Dissolved titanium distributions in the Mid-Atlantic Bight   总被引：1，自引：0，他引：1  

Stephen A. Skrabal   《Marine Chemistry》2006,102(3-4):218-229

Although titanium is abundant in Earth's crust, its sources and distribution in the ocean are poorly understood. To elucidate its behavior, distributions of dissolved (< 0.2 μm) Ti were determined in surface waters and vertical profiles from the Mid-Atlantic Bight (MAB). Concentrations of Ti decreased from 390 pM at the Delaware Bay mouth to < 100 pM across the Delaware continental shelf. In vertical profiles, small increases in bottom waters suggest a possible flux of Ti from shelf sediments, consistent with previous reports of pore water enrichments of dissolved Ti in MAB sediments. Concentrations in surface waters of the outer shelf and slope ranged between 30 and 140 pM, with most values below 90 pM. Concentrations in a 1000 m vertical profile in the eastern Gulf Stream ranged between 110 and 280 pM, and showed a variable distribution attributed to the mixing of water masses in the outer MAB. A simple model of Ti sources to the MAB suggests that atmospheric deposition of dissolved Ti is comparable to net riverine contributions and therefore must be considered in applications of Ti as a tracer of oceanographic processes.  相似文献   

The influence of island generated eddies on the carbon dioxide system, south of the Canary Islands     

Melchor Gonzlez-Dvila  J. Magdalena Santana-Casiano  Demetrio de Armas  Jos Escnez  Miguel Suarez-Tangil 《Marine Chemistry》2006,99(1-4):177

Measurements of surface partial pressure of CO₂ and water column alkalinity, pH_T, nutrients, oxygen, fluorescence and hydrography were carried out, south of the Canary Islands during September 1998. Cyclonic and anticyclonic eddies were alternatively observed from the northwestern area to the central area of the Canary Islands. Nutrient pumping and vertical uplifting of the deep chlorophyll maximum by cyclonic eddies were also ascertained by upward displacement of dissolved inorganic carbon. A model was applied to determine the net inorganic carbon balance in the cyclonic eddy. The fluxes were determined considering both the diffusive and convective contributions from the upward pumping and the corresponding horizontal transport of water outside the area. An increase in the total inorganic carbon concentration in the upper layers inside the eddy field of 133 mmol C m^− 2 d^− 1 was determined. The upward flux of inorganic carbon decreased the effect of the increased primary production on the carbon dioxide chemistry. The reduced fCO₂ inside the cyclonic eddy, 15 μatm lower than that observed in non-affected surface water, was explained by thermodynamic aspects, biological activity, eddy upward pumping and diffusion and air–sea water exchange effects.  相似文献   

Semidiurnal Dynamics of Salinity, Nutrients and Suspended Particulate Matter in an Estuary in the Seto Inland Sea, Japan, during a Spring Tide Cycle   总被引：3，自引：0，他引：3  

Paolo Magni  Shigeru Montani  Kuninao Tada 《Journal of Oceanography》2002,58(2):389-402

The physical and chemical variability of the water column at subtidal station of an estuary in the Seto Inland Sea, Japan, was studied over a 24-hour period during a spring tide (tidal range ca. 2 m) in May 1995. Surface water and several depths through the water column were monitored every one and two hours, respectively. At each occasion, water temperature, salinity and dissolved oxygen concentration were measured and water samples were collected for the determination of nutrients and suspended particulate matter (SPM). Disruptive changes in the physical and chemical characteristics of the water was produced by the tidal cycle and the mixing of water masses of different origin. These changes were highly significant both spatially and temporally, yet with varying effects on physical parameters, nutrients and the different components of SPM. Significant differences in nutrient concentrations were also observed when the data-set was divided into ebb and flood components, irrespective of the depth. Nitrate and nitrite rose to 1.8 times higher during the flood. Spatial differences of SPM were less marked than those of nutrients, only particulate organic carbon (POC) being significantly higher at the surface than in the intermediate and the lower layer. Both POC and pheopigment concentrations increased markedly through the water column, being highest shortly before the lower low tide. In contrast, suspended solid (SS) content increased sharply after the lower low tide (>40 mg l⁻¹) and this coincided with a marked decrease of the C/SS content (<20 mg g⁻¹). The lagtime between POC and SS tidal transport was caused by particle resuspension from the exposed intertidal sediments as the tidal level rose, and particle transport selection in relation to the tidal state. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Applications of AnnAGNPS model for soil loss estimation and nutrient loading for Malaysian conditions     

