石墨炉原子吸收光谱法测定农业地质调查土壤样品中镉的不确定度评定   总被引：2，自引：5，他引：2  

孙爱琴  王烨  王苏明  陈爱平  陈浩凤 《岩矿测试》2007,26(1):51-54

用实例对石墨炉原子吸收光谱法测定土壤样品中镉元素的不确定度进行评定,采用《测量不确定度评定与表示指南》对测量结果进行评估。分析了不确定度的主要来源,包括测量浓度的不确定度、体积的不确定度、称量不确定度及测量重复性引起的不确定度。评估了镉含量的合成标准不确定度和扩展不确定度。对于镉含量为0.42×10-6的土壤样品,其扩展不确定度为0.04×10-6。  相似文献   

Shallow seismic refraction analysis: Application to studying the active North Sakhalin fault     

V. V. Zhigulev  V. N. Patrikeev 《Russian Journal of Pacific Geology》2007,1(1):15-21

Results are presented from a seismic refraction survey (P-S waves) carried out in different years on recent faults of North Sakhalin. Structural features of the near-surface zone of active faults with different types of tectonic motions and their imaging in seismic fields are demonstrated. Criteria for estimating the activity of the studied tectonic disruption are proposed.  相似文献   

一个双波地形重力波拖曳参数化方案   总被引：4，自引：0，他引：4  

王元  唐锦赟  伍荣生 《气象学报》2007,65(5):733-743

当地形次尺度强迫的作用与显式的经典动力作用效应相当时,地形重力波拖曳力对于环流的维持,以及动量和热量通量输送的动力效应变得十分显著。这种地形次尺度拖曳作用项可通过参数化的方法,在动力方程中加入额外的小项而引入数值模式。目前成熟的地形重力波拖曳参数化方法,如第1代基于线性单波理论的参数化方案;以及侧重考虑了临界层作用等因素对拖曳力的额外贡献的第2代参数化方案,都无法有效表达风速垂直变化引起的波动应力随高度变化的特征。基于上述考虑,本文给出了一个双波参数化方案用于计算地形重力波拖曳中由线性自由传播重力波造成的波动应力的垂直分布。通过二阶WKB近似,它对由风速垂直变化引起的对波动应力的选择性临界层吸收过程和经典的临界层吸收过程做了显式处理;而在不发生临界层吸收现象的地区,则用两个单波同时在垂直方向上进行应力的传播,并利用波饱和标准进行应力耗散。进一步地在真实地形(以大别山地区为个例)条件下的测试结果表明,通过在不同理想风速廓线以及北半球冬季中纬度纬向平均风廓线下对波动应力垂直分布的计算,证明该方案确实能有效地给出应力随高度变化的特征。  相似文献   

Damped Lyα absorbers from dwarf galaxy ejecta     

P. E. J. Nulsen  X. Barcons  & A. C. Fabian 《Monthly notices of the Royal Astronomical Society》1998,301(1):168-174

It is argued that the formation of a dwarf galaxy causes a massive burst of star formation, resulting in the ejection of most of the available gas from the galaxy as a weakly collimated wind. The ejected gas can give rise to a damped Lyα absorber (DLA). Weakly collimated outflows naturally explain the asymmetric profiles seen in low-ionization absorption lines caused by heavy elements associated with DLAs, where absorption is strongest at one edge of the absorption feature. The shape of the distribution of column densities in the model agrees reasonably well with observations. In particular, the break in slope is caused by external photoionization of the wind. A semi-analytical model for galaxy formation is used to show that, for currently acceptable cosmological parameters, dwarf galaxy outflows can account for the majority of DLA systems and their distribution with redshift. This model also predicts a correlation between velocity structure and metallicity of DLA systems, in qualitative agreement with observations. DLAs do not require many large, rapidly rotating disc galaxies to have formed early on, as in other models for their origin.  相似文献   

HST images of a galaxy group at z = 2.81, and the sizes of damped Lyα galaxies     

P. Møller  & S. J. Warren 《Monthly notices of the Royal Astronomical Society》1998,299(3):661-671

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Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea     

Jin-Soo Lee  Hyo-Taek Chon  Kyoung-Woong Kim 《Journal of Geochemical Exploration》1998,65(1):61-78

