氧化铬柱支撑蒙脱石的制备研究   总被引：4，自引：1，他引：3  

田淑贵  王冠鑫 《矿物学报》1998,18(4):390-395

以浙江和新疆的膨润土为原料合成了氧化铝柱支撑蒙脱石,成柱溶液以Na2CO3为碱水解铝盐溶液制得。因为制备含有大聚羟基铬阳离子的成柱溶液是获得具有大的基面间距的柱支撑粘土的关键,我们详细研究了CO32-／Cr3＋值、水解温度和水解时间对所得柱支撑蒙脱石性质的影响。聚羟基铬阳离子通过阳离子交换引入蒙脱石,所得产物用X射线衍射分析和BET氮比表面等方法研究。所得氧化铝柱支撑蒙脱石（简称Cr－mont）的基面间距为2．55nm,BET氮比表面积为190～230m2／g。  相似文献   

Assessment of δ13C and C/N ratios in bulk organic matter as palaeosalinity indicators in Holocene and Lateglacial isolation basin sediments,northwest Scotland     

Elizabeth A. V. Mackie  Jeremy M. Lloyd  Melanie J. Leng  Michael J. Bentley  Carol Arrowsmith 《第四纪科学杂志》2007,22(6):579-591

Carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter have recently been used as alternative proxies for relative sea‐level (RSL) reconstruction where there are problems associated with conventional biological indictors. A previous study on a single isolation basin (Upper Loch nan Eala) in northwest Scotland has shown a clear relationship between δ¹³C, C/N ratios and palaeosalinity from Younger Dryas and Holocene aged sediments. In this paper we present results of δ¹³C and C/N ratio analyses from other isolation basins in northwest Scotland over the Holocene and the Lateglacial period in order to validate this technique. The results from the Holocene sequences support the earlier findings that this technique can be used to identify RSL change from isolation basins over the Holocene in this region. The relationship between δ¹³C, C/N ratios and RSL change is not apparent in sediments of Lateglacial age. Other environmental variables such as atmospheric CO₂ concentration, poor vegetation development and temperature influence δ¹³C values during this period. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Bayesian modelling of the cool core galaxy group NGC 4325     

Paul A. Russell  Trevor J. Ponman  Alastair J. R. Sanderson 《Monthly notices of the Royal Astronomical Society》2007,378(4):1217-1228

We present an X-ray analysis of the radio-quiet cool-core galaxy group NGC 4325  ( z = 0.026)  based on Chandra and ROSAT observations. The Chandra data were analysed using xspec deprojection, 2D spectral mapping and forward-fitting with parametric models. Additionally, a Markov Chain Monte Carlo method was used to perform a joint Bayesian analysis of the Chandra and ROSAT data. The results of the various analysis methods are compared, particularly those obtained by forward-fitting and deprojection. The spectral mapping reveals the presence of cool gas displaced up to 10 kpc from the group centre. The Chandra X-ray surface brightness shows the group core to be highly disturbed, and indicates the presence of two small X-ray cavities within 15 kpc of the group core. The xspec deprojection analysis shows that the group has a particularly steep entropy profile, suggesting that an active galactic nucleus (AGN) outburst may be about to occur. With the evidence of prior AGN activity, but with no radio emission currently observed, we suggest that the group in a pre-outburst state, with the cavities and displaced gas providing evidence of a previous, weak AGN outburst.  相似文献   

Recent discoveries of supersoft X‐ray sources in M 31     

M. Henze  W. Pietsch  F. Haberl  G. Sala  M. Hernanz  D. Hatzidimitriou  A. Rau  D.H. Hartmann  J. Greiner  M. Orio  H. Stiele  M.J. Freyberg 《Astronomische Nachrichten》2010,331(2):193-196