A. Shamshad  C.S. LeowA. Ramlah  W.M.A. Wan HussinS.A. Mohd. Sanusi 《International Journal of Applied Earth Observation and Geoinformation》2008

The study evaluated the performance and suitability of AnnAGNPS model in assessing runoff, sediment loading and nutrient loading under Malaysian conditions. The watershed of River Kuala Tasik in Malaysia, a combination of two sub-watersheds, was selected as the area of study. The data for the year 2004 was used to calibrate the model and the data for the year 2005 was used for validation purposes. Several input parameters were computed using methods suggested by other researchers and studies carried out in Malaysia. The study shows that runoff was predicted well with an overall R² value of 0.90 and E value of 0.70. Sediment loading was able to produce a moderate result of R² = 0.66 and E = 0.49, nitrogen loading predictions were slightly better with R² = 0.68 and E = 0.53, and phosphorus loading performance was slightly poor with an R² = 0.63 and E = 0.33. The erosion map developed was in agreement with the erosion risk map produced by the Department of Agriculture, Malaysia. Rubber estates and urban areas were found to be the main contributors to soil erosion. The simulation results showed that AnnAGNPS has the potential to be used as a valuable tool for planning and management of watersheds under Malaysian conditions.  相似文献   

新地球观   总被引：11，自引：0，他引：11  

张昀 《地球科学进展》1992,7(1):57-64

One of the most important achivements on science in 20th century is the new recognition on the Earth:the Earth,out of the other planets, exhibits very peculiar features because it has an extremely complex and active periphery part (surfacial layers). This periphery part is an open system sustained by inputting solar energe , which is captured , transfered and stored by life. Through the system , cyclings of matters and energe flow are driven and regulated by life activities. This system is self-equilibrated,self-controlled and far away from astrophysical and thermodynamic equilibria mainly because of life and life activities.
Development of human calture influences increasingly on流Earth's periphery system , at last , the natural biosphere that has existed for 3 billion years on the Earth's surface will inavoidably be replaced by so called "noosphere",which is man一reconstructed,man-controlled and unstable system. Thus the fate of the Earth,to a great extent,will be determined by the direction of human calture evolution.
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Periodicities in natural remanent magnetization and palaeoclimatic records detected by walsh spectra     

J. G. Negi  R. K. Tiwari 《Pure and Applied Geophysics》1990,132(4):757-769

The time series consisting of nonsinusoidal Natural Remanent Magnetization (NRM) and palaeoclimatic variations for the past two million years have been spectrally examined by using a new Walsh transform technique. The results show statistically significant periodicities (at 95% confidence level) of approximately 92,000 years; 43,000 years and 21,000 years in the ensemble spectra of the NRM intensity (mineralogic) variations. These NRM periodicities are remarkably close to the well-known Milankovitch cycles. The ensemble spectra of palaeoclimatic records reveal only 41,000 years statistically significant (95%) periodicity corresponding to the obliquity cycle. The study suggests that NRM variations in deep sea sediments probably are more sensitive recorders of palaeoclimatic memory than the oxygen isotope variations.  相似文献   

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean     

B. C. Nguyen  N. Mihalopoulos  S. Belviso 《Journal of Atmospheric Chemistry》1990,11(1-2):123-141

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.  相似文献   

Cyclic palaeokarst surfaces in Aptian peritidal carbonate successions (Taurides, southwest Turkey): internal structure and response to mid-Aptian sea-level fall     

&#x;smail mer Y&#x;lmaz  Demir Alt&#x;ner 《Cretaceous Research》2006,27(6):814-827