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.  相似文献   

铝硅酸盐矿物和玻璃中Al的配位与局部结构   总被引：3，自引：2，他引：1  

彭明生  李迪恩 《矿物学报》1998,18(4):425-430

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。  相似文献   

Explicit solution of a free boundary problem for a nonlinear absorption model of mixed saturated-unsaturated flow     

Adriana C. Briozzo  Domingo A. Tarzia 《Advances in water resources》1998,21(8):1989

In wet soils, zones of saturation naturally develop in the vicinity of impermeable strata, surface ponds and subterranean cavities. Hydrology must be then concerned with transient flow through coexisting unsaturated and saturated zones. The models of advancing saturated zones necessarily involve a nonlinear free boundary problem.A closed-form analytic solution is presented for a nonlinear diffusion model under conditions of ponding at the surface. The soil water diffusivity is restricted to the special functional form D(θ) = a/(b − θ)², where θ is the water content field to be determined and a, b are positive constants. The explicit solution depends on a parameter C (determined by the data of the problem), according to two cases: 1 < C < C₁ or C ≥ C₁, where C₁ is a constant which is obtained as the unique solution of an equation. This result complements the study given in P. Broadbridge, Water Resources Research, 1990, 26, 2435–2443, in order to established when the explicit solution is available. The behavior of the bifurcation parameter C₁ as a function of the driving potential is studied with the corresponding limits for small and large values. Moreover, the sorptivity is proven to be continuously differentiable function of the variable C.  相似文献   

Isometamorphic variations in the reflectance and fluorescence of vitrinite—a key to depositional environment     

C. F. K. Diessel  L. Gammidge 《International Journal of Coal Geology》1998,36(3-4)

Petrographic investigations of serial ply samples from five high- to medium-volatile bituminous coal seams from Australia (4) and Canada (1) reveal substantial in-seam variations in the reflectance and monochromatic microfluorescence intensities of the maceral subgroup telovitrinite. The variations consist of one case of reflectance enhancement and fluorescence suppression, and four cases of reflectance suppression and fluorescence enhancement. The single case of reflectance enhancement and fluorescence suppression is due to the oxidation of the vitrinite nuclei at the sequence boundary between the Bayswater and Upper Wynn seams in New South Wales. The four cases of reflectance suppression and fluorescence enhancement result from the syn- and epigenetic absorption by the vitrinite nuclei of hydrogen donated by, presumably, anaerobic bacteria-generated lipids. Two of the coals are marine-influenced: the Liskeard Seam from the Bowen Basin by combined syngenetic and epigenetic effects, and the Greta Seam from the Sydney Basin mainly by epigenetic contact with sea water. For both coals, the results are strong vitrinite reflectance suppression and fluorescence enhancement. The remaining two coals, the Bulli Seam from the Sydney Basin and a coal seam from the Gates Formation in British Columbia, show moderate epigenetic effects on the optical properties of telovitrinite by fresh-water. In the Bulli Seam which was studied in two adjacent localities, the reflectance suppression and fluorescence enhancement of telovitrinite are stronger under sandstone roof than under shale roof. In some cases, the epigenetic effects are superimposed on syngenetic telovitrinite reflectance and fluorescence variations resulting from the cogeneration and mixing of different telovitrinite precursors, for example, autochthonous roots and hypautochthonous or allochthonous shoots. A measure of the degree of dispersal and mixing is the coefficient of variation of telovitrinite reflectance and/or fluorescence. This coefficient correlates well with detrital minerals and dispersed macerals, e.g., inertodetrinite and, to a lesser extent, sporinite. Some comments are made on slitted so-called pseudovitrinite which is regarded as a telovitrinite that was subjected to very weak post-coalification desiccation and possibly oxidation without losing much of its thermoplastic properties.  相似文献   

在97.8GHz处测量地球大气的不透明度     

杨戟  曹逸庭 《天文学报》1998,39(3):333-336

用研制的全自动辐射计在97．8GHz上测量南京市内大气的不透明度以及这种不透明度随时间的变化．辐射计记录大气在不同天顶高度的辐射温度,由此测出天顶方向的大气不透明度。在56小时的测量时间内,取得了1400多组数据,拟合得到了在观测时段内天顶方向的大气不透明度在0．2至0．7之间,典型值为0．4,表明测试地点的大气条件允许进行3mm波段的射电天文观测．由于在工作频段内大气不透明度的主要来源是对流层水汽的吸收,测量的不透明度可用来直接反映大气内水汽的含量,并实时校准大气吸收．  相似文献