 2Dol + Qtz = Fo + 2Cal + 2CO2 (ξ2). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.  相似文献   
99.
用XRD,SEM和TEM研究新型配合物Cu(C3N2H4)2(C4H5O4)2的超分子结构和微观形貌,并对新型晶体的平衡外形进行模拟计算,结果表明:该配合物分子具有丁二酸桥联的双核铜结构,中心铜离子处在2个咪唑和4个丁二酸以单齿配位组成的八面体中心,在ab平面,分子中有十四元大环,环内Cu(1)-Cu(2)原子间距为0.8031nm,C(2)-C(2′)为0.4183nm;在ac平面,沿着[010]方向分子内呈现凹的六边形纳米级孔洞;沿[100]方向分子依靠弱的氢键作用,层状堆积成三维超分子结构。此外,随着丁二酸的碳链沿[001]方向无限延伸,形成以铜离子为交叉中心的带状拓扑构型。SEM观察到晶体表面形成有明显的凹坑,区域呈现层状阶梯,说明晶体在(100)面遵照台阶-扭折模型呈层状生长结晶。TEM微区形貌像显示晶体存在条纹和缺陷结构,整体保持柱状构型,这与模拟的晶体平衡外形呈柱状一致。模拟结果表明晶体最易外显晶面为(100)面,外显比例达41.247%,这与晶体超分子层沿[100]方向通过氢键作用堆积,键作用力较弱密切相关。  相似文献   
100.
There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems.  相似文献   
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