Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea     

Jin-Soo Lee  Hyo-Taek Chon  Kyoung-Woong Kim 《Journal of Geochemical Exploration》1998,65(1):61-78

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.  相似文献   

铝硅酸盐矿物和玻璃中Al的配位与局部结构   总被引：3，自引：2，他引：1  

彭明生  李迪恩 《矿物学报》1998,18(4):425-430

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。  相似文献   

Explicit solution of a free boundary problem for a nonlinear absorption model of mixed saturated-unsaturated flow     

Adriana C. Briozzo  Domingo A. Tarzia 《Advances in water resources》1998,21(8):1989

In wet soils, zones of saturation naturally develop in the vicinity of impermeable strata, surface ponds and subterranean cavities. Hydrology must be then concerned with transient flow through coexisting unsaturated and saturated zones. The models of advancing saturated zones necessarily involve a nonlinear free boundary problem.A closed-form analytic solution is presented for a nonlinear diffusion model under conditions of ponding at the surface. The soil water diffusivity is restricted to the special functional form D(θ) = a/(b − θ)², where θ is the water content field to be determined and a, b are positive constants. The explicit solution depends on a parameter C (determined by the data of the problem), according to two cases: 1 < C < C₁ or C ≥ C₁, where C₁ is a constant which is obtained as the unique solution of an equation. This result complements the study given in P. Broadbridge, Water Resources Research, 1990, 26, 2435–2443, in order to established when the explicit solution is available. The behavior of the bifurcation parameter C₁ as a function of the driving potential is studied with the corresponding limits for small and large values. Moreover, the sorptivity is proven to be continuously differentiable function of the variable C.  相似文献   

Isometamorphic variations in the reflectance and fluorescence of vitrinite—a key to depositional environment     

C. F. K. Diessel  L. Gammidge 《International Journal of Coal Geology》1998,36(3-4)

Petrographic investigations of serial ply samples from five high- to medium-volatile bituminous coal seams from Australia (4) and Canada (1) reveal substantial in-seam variations in the reflectance and monochromatic microfluorescence intensities of the maceral subgroup telovitrinite. The variations consist of one case of reflectance enhancement and fluorescence suppression, and four cases of reflectance suppression and fluorescence enhancement. The single case of reflectance enhancement and fluorescence suppression is due to the oxidation of the vitrinite nuclei at the sequence boundary between the Bayswater and Upper Wynn seams in New South Wales. The four cases of reflectance suppression and fluorescence enhancement result from the syn- and epigenetic absorption by the vitrinite nuclei of hydrogen donated by, presumably, anaerobic bacteria-generated lipids. Two of the coals are marine-influenced: the Liskeard Seam from the Bowen Basin by combined syngenetic and epigenetic effects, and the Greta Seam from the Sydney Basin mainly by epigenetic contact with sea water. For both coals, the results are strong vitrinite reflectance suppression and fluorescence enhancement. The remaining two coals, the Bulli Seam from the Sydney Basin and a coal seam from the Gates Formation in British Columbia, show moderate epigenetic effects on the optical properties of telovitrinite by fresh-water. In the Bulli Seam which was studied in two adjacent localities, the reflectance suppression and fluorescence enhancement of telovitrinite are stronger under sandstone roof than under shale roof. In some cases, the epigenetic effects are superimposed on syngenetic telovitrinite reflectance and fluorescence variations resulting from the cogeneration and mixing of different telovitrinite precursors, for example, autochthonous roots and hypautochthonous or allochthonous shoots. A measure of the degree of dispersal and mixing is the coefficient of variation of telovitrinite reflectance and/or fluorescence. This coefficient correlates well with detrital minerals and dispersed macerals, e.g., inertodetrinite and, to a lesser extent, sporinite. Some comments are made on slitted so-called pseudovitrinite which is regarded as a telovitrinite that was subjected to very weak post-coalification desiccation and possibly oxidation without losing much of its thermoplastic properties.  相似文献   

在97.8GHz处测量地球大气的不透明度     

杨戟  曹逸庭 《天文学报》1998,39(3):333-336

用研制的全自动辐射计在97．8GHz上测量南京市内大气的不透明度以及这种不透明度随时间的变化．辐射计记录大气在不同天顶高度的辐射温度,由此测出天顶方向的大气不透明度。在56小时的测量时间内,取得了1400多组数据,拟合得到了在观测时段内天顶方向的大气不透明度在0．2至0．7之间,典型值为0．4,表明测试地点的大气条件允许进行3mm波段的射电天文观测．由于在工作频段内大气不透明度的主要来源是对流层水汽的吸收,测量的不透明度可用来直接反映大气内水汽的含量,并实时校准大气吸收．  相似文献   