The sedimentology and cyclic stratigraphy of palaeokarst structures in Aptian peritidal carbonate successions are interpreted using field and laboratory microfacies analyses of closely spaced samples from measured outcrop stratigraphic sections in southwest Turkey. Cycles displaying shallowing-upward metre-scale cyclicity are generally composed of lime mudstones/wackestones/packestones at the bottom and stromatolites or lime mudstones with charophytes and ostracods at the top. Subaerial exposure structures such as in situ karst breccias, dissolution vugs/pipes, mud cracks and sheet cracks are encountered at the top of the cycles. The presence of limestone layers between the successive karst breccia levels indicates that they are in situ palaeokarst structures, not recent karstifications or deep penetration from the upper palaeokarst surface down to the older strata. Palaeokarst breccia deposits are interpreted as mantling breccia formed as a result of epikarstification. Three main palaeokarst levels are recorded in nearly all sections. The sedimentology of the palaeokarst breccias, their position in cyclic peritidal carbonates and the biostratigraphic framework are used to trace the record of the global mid-Aptian sea-level fall in the southwest Taurides. The successive occurrences of three karst breccia levels close to the mid-Aptian sea-level fall correspond to falling periods of high-amplitude sea-level fluctuation within a late high-stand or early fall condition of a third-order sea level.  相似文献   

Limestone–marl alternations as environmental archives and the role of early diagenesis: a critical review     

Hildegard Westphal 《International Journal of Earth Sciences》2006,95(6):947-961

Limestone–marl alternations and other micritic calcareous rhythmites have long appealed to sedimentologists, as they appeared to directly reflect high-frequency environmental change. In particular, when orbital forcing gained popularity amongst sedimentologists and paleoclimatologists in 1980s, such rhythmites seemed to offer an ideal tool for high-resolution chronostratigraphy and environmental reconstruction. However, in spite of the fact that orbital forcing has become a routine interpretation of calcareous rhythmites, and that the processes of formation of calcareous rhythmites are considered well understood, research in the past 10 years again has questioned their primary origin and their direct interpretability. Detailed petrographic, paleontological, and geochemical data from numerous successions through geological time provided the basis for testing whether or not the regular alternation of limestone beds and marl or shale interlayers represents bimodally fluctuating environmental conditions in a direct way. In particular, these data, supplemented by box model simulations, imply that post-depositional alteration (diagenesis) has the potential to not only seriously distort primary environmental signals, but also to mimic primary signals. This questions the use of micritic calcareous rhythmites for high-resolution chronostratigraphy and for environmental interpretations where independent data of diagenetically inert parameters are not available. Diagenetic changes appear to have a yet widely underestimated influence on the appearance of limestone–marl alternations and other calcareous rhythmites. The aim of the present review is to summarize new approaches and give an overview of our research results in this field of the past decade. This review also aims at pointing to still enigmatic aspects that need to be addressed before the interpretation of micritic calcareous rhythmites can be considered a reliable tool for high-resolution chronostratigraphy and paleoenvironmental interpretation. “This difference [between shale and limestone] does not find definite expression in the chemical composition but appeals to the eye.” Gilbert (1895)  相似文献   

云南鹤庆盆地近1Ma来的气候序列重建初探   总被引：5，自引：3，他引：5       下载免费PDF全文

童国榜  刘志明  王苏民  羊向东  王书兵 《第四纪研究》2002,22(4):332-339

云南鹤庆盆地近1Ma来的孢粉植物群很好地揭示了本区的环境演化过程。本文利用植物生态位知识,通过模糊数学方法对鹤庆(QH)孔孢粉序列所记录的古气候信息进行重塑,建立了近1Ma来的年均温、年降水量及年较差序列,并将本区气候演化分为4个气候旋回,32个气候期。该序列可与黄土-古土壤序列及海洋^δ18O阶段对比,但冷暖波动的幅度及降温时段持续的长短有其特色,表明本区气候既受全球气候变化的控制,又受青藏高原阶段隆升的制约;近1Ma来气温的波动幅度呈递增趋势,0.30MaB.P.尤其显著;冷、暖段间年均温的变化幅度由第一气候旋回的7℃增大到第三气候旋回的9℃(按4次平滑值计算),而样点的实际最大差值由8℃增至16℃;最强烈的降温发生在第二气候旋回中的0.45～0.14MaB.P.时间段,这与玉龙雪山冰川活动规模最大相一致;降温时年降水量及年较差值增大,证实近1Ma来,西南季风区的气候组构与东南季风区不同。  相似文献