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A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO 3 are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO2 in the water and the consequent enhancement of Ca2+ and HCO 3 . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO 4 3− content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.  相似文献   
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The textural and chemical evolution of allanite and monazite along a well‐constrained prograde metamorphic suite in the High Himalayan Crystalline of Zanskar was investigated to determine the P–T conditions for the crystallization of these two REE accessory phases. The results of this study reveals that: (i) allanite is the stable REE accessory phase in the biotite and garnet zone and (ii) allanite disappears at the staurolite‐in isograd, simultaneously with the occurrence of the first metamorphic monazite. Both monazite and allanite occur as inclusions in staurolite, indicating that the breakdown of allanite and the formation of monazite proceeded during staurolite crystallization. Staurolite growth modelling indicates that staurolite crystallized between 580 and 610 °C, thus setting the lower temperature limit for the monazite‐forming reaction at ~600 °C. Preservation of allanite and monazite inclusions in garnet (core and rim) constrains the garnet molar composition when the first monazite was overgrown and subsequently encompassed by the garnet crystallization front. Garnet growth modelling and the intersection of isopleths reveal that the monazite closest to the garnet core was overgrown by the garnet advancing crystallization front at 590 °C, which establishes an upper temperature limit for monazite crystallization. Significantly, the substitution of allanite by monazite occurs in close spatial proximity, i.e. at similar P–T conditions, in all rock types investigated, from Al‐rich metapelites to more psammitic metasedimentary rocks. This indicates that major silicate phases, such as staurolite and garnet, do not play a significant role in the monazite‐forming reaction. Our data show that the occurrence of the first metamorphic monazite in these rocks was mainly determined by the P–T conditions, not by bulk chemical composition. In Barrovian terranes, dating prograde monazite in metapelites thus means constraining the time when these rocks reached the 600 °C isotherm.  相似文献   
35.
The growth and dissolution behaviour of accessory phases (and especially those of geochronological interest) in metamorphosed pelites depends on, among others, the bulk composition, the prograde metamorphic evolution and the cooling path. Monazite and zircon are arguably the most commonly used geochronometers for dating felsic metamorphic rocks, yet crystal growth mechanisms as a function of rock composition, pressure and temperature are still incompletely understood. Ages of different growth zones in zircon and monazite in a garnet‐bearing anatectic metapelite from the Greater Himalayan Sequence in NW Bhutan were investigated via a combination of thermodynamic modelling, microtextural data and interpretation of trace‐element chemical ‘fingerprint’ indicators in order to link them to the metamorphic stage at which they crystallized. Differences in the trace‐element composition (HREE, Y, EuN/Eu*N) of different phases were used to track the growth/dissolution of major (e.g. plagioclase, garnet) and accessory phases (e.g. monazite, zircon, xenotime, allanite). Taken together, these data constrain multiple pressure–temperature–time (P–T–t) points from low temperature (<550 °C) to upper amphibolite facies (partial melting, >700 °C) conditions. The results suggest that the metapelite experienced a cryptic early metamorphic stage at c. 38 Ma at <550 °C, ≥0.85 GPa during which plagioclase was probably absent. This was followed by a prolonged high‐T, medium‐pressure (~600 °C, 0.55 GPa) evolution at 35–29 Ma during which the garnet grew, and subsequent partial melting at >690 °C and >18 Ma. Our data confirm that both geochronometers can crystallize independently at different times along the same P–T path and that neither monazite nor zircon necessarily provides timing constraints on ‘peak’ metamorphism. Therefore, collecting monazite and zircon ages as well as major and trace‐element data from major and accessory phases in the same sample is essential for reconstructing the most coherent metamorphic P–T–t evolution and thus for robustly constraining the rates and timescales of metamorphic cycles.  相似文献   
36.