Classical novae (CNe) have recently been reported to represent the major class of supersoft X‐ray sources (SSSs) in the central area of our neighbouring galaxy M 31. This paper presents a review of results from recent X‐ray observations of M 31 with XMM‐Newton and Chandra. We carried out a dedicated optical and X‐ray monitoring program of CNe and SSSs in the central area ofM 31. We discovered the first SSSs in M 31 globular clusters (GCs) and their connection to the very first discovered CN in a M 31 GC. This result may have an impact on the CN rate in GCs. Furthermore, in our optical and X‐ray monitoring data we discovered the CN M3 1N 2007‐11a, which shows a very short SSS phase of 29–52 days. Short SSS states (durations ≤ 100 days) of CNe indicate massive white dwarfs (WDs) that are candidate progenitors of supernovae type Ia. In the case of M31N 2007‐11a, the optical and X‐ray light curves suggest a binary containing a WD with M_WD > 1.0 M_⊙. Finally, we present the discovery of the SSS counterpart of the CN M31N 2006‐04a. The X‐ray light curve of M31N 2006‐04a shows short‐time variability, which might indicate an orbital period of about 2 hours (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Origin of Paleofluids in Dabashan Foreland Thrust Belt:Geochemical Evidence of 13C,18O and 87Sr/86Sr in Veins and Host Rocks     

Zeng Jianhui  Xu Tianwu  Sun Zhanqiang  Zhang Yongwang 《《地质学报》英文版》2010,84(5):1239-1255

In the last ten years, with important discoveries from oil and gas exploration in the Dabashan foreland depression belt in the borderland between Shanxi and Sichuan provinces, the relationship between the formation and evolution of, and hydrocarbon accumulation in, this foreland thrust belt from the viewpoint of basin and oil and gas exploration has been studied. At the same time, there has been little research on the origin of fluids within the belt. Based on geochemical system analysis including Z values denoting salinity and research on δ13C, δ18O and 87Sr/86Sr isotopes in the host rocks and veins, the origin of paleofluids in the foreland thrust belt is considered. There are four principal kinds of paleofluid, including deep mantle-derived, sedimentary, mixed and meteoric. For the deep mantle-derived fluid, the δ13C is generally less than ?5.0‰PDB, δ18O less than -10.0‰PDB, Z value less than 110 and 87Sr/86Sr less than 0.70600; the sedimentary fluid is mainly marine carbonate-derived, with the δ13C generally more than ?2.0‰PDB, δ18O less than ?10.0‰PDB, Z value more than 120 and 87Sr/86Sr ranging from 0.70800 to 0.71000; the mixed fluid consists mainly of marine carbonate fluid (including possibly a little mantle-derived fluid or meteoric water), with the δ13C generally ranging from ?2.0‰ to ?8.0‰PDB, δ18O from ?10.0‰ to ?18.0‰ PDB, Z value from 105 to 120 and 87Sr/86Sr from 0.70800 to 0.71000; the atmospheric fluid consists mainly of meteoric water, with the δ13C generally ranging from 0.0‰ to ?10.0‰PDB, δ18O less than ?8.0‰PDB, Z value less than 110 and 87Sr/86Sr more than 0.71000. The Chengkou fault belt encompasses the most complex origins, including all four types of paleofluid; the Zhenba and Pingba fault belts and stable areas contain a simple paleofluid mainly of sedimentary type; the Jimingsi fault belt contains mainly sedimentary and mixed fluids, both consisting of sedimentary fluid and meteoric water. Jurassic rocks of the foreland depression belt contain mainly meteoric fluid.  相似文献   

利用氮氧同位素研究桂林寨底地下河硝酸盐来源   总被引：3，自引：0，他引：3  

王松  裴建国  梁建宏 《地质灾害与环境保护》2010,21(4):54-56,81

工农业生产的迅速发展使地下水硝酸盐氮(NO3-—N)污染成为世界性的环境问题。地下水中硝酸盐的来源研究在水文地质结构特殊的西南岩溶地区就显得尤为重要。稳定氮同位素和氧同位素在地下水硝酸盐的来源示踪研究中有着广泛的应用。本研究选取岩溶地区典型地下河——广西桂林寨底地下河为研究对象,通过氮氧同位素数据,判断寨底地下河硝酸盐来源是以动物粪便为主的农家肥,为该区地下水的保护和利用提供科学依据。  相似文献   

Uptake and recovery of soil nitrogen by bryophytes and vascular plants in an alpine meadow   总被引：2，自引：2，他引：0  

WANG Jin-niu  SHI Fu-sun  XU Bo  WANG Qian  WU Yan  WU Ning 《山地科学学报》2014,11(2):475-484