Microlensing of broad absorption line quasars     

Lewis  & Belle 《Monthly notices of the Royal Astronomical Society》1998,297(1):69-76

The physical nature of the material responsible for the high-velocity broad absorption line (BAL) features seen in a small fraction of quasar spectra has been the subject of debate since their discovery. This has been especially compounded by the lack of observational probes of the absorbing region. In this paper we examine the role of 'microlenses' in external galaxies in the observed variability in the profiles of BALs in multiply imaged quasars. Utilizing realistic models for both the BAL region and the action of an ensemble of microlensing masses, we demonstrate that stars at cosmological distances can provide an important probe of the physical state and structure of material at the heart of these complex systems. Applying these results to the macrolensed BAL quasar system H1413+117, the observed spectral variations are readily reproduced, but without the fine-tuning requirements of earlier studies which employ more simplistic models.  相似文献   

High-redshift galaxies in the Hubble Deep Field— II. Colours and number counts     

Lucia Pozzetti  Piero Madau  Gianni Zamorani  Henry C. Ferguson  & Gustavo Bruzual A. 《Monthly notices of the Royal Astronomical Society》1998,298(4):1133-1144

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Precise laboratory wavelengths of the Mg I and Mg II resonance transitions at 2853, 2803 and 2796 Å     

J. C. Pickering  A. P. Thorne  & J. K. Webb 《Monthly notices of the Royal Astronomical Society》1998,300(1):131-134

Strong ultraviolet resonance transitions are observed routinely both in the Galactic interstellar medium and in quasar absorption systems. The quality of the astronomical spectroscopic data now available demands more precise laboratory rest wavelengths. Of particular interest is the accuracy with which one can constrain space–time variations in fundamental constants using quasar spectra. A recent analysis by Webb et al. of 25 quasar spectra using Mg and Fe transitions tentatively suggests that the fine-structure constant was smaller at earlier epochs. To permit a check on this result, and to allow further more extensive investigations, we have carried out a new determination of the laboratory wavelengths of Mg  i  2853 Å, Mg  II  2796 Å and Mg  II  2803 Å by high-resolution Fourier transform spectroscopy. Our results for Mg  II  2796 Å are consistent with the value measured independently by two other groups. To our knowledge, no previous measurements of comparable precision exist for Mg  I  2853 Å and Mg  II  2803 Å.  相似文献   

Intercomparison of Tropospheric OH Measurements by Different Laser Techniques during the POPCORN Campaign 1994     

A. Hofzumahaus  U. Aschmutat  U. Brandenburger  T. Brauers  H.-P. Dorn  M. Hausmann  M. Heßling  F. Holland  C. Plass-Dülmer  D. H. Ehhalt 《Journal of Atmospheric Chemistry》1998,31(1-2):227-246

In-situ OH measurements by laser-induced fluorescence (LIF) spectroscopy and folded long-path differential optical absorption spectroscopy (DOAS) were carried out in a rural environment in North-East Germany as part of the field experiment POPCORN in August 1994. The large set of OH data obtained allowed an intercomparison of both techniques based on relative diurnal profiles and simultaneously measured absolute concentrations. Most of the time the two OH instruments encountered the same air and agreed well in the measured relative diurnal variations. Only on a few occasions the measurements significantly disagreed due to a perturbation of the DOAS measurements by a local OH source in the north-western wind sector. Excluding data from this wind direction, the statistical analysis of 137 data pairs yields a correlation coefficient of r = 0.90 and a weighted linear fit with a slope of 1.09 ± 0.12. The correlations are carefully analyzed. The comparison of both instruments is discussed in the light of newly published effective absorption cross-sections for H2O and O2 that affect the calibration of LIF.  相似文献   

地震CT及其在采空区探测中的应用   总被引：7，自引：0，他引：7       下载免费PDF全文

王超凡  赵永贵  靳洪晓  郭鸿  李勤 《地球物理学报》1998,41(Z1):367-375

应用地震波速CT和吸收CT相结合的方法对山东省招远市界河金矿隐伏采空区进行了联合探测研究．波速CT是利用地震波走时资料反演地质体内部波速结构;吸收CT是通过能量变化观测反演吸收系数分布．地震波速对岩性敏感,吸收系数与岩石的完整性关系更密切在界河金矿采空区探测中利用地震波速和吸收系数为层析物理量,在巷道和地表间进行透射观测,以优于2m的分辨率清楚地揭示了测区内采空区和断裂破碎带的分布,探测结果已被后期的采掘所证实．探测的成功为解决同类问题提供了一种可行的方案,对促进工程地球物理探测技术的发展也有重要意义．  相似文献