在特提斯喜马拉雅带东部江孜-康马一带发育大量近东西向展布的辉绿岩体/墙,研究表明这些基性岩至少可分为三期:(1)形成于~140Ma的辉绿岩具有OIB型地球化学特征,部分样品Sr-Nd同位素组成与其东部~132Ma错美-班布里大火成岩省中基性岩相当,部分高镁样品具有Nb-Ta负异常和Pb正异常,εNd(t)值小于0;(2)形成于~120Ma的辉绿岩显示N-MORB型地球化学特征;(3)形成于~90Ma的辉绿岩显示E-MORB型地球化学特征。后两期基性岩的Sr-Nd同位素组成均显示与印度洋MORB相关。结合同时期的Kerguelen地幔柱活动轨迹及东冈瓦纳大陆裂解事件,本文认为江孜-康马地区~140Ma基性岩代表Kerguelen地幔柱及其与上覆东冈瓦纳大陆岩石圈地幔相互作用产物,是Kerguelen地幔柱长期潜伏于东冈瓦纳大陆下的证据,在前人研究基础上将该地幔柱影响的范围从错美向西拓展了约200km;之后随着东冈瓦纳大陆裂解和印度洋的开启及扩张,印度板块逐渐北移并远离Kerguelen地幔柱,江孜-康马地区~120Ma和~90Ma两期基性岩代表新生印度洋软流圈部分熔融的产物,与Kerguelen地幔柱无关。该区识别出的三期基性岩浆活动表明:特提斯喜马拉雅带的东部在白垩纪经历了与东冈瓦纳大陆裂解、印度洋的开启和扩张相关的多期基性岩浆活动。这些基性岩为深入了解和限定特提斯喜马拉雅带自140Ma以来的古地理位置和构造演化过程提供了新的岩石记录和时间坐标。  相似文献   
37.
欧亚与印度大陆的碰撞使得印度大陆的北东角强烈挤入欧亚大陆内部,形成东构造结,其引发的强烈变形将南羌塘地块、北羌塘地块、拉萨地块、保山地块、兰坪-思茅地块以及地块之间的缝合带挤压于很窄的范围内,造成青藏高原腹地与其东南缘之间构造单元划分、对比困难。滇西福贡地区位于青藏高原东南缘,东构造结影响范围内,是三江造山带及青藏高原相关地块的汇聚处。福贡地区石炭系岩石组合表明其形成于较为稳定的浅海相沉积环境中,具有被动大陆边缘沉积特征。三件石炭系二云母石英片岩碎屑锆石表面年龄数据(194个有效分析点)形成五个主要年龄区间:2550~2400Ma、1800~1550Ma、1200~1080Ma、1000~850Ma和600~480Ma,峰值分别为~2502Ma、~1724Ma、~1120Ma、~886Ma和~512Ma。对比其他地块同时代地层的碎屑锆石年龄谱表明,福贡地区石炭系可能是拉萨地块的一部分,与腾冲地块一样,属于其南延部分。结合中新生代岩浆岩带的构造连续性,我们认为,印度板块东北角向北、北东方向的强烈挤压导致拉萨地块及冈底斯岩浆岩带弯曲、缩颈、并发生分离与旋转。  相似文献   
38.
Mafic microgranular enclaves (MMEs) in host granitoids can provide important constraints on the deep magmatic processes. The Oligocene-Miocene granitoid plutons of the NW Anatolia contain abundant MMEs. This paper presents new hornblende Ar-Ar ages and whole-rock chemical and Sr-Nd isotope data of the MMEs from these granitic rocks. Petrographically, the MMEs are finer-grained than their host granites and contain the same minerals as their host rocks (amphibole + plagioclase + biotite + quartz + K-feldspar), but in different proportions. The Ar-Ar ages of the MMEs range from 27.9 ± 0.09 Ma to 19.3 ± 0.01 Ma and are within error of their respective host granitoids. The MMEs are metaluminous and calc-alkaline, similar to I-type granites. The Sr-Nd isotopes of MMEs are 0.7057 to 0.7101 for 87Sr/86Sr and 0.5123 to 0.5125 for 143Nd/144Nd, and are similar to their respective host granitoids. These lithological, petrochemical and isotopic characteristics suggest that the MMEs in this present study represent chilled early formed cogenetic hydrous magmas produced during a period of post-collisional lithospheric extension in NW Anatolia. The parental magma for MMEs and host granitoids might be derived from partial melting of underplated mafic materials in a normally thickened lower crust in a post-collisional extensional environment beneath the NW Anatolia. Delamination or convective removal of lithospheric mantle generated asthenospheric upwelling, providing heat and magma to induce hydrous re-melting of underplated mafic materials in the lower crust.  相似文献   
39.
