利用氮同位素技术识别石家庄市地下水硝酸盐污染源   总被引：36，自引：2，他引：36  

张翠云  张胜  李政红  刘少玉 《地球科学进展》2004,19(2):183-191

地下水NO－ 3污染是石家庄市地下水管理面临的一个主要问题。本次研究通过地下水及其潜在补给源的氮同位素和水化学调查，确定和识别石家庄市地下水NO－ 3污染程度和污染源。地下水中的无机氮化合物主要以NO－ 3形式存在，浓度变化在 2．65～152．1 m g／L之间，均值为（54．88± 31）m g／L（ n＝44），48％的样品浓度超过国际饮水标准（50 m g／L）。地下水样品的NO－ 3－ 15 N值域＋4．53‰～＋25．36‰，均值＋9．94‰±4．40‰（ n＝34）。34个样品中，22个样品（65％）的氮同位素值大于＋8‰；与1991年相比，氮同位素组成指示地下水NO－ 3的主要来源已由当时矿化的土壤有机氮变为现在的动物粪便或污水；结合Cl－分析，南部地下水NO－3还受到东明渠污水的影响。其余12个样品（35％）的氮同位素值变化在＋4‰～＋8‰之间，其中 15 N值较大的（＋6‰～＋8‰）指示来自土壤有机氮，较小的（＋4‰～＋6‰）指示来自氨挥发较弱、快速入渗的化肥厂污水。根据上述研究结果，提出了改善石家庄市地下水管理的措施。  相似文献   

Assessment of the atmospheric nitrogen and sulphur inputs into the North Sea using a Lagrangian model     

O. Hertel  C. Ambelas Skjøth  L.M. Frohn  E. Vignati  J. Frydendall  G. de Leeuw  Uwe Schwarz  Stefan Reis 《Physics and Chemistry of the Earth》2002,27(35):1507-1515

The atmospheric chemistry and deposition model has been applied for calculation of nitrogen and sulphur depositions to the entire North Sea area for the year 1999. The total atmospheric nitrogen and sulphur depositions to the North Sea area were determined to 709 kton (kt) N and 551 kt S, respectively. Since the North Sea area was calculated to be 747,988 km², this is equivalent to an average deposition of 0.9 ton N km^?2 and 0.7 ton S km^?2, respectively. The depositions decrease strongly from the south end (about 2–3 kt N km^?2) to the north end (about 0.2 kt N km^?2) of the North Sea, due to increasing distance to the large source areas in the northern part of the European continent. The territorial waters of Belgium, the Netherlands and Germany receive about 50% higher deposition densities than the average value for the entire North Sea area. For the remaining territorial waters of the North Sea the depositions follow more or less the fraction of the area. The results furthermore show that about 60% of the total nitrogen deposition is related to emissions from combustion sources (nitrogen oxides) and about 40% from emissions related to agricultural activities (ammonia).  相似文献   

闪电产生氮氧化物（LNOX）区域特征计算（I）：理论和计算方法   总被引：2，自引：8，他引：2  

张义军  言穆弘等 《高原气象》2002,21(4):348-353

介绍了目前关于闪电产生氮氧化物（MOX）的研究概况，包括产生机理、特征、输运过程以及在全球气候变化中的作用。重点叙述了发生在区域性雷暴中闪电产生氮氧化物的机制、传输以及计算方法和可能误差，并对闪电产生氮氧化物区域特征计算方法和参数的选取作了简要介绍。  相似文献   

Carbonic inclusions   总被引：17，自引：0，他引：17  

Alfons Van den Kerkhof  Rgis Thiry 《Lithos》2001,55(1-4):49-68

The paper gives an overview of the phase relations in carbonic fluid inclusions with pure, binary and ternary mixtures of the system CO₂–CH₄–N₂, compositions, which are frequently found in geological materials. Phase transitions involving liquid, gas and solid phases in the temperature range between −192°C and 31°C are discussed and presented in phase diagrams (PT, TX and VX projections). These diagrams can be applied for the interpretation of microthermometry data in order to determine fluid composition and molar volume (or density).  相似文献   

The partitioning of nitrogen oxides in the lower Arctic troposphere during spring 1988     