Due to their particular physiology and life history traits, bryophytes are critical in regulating biogeochemical cycles and functions in alpine ecosystem. Hence, it is crucial to investigate their nutrient utilization strategies in comparison with vascular plants and understand their responses to the variation of growing season caused by climate change. Firstly, this study testified whether or not bryophytes can absorb nitrogen(N) directly from soil through spiking three chemical forms of 15N stable isotope tracer. Secondly, with stronger ability of carbohydrates assimilation and photosynthesis, it is supposed that N utilization efficiency of vascular plants is significantly higher than that of bryophytes. However, the recovery of soil N by bryophytes can still compete with vascular plants due to their greater phytomass. Thirdly, resource acquisition may be varied from the change of growing season, during which N pulse can be manipulated with 15N tracer addition at different time. Both of bryophytes and vascular plants contain more N in a longer growing season, and prefer inorganic over organic N. Bryophytes assimilate more NH4+ than NO3– and amino acid, which can be indicated from the greater shoot excess 15N of bryophytes. However, vascular plants prefer to absorb NO3– for their developed root systems and vascular tissue. Concerning the uptake of three forms N by bryophytes, there is significant difference between two manipulated lengths of growing season. Furthermore, the capacity of bryophytes to tolerate N-pollution may be lower than currently appreciated, which indicates the effect of climate change on asynchronous variation of soil N pools with plant requirements.  相似文献   

低序级断层成像技术在c13地区的应用     

许建国 《海洋地质前沿》2014,(2):56-62

低序级断层在地震剖面上,通常表现为具有微小错动,同相轴扭曲,或者振幅变弱,延伸短、断距小、识别难,描述难等特征。在对采集处理过程中影响低序级断层识别的观测系统面元网格、信噪比、频率、速度误差等因素详细分析的基础上,通过建立全波场正演地质模型,借助方查体属性技术以及井资料,研究了针对性的处理技术。同时利用相干体属性、曲率属性沿层切片、方差体等技术进行有效识别低级序断层,取得了较好的效果。  相似文献   

Trophic ecology of Pomatoschistus microps within an intertidal bay (Roscoff,France), investigated through gut content and stable isotope analyses     

Jean‐Charles Leclerc  Pascal Riera  Laure M.‐L. J. Noël  Cédric Leroux  Ann C. Andersen 《Marine Ecology》2014,35(2):261-270

The diet of Pomatoschistus microps has been studied using both gut content and stable isotope analyses. In the Roscoff Aber Bay (Brittany, France), this fish is commonly found on sandy muddy intertidal flats. Gut content analyses were also interpreted using trophic indices. Owing to the large diversity of prey consumed, these indices emphasised the opportunistic feeding behaviour of P. microps. Here, this species fed mainly on endofauna with meiofauna being of high relative importance. The main biotic components of its trophic habitat, characterized by δ¹³C and δ¹⁵N, provided evidence of a major trophic pathway based on drift Enteromorpha sp. Trophic positions estimated by both diet analyses and isotopic analyses led to similar results. In this bay, P. microps is a first‐order predator with a low degree of omnivory. Despite a preferential consumption of the amphipod Corophium arenarium, we assumed that this goby behaves as a generalist feeding on a uniform variety of endofauna taxa.  相似文献   

白令海颗粒有机物碳、氮同位素组成及其生物地球化学意义   总被引：1，自引：0，他引：1  

林峰  陈敏  童金炉  曹建平  邱雨生  郑敏芳 《海洋学报(英文版)》2014,33(12):40-47

Stable carbon and nitrogen isotopic composition of particulate organic matter(POM) were measured for samples collected from the Bering Sea in 2010 summer. Particulate organic carbon(POC) and particulate nitrogen(PN) showed high concentrations in the shelf and slope regions and decreased with depth in the slope and basin, indicating that biological processes play an important role on POM distribution. The low C/N ratio and heavy isotopic composition of POM, compared to those from the Alaska River, suggested a predominant contribution of marine biogenic organic matter in the Bering Sea. The fact that δ13C and δ15N generally increased with depth in the Bering Sea basin demonstrated that organic components with light carbon or nitrogen were decomposed preferentially during their transport to deep water. However, the high δ13C and δ15N observed in shelf bottom water were mostly resulted from sediment resuspension.  相似文献