The influence of the North Atlantic on the margins of Europe means the region is particularly sensitive to changes in the ocean–atmospheric system. During the Last Glacial–Interglacial Transition (16–8 cal ka bp ) this system was repeatedly disrupted, leading to a series of abrupt and short-lived shifts in climate. Despite much research, the number and magnitude of these ‘centennial-scale’ events is not well understood. To address this, we expand upon investigations at Quoyloo Meadow, Orkney, Scotland, one of the best chronologically constrained palaeoclimate records in northern Britain. By coupling stable isotope and chironomid fossil analyses with existing data, this study identifies multiple phases of centennial-scale disturbance at: c. 14.0, 11.1, 10.8, 10.5, 10.45 and 10.3 cal ka bp , with the events at 14.0 and 10.3 exhibiting a particularly pronounced cold-climate signature. During the Holocene, the strongest response to climate forcing was at c. 10.3–10.0 cal ka bp , expressed as a two-stage drop in mean July temperatures, a shift in pollen spectra indicative of ‘less-stable’ climatic regimes, and a depletion in δ18O values. We interpret this as the first reliably dated incidence of the ‘10.3-ka event’ in the British Isles and consider the wider impact of this climatic reversal in other Holocene records.  相似文献   
40.
稀有金属矿物记录了花岗伟晶岩成岩成矿的重要信息。喜马拉雅是全球著名的淡色花岗岩带,库曲岩体位于喜马拉雅东段的特提斯喜马拉雅岩系中。本文调查了库曲岩体的二云母花岗岩、白云母花岗岩、电气石花岗岩和花岗伟晶岩,其中,花岗伟晶岩涉及花岗岩的伟晶岩相和独立伟晶岩脉。库曲岩体产出的稀有金属矿物包括锂辉石、锂绿泥石、绿柱石、铌铁矿-钽铁矿、钇铀钽烧绿石和细晶石,它们主要赋存于似文象伟晶岩、石英-钠长石-白云母伟晶岩、块体长石-钠质细晶岩、块体长石-电气石钠质细晶岩、锂辉石-块体长石-细晶岩、白云母花岗岩的伟晶岩相以及电气石花岗岩内。显微镜观察、电子探针和LA-ICP-MS测试结果显示锂辉石具有四种产状,包括粗粒锂辉石自形-半自形晶、细粒锂辉石-石英镶嵌晶、中细粒锂辉石-钾长石-钠长石-云母镶嵌晶以及发育锂绿泥石的粗粒锂辉石,揭示了其形成时复杂的熔流体动荡结晶环境。绿柱石背散射电子图像(BSE)下呈均一结构和不均一结构(蚀变边、不规则分带和补丁分带),元素替代机制包括通道-八面体替代、通道-四面体替代以及通道中碱金属阳离子间的置换。铌铁矿族矿物包括原生、蚀变边和不规则分带结构,部分被钇铀钽烧绿石和细晶石交代。与原生铌铁矿相比,蚀变边和不规则分带铌铁矿族矿物总体上富钽贫锰,显示了结晶分异、过冷却引起的过饱和以及流体作用。根据稀有金属矿物揭示的成因信息,独立伟晶岩脉(似文象伟晶岩)、白云母花岗岩的伟晶岩相和电气石花岗岩在岩浆分异程度、经历的演化过程、以及流体活动方面存在差异,很可能是不同期次岩浆活动的产物。库曲岩体绿柱石的Rb和Zn含量、以及铌铁矿族矿物的Sc2O3、SiO2和PbO含量,与已有指示标志存在相关性,作为潜在指示标志仍需开展更多的研究工作。综合含锂辉石伟晶岩的产出、岩浆分异演化程度、多期花岗质岩浆活动、复杂的流体作用以及所属锂丰度高值区等因素,库曲岩体是喜马拉雅东段找锂的有利地段。  相似文献   
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