Jan W. Bottenheim  Leonard A. Barrie  Elliot Atlas 《Journal of Atmospheric Chemistry》1993,17(1):15-27

Surface observations of several nitrogen oxides in the Canadian high Arctic during the period March-April 1988 are reported. These include data on NO₂, the inorganic nitrates HNO₃ and particulate nitrate, and the organic nitrates PAN and C₃–C₇ alkyl-nitrates. It is found that the organic nitrates make up 70–80% of the sum of the measured nitrogen oxides. Based on concurrently measured sulphur oxides, the period of observation was divided into two halves with the first half representing less polluted, more aged air than the second. The preponderance of the organic nitrates was less in the first period than the second. In contrast, there was little difference in the inorganic nitrates and NO₂ concentrations. The dominant inorganic nitrate shifted from particulate nitrate in the first period towards gaseous HNO₃ in the second. No correlation between the nitrates (inorganic or organic) and O₃ was observed; although some indication of a positive correlation between NO₂ and O₃ has been reported earlier (Bottenheimet al., 1990). Possible explanations for these observations are proposed. A survey of other potential nitrogen oxides that may be present in the Arctic air but not measured in these experiments suggests that the nitrogen oxides not measured here constitute a minor fraction of the total reactive nitrogen (NO _y ).Paper submitted to the 7th International Symposium of the Commission for Atmospheric Chemistry and Global Pollution on the Chemistry of the Global Atmosphere held in Chamrousse, France, from 5 to 11 September 1990.  相似文献   

Potential nitrate pollution of groundwater in Germany: A supraregional differentiated model     

F. Wendland  H. Albert  M. Bach  R. Schmidt 《Environmental Geology》1994,24(1):1-6

Implemented on behalf of the Federal Ministry for Research and Technology (BMFT), a model is developed to trace the nutrient flow of nitrate in the soil and the groundwater on a supraregional scale. Research work is intended to indicate regionally differentiated hazardous potentials and thereby provide a basis for recommending comprehensive measures to protect groundwater in Germany. The adaption of the model to the hydrogeological and agricultural conditions of other states is possible in principle. This article focuses on the hydrogeological model parts. A high nitrate pollution of groundwater can be expected in all regions with intensive agricultural use of the topsoil. In particular, groundwater in solid rock areas is susceptible to nitrate pollution. There a rapid groundwater turnover and thus a short residence time for the groundwater in the aquifer is typical. Oxidizing aquifer conditions usually prevail in solid rock aquifers, preventing nitrate degradation. In many loose rock areas, in contrast, the groundwater has a low flow velocity and a long residence time in the aquifer. Because of a lack of free oxygen, a complete degradation of nitrate can occur, as long as iron sulfide compounds and/or organic carbon are available in the aquifer. A more detailed presentation of the whole research work is given in Wendland et al. (1993).  相似文献   

Assessing a farmer's decision concerning the application timing of nitrogen fertilizer     

W. -Y. Huang  N. D. Uri  L. Hansen 《Environmental Geology》1994,24(1):43-56

This paper is concerned with a farmer's decision on the timing of nitrogen fertilizer application. Analytical models are developed to determine the necessary conditions for the optimal timing of the application of nitrogen fertilizer. The models, coupled with an estimated cotton yield function, are used to assess a farmer's decision on the optimal application timing of nitrogen fertilizer in cotton production. The empirical results explain various observed application timings of nitrogen fertilizer being used in cotton production in Mississippi, USA, and provide an estimate of the cost to a farmer when he or she must comply with a restriction on the timing of the application of nitrogen fertilizer.The views expressed are those of the authors, and do not necessarily represent the policies of the US Department of Agriculture or the views of other US Department of Agriculture staff members  相似文献   

Isotopic biogeochemistry of dissolved organic nitrogen: A new technique and application   总被引：1，自引：0，他引：1  

Timothy P. Feuerstein  Peggy H. Ostrom  Nathaniel E. Ostrom 《Organic Geochemistry》1997,27(7-8)

