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81.
Adiabatic indices for a non-dissipative anisotropic convecting plasma are analyzed, and general expressions for the effective adiabatic index and the partial adiabatic indices parallel (γ∥) and perpendicular (γ⟂) to the magnetic field are obtained. It is shown that, in the general case, the value of the effective adiabatic index is not an universal constant and depends on the plasma temperature anisotropy and on the properties of the plasma motion. The values of γ⟂ and γ∥ are shown to be independent of the plasma parameters being completely determined by the characteristics of the plasma flow. 相似文献
82.
高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素 总被引:4,自引:0,他引:4
An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples. 相似文献
83.
We developed kinetic theory for the charging processes of small dust grains near the lunar surface due to interaction with the anisotropic solar wind plasma. Once charged, these dust grains, which are exposed to the electric field in the sheath region near the lunar surface, could loft and distribute around such heights off the surface where they reach equilibrium with the local gravitational force. Analytical solutions were derived for the charging time, grain floating potential, and grain charge, characterizing the charging processes of small dust grains in a two-component and in a multi-component solar wind plasma, and further highlighting the unique features presented by the high streaming plasma velocity. We have also formulated a novel kinetic theory of sheath formation around an absorbing planar surface immersed in the anisotropic solar wind plasma in the case of a negligible photoelectric effect and presented solutions for the sheath structure. In this study we combined the results from these analyses and provided estimates for the size distribution function of dust that is expected to be lofted in regions dominated by the solar wind plasma, such as near the terminator and in nearby shadowed craters. Corresponding to the two dominant streaming velocity peaks of 300 and 800 km/s, mean dust diameters of 500 and 350 nm, respectively, are expected to be found at equilibrium at heights of relevance to exploration operations, e.g., around 1.5 m height off the lunar surface. In shadowed craters near the terminator region, where isotropic plasma should be dominating, we estimate mean lofted dust diameter of 800 nm around the same 1.5 m height off the lunar surface. The generally applicable solutions could be used to readily calculate the expected lofted size distribution near the lunar surface as a function of plasma parameters, dust grain composition, and other parameters of interest. 相似文献
84.
The reduced magnetic helicity is a quantity related to the handedness of the magnetic field fluctuations. In the present paper we study the scaling law of the reduced magnetic helicity in fast streams in the solar wind by using high-resolution magnetic field data by the Ulysses spacecraft. We show that at high frequencies both the left-hand and the right-hand helicity survives, implying that there is no predominance of a single sign. In addition, the scaling law of the magnetic helicity exhibits a strong dependence on the data set analyzed and we do not observe any universal behavior. 相似文献
85.
Ion waves excited by charged dust beams streaming across or along the geomagnetic field in the ionosphere may be generated by plasma instabilities during aerosol release experiments. The injection speed of the dust and gas is comparable to or larger than the ion thermal speed in the background plasma. The dust grains can get charged by plasma collection from the ambient ionosphere, and can thus act as a charged beam that excites instabilities in the background plasma. The theory is applied to relatively early time scales of the order of in the dust-gas cloud expansion, with wave frequencies that are larger than the ion gyrofrequency, and collisions with neutrals are included. 相似文献
86.
Shang-Song Yang Fangfang Zhang Feng Yuan De-Gao Zhai Yu-Jie Li 《International Geology Review》2017,59(15):1908-1928
West Qinling is one of the most important parts of the Qinling orogenic belt and includes acidic–intermediate plutons and many types of ore deposits. In this article, we collected geochemical and geochronological data for the Triassic granitoid plutons of West Qinling and found that nearly all plutons share the similar features with the Zhongchuan pluton. We present new laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb ages, major and trace element geochemistry, and zircon Hf isotope systematics for the granites of the Zhongchuan pluton to elucidate the evolution of granitoid plutons in West Qinling during the Triassic. LA-ICP-MS zircon U–Pb dating indicates that the Xujiaba and Guandigou units formed at 220.1 ± 1.2 and 215.9 ± 0.85 Ma, respectively, reflecting the time of the Late Triassic. The rocks of the Zhongchuan pluton are metaluminous to weakly peraluminous and have a high-K calc-alkaline to shoshonite series with high SiO2 (63.59–76.22%) and low P2O5 (0–0.2%) concentrations, a high K2O/Na2O ratio (1.18–17.92), a high differentiation index (78.45–93.04) and a medium A/CNK ratio (0.98–1.69). The zircon Hf isotope dating indicates that the Xujiaba and Guandigou units have an inhomogeneous εHf(t) (?4.425 to 1.067 for Xujiaba and ?4.920 to 2.042 for Guandigou) and two-stage Hf model ages (1123–1531 Ma for Xujiaba and 1115–2342 Ma for Guandigou). The geochemical and isotopic data imply that the granites of each unit share the same origin. They probably derived from the partial melt of metagreywackes and then mixed with the mantle-derived magma. Based on the regional geological history, petrographic characteristics and new geochemical and isotopic data of the Zhongchuan pluton, we suggest that the Triassic magma was derived from the partial melts of metagreywackes and was influenced by the mantle-derived melt during the collision of the Yangtze and Qinling plates. 相似文献
87.
88.
电感耦合等离子体质谱(ICP-MS) 测定地质样品中稀土元素的过程中,尤其对于高Ba基体的地质样品,由Ba形成
的氧化物和氢氧化物离子对Eu元素会产生质谱峰的重叠干扰,严重影响Eu测定结果的准确度和精确度。通过标准溶液的
条件实验,测定Ba干扰项相对Ba总量的比例(干扰率) 并进行相应的Eu扣除,是一种解决干扰导致Eu测定结果偏高的思
路。然而该干扰率在不同基质溶液中是否一致,且随着Ba含量变化是否稳定目前尚不明确。本文通过对不同基体溶液中Ba
对Eu干扰率的测定(低分辨模式测定),发现随着溶液中Ba浓度的变化,同一基体溶液中该干扰率较为恒定,而不同基体
溶液中干扰率有明显的差别。这说明在对Eu测定结果进行干扰扣除时,需要利用匹配的基体溶液来获取准确的Ba干扰
率。应用这种方法扣除得到的Eu结果与质谱的高分辨模式(R=10000) 下的测定结果较为一致,数据的重现性也较为理
想。因此,利用基体匹配的方式来进行Ba对Eu的数学扣除是一种可行的方法。 相似文献
89.
Hélène Balcone‐Boissard Agnès Michel Benoît Villemant 《Geostandards and Geoanalytical Research》2009,33(4):477-485
Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l?1 for both F and Cl and 10 ng l?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg?1 for F and Cl and 2 μg kg?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg?1 for F and Cl, 100 μg kg?1 for Br and 25 μg kg?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level. 相似文献
90.
利用THEMIS THC卫星观测数据统计分析近地等离子体片中磁场扰动和等离子体整体流的速度扰动的关系,研究Alfven波动的活动性.研究结果表明:1)等离子体整体流的速度扰动幅度依赖于平均速度的大小,速度扰动幅度随平均速度的增加而增加;2)速度扰动幅度与磁场扰动幅度存在较强的正相关性;3)磁场扰动幅度与AE指数密切相关,磁场扰动幅度随着AE指数增加而增加,而速度扰动幅度与AE指数之间没有明显的相关性;4)Alfven比与AE指数的相关系数较小,但能够看出Alfven比随着AE指数增加而减小的趋势;5)速度扰动幅度和磁场扰动幅度与尾向距离及距中性片距离的关系不明显. 相似文献