Application research of enhanced in-situ micro-ecological remediation of petroleum contaminated soil          下载免费PDF全文

ZHANG Sheng  ZHANG Cui-yun  HE Ze  CHEN Li  ZHANG Fa-wang  YIN Mi-ying  NING Zhuo  SUN Zhen-hua  ZHEN Shi-jun 《地下水科学与工程》2016,4(3):157-164

Experimental study of enhanced in-situ micro-ecological remediation of petroleum contaminated loess soil was carried out in Zhongyuan oil production areas, and the enhanced in-situ micro-ecological remediation technique includes optimistic in-situ microbial communities, physical chemistry methods, alfalfa planting and regulation of soil environmental elements. Experiments showed that the oil content in the contaminated soil with oil content about 2 898.25 mg/kg can be reduced about 98.61% after in-situ micro-ecological remediation for 99 days, which demonstrated the effectiveness of in-situ micro-ecological remediation methods for petroleum contaminated soil in central plains of China, and explored the practical and feasible application of these methods.  相似文献   

Controls on reservoir heterogeneity of tight sand oil reservoirs in Upper Triassic Yanchang Formation in Longdong Area,southwest Ordos Basin,China: Implications for reservoir quality prediction and oil accumulation     

《Marine and Petroleum Geology》2016

Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively.  相似文献   

Geological control factors of micro oil distribution in tight reservoirs     

《Marine and Petroleum Geology》2016

Understanding the oil distribution characteristics in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil distribution characteristics are mostly concerned with the basin scale. Based on Lucaogou core samples, geochemical approaches including Soxhlet extraction, total organic carbon (TOC), and Rock-Eval are combined with reservoir physical approaches including mercury injection capillary pressure (MICP) and porosity-permeability analysis, to quantitatively evaluate oil distribution of tight reservoirs on micro scale. The emphasis is to identify the key geological control factors of micro oil distribution in such tight reservoirs. Dolomicrites and non-detrital mudstones have excellent hydrocarbon generation capacity while detritus-containing dolomites, siltstones, and silty mudstones have higher porosity and oil content, and coarser pore throat radius. Oil content is mainly controlled by porosity, pore throat radius, and hydrocarbon generation capacity. Porosity is positively correlated with oil content in almost all samples including various lithologies, indicating that it is a primary constraint for providing storage space. Pore throat radius is also an important factor, as oil migration is inhibited by the capillary pressure which must be overcome. If the reservoir rock with suitable porosity has no hydrocarbon generation capacity, pore throat radius will be decisive. As tight reservoirs are generally characterized by widely distributed nanoscale pore throats and high capillary pressure, hydrocarbon generation capacity plays an important role in reservoir rocks with suitable porosity and fine pore throats. Because such reservoir rocks cannot be charged completely. The positive correlation between hydrocarbon generation capacity and oil content in three types of high porosity lithologies (detritus-containing dolomites, siltstones, and silty mudstones) supports this assertion.  相似文献   

Research achievements of the Qinghai-Tibet Plateau based on 60 years of aeromagnetic surveys     

《China Geology》2021,4(1):147-177

The Qinghai-Tibet Plateau (also referred to as the Plateau) has long received much attention from the community of geoscience due to its unique geographical location and rich mineral resources. This paper reviews the aeromagnetic surveys in the Plateau in the past 60 years and summarizes relevant research achievements, which mainly include the followings. (1) The boundaries between the Plateau and its surrounding regions have been clarified. In detail, its western boundary is restricted by West Kunlun-Altyn Tagh arc-shaped magnetic anomaly zone forming due to the arc-shaped connection of the Altyn Tagh and Kangxiwa faults and its eastern boundary consists of the boundaries among different magnetic fields along the Longnan (Wudu)-Kangding Fault. Meanwhile, the fault on the northern margin of the Northern Qilian Mountains serves as its northern boundary. (2) The Plateau is mainly composed of four orogens that were stitched together, namely East Kunlun-Qilian, Hoh-Xil-Songpan, Chamdo-Southwestern Sanjiang (Nujiang, Lancang, and Jinsha rivers in southeastern China), and Gangdese-Himalaya orogens. (3) The basement of the Plateau is dominated by weakly magnetic Proterozoic metamorphic rocks and lacks strongly magnetic Archean crystalline basement of stable continents such as the Tarim and Sichuan blocks. Therefore, it exhibits the characteristics of unstable orogenic basement. (4) The Yarlung-Zangbo suture zone forming due to continent-continent collisions since the Cenozoic shows double aeromagnetic anomaly zones. Therefore, it can be inferred that the Yarlung-Zangbo suture zone formed from the Indian Plate subducting towards and colliding with the Eurasian Plate twice. (5) A huge negative aeromagnetic anomaly in nearly SN trending has been discovered in the middle part of the Plateau, indicating a giant deep thermal-tectonic zone. (6) A dual-layer magnetic structure has been revealed in the Plateau. It consists of shallow magnetic anomaly zones in nearly EW and NW trending and deep magnetic anomaly zones in nearly SN trending. They overlap vertically and cross horizontally, showing the flyover-type geological structure of the Plateau. (