We present a new technique for isolating and isotopically characterizing dissolved organic nitrogen (DON) for non-marine waters, δ¹⁵N values for DON from lacustrine samples and data suggesting that this technique will be applicable to marine samples. Our technique involves preconcentration of DON via rotary evaporation and removal of dissolved inorganic nitrogen (DIN) via dialysis using a membrane that retains material above 100 Da. Results demonstrate quantitative removal of DIN, complete recovery of DON (95% or greater) and retention of isotopic integrity (isotope effect less than 0.4‰) for a solution containing a DON standard (tripeptide) and DIN in deionized water. Reproducibility of carbon and nitrogen isotope values and elemental concentrations is demonstrated for DOM from Chefswet Basin, Lake Superior and Grand Traverse Bay, Lake Michigan. The applicability of this technique to marine samples is suggested by demonstrating 99% removal of DIN from a sample of Gulf Stream water amended with ammonium and nitrate.  相似文献   

Disparate history of transgressing planetary boundaries for nutrients     

《Global Environmental Change》2023

The activation of nitrogen and phosphorus for food production has caused the transgression of the safe operating space of the Earth system. However, countries differ in the use of their fair share of global nutrient activation, causing a disparity that has severe implications for the environment, land degradation and food security. Both the impact on Earth system processes as well as productivity gains and losses and the consequent socio-economic impacts depend on past use. Therefore, in this study, we examined how the activation of nitrogen and phosphorus for food production in relation to countries’ fair shares has evolved globally. The first transgressions of the planetary boundaries occurred in 1970 and 1964 for nitrogen and phosphorus, respectively. Since then, activation has increased 160% and 200%, respectively. Further, notable differences were observed between countries, in which high-income regions such as western Europe and North America had the highest cumulative transgression and sub-Saharan Africa and Oceania had the greatest deficit relative to their fair shares. The main driver for transgression was economic growth rather than population growth or the relatively recent fertiliser subsidies. Although the use of fertilisers has decreased in areas with previous high use, past usage will slow down the effects of fertiliser reductions on ecosystem recovery and maintain a legacy of inequality. Consequently, in addition to reductions in nitrogen and phosphorus activation, recycling accumulated nutrients to regions operating below their fair shares should be explored and economically enabled in order to secure Earth system functioning while eradicating hunger.  相似文献   

Correlation between nitrate concentration in groundwater and parameters affecting aquifer intrinsic vulnerability   总被引：3，自引：0，他引：3  

Laura Debernardi  Domenico Antonio De Luca  Manuela Lasagna 《Environmental Geology》2008,55(3):539-558

This paper is the result of a study which was carried out in order to verify if the traditional methods to evaluate the intrinsic vulnerability or vulnerability related parameters, are able to clarify the problem of nitrate pollution in groundwater. In particular, the aim was to evaluate limitations and problems connected to aquifer vulnerability methods applied to nitrate contamination prevision in groundwater. The investigation was carried out by comparing NO₃ ⁻ concentrations, measured in March and November 2004 in the shallow aquifer, and the vulnerability classes, obtained by using GOD and TOT methods. Moreover, it deals with a comparison between NO₃ ⁻ concentrations and single parameters (depth to water table, land use and nitrogen input). The study area is the plain sector of Piemonte (Northern Italy), where an unconfined aquifer nitrate contamination exists. In this area the anthropogenic presence is remarkable and the input of N-fertilizers and zootechnical effluents to the soil cause a growing amount of nitrates in groundwater. This approach, used in a large area (about 10,000 km²) and in several monitoring wells (about 500), allowed to compare the efficiency of different vulnerability methods and to verify the importance of every parameter on the nitrate concentrations in the aquifer. Furthermore it allowed to obtain interesting correlations in different hydrogeological situations. Correlations between depth to water table, land use and nitrogen input to the soil with nitrate concentrations in groundwater show unclear situations: in fact these comparisons describe the phenomenon trend and highlight the maximum nitrate concentrations for each circumstance but often show wide ranges of possible nitrate concentrations. The same situation could be observed by comparing vulnerability indexes and nitrate concentrations in groundwater. These results suggest that neither single parameters nor vulnerability methods (GOD and TOT) are able to describe individually the complex phenomena affecting nitrate concentrations in soil, subsoil and groundwater. In particular, the traditional methods for vulnerability analysis do not analyze physical processes in aquifers, such as denitrification and nitrate dilution. According to a recent study in the shallow unconfined aquifer of the Piemonte plain, dilution can be considered as the main cause for nitrate attenuation in groundwater.  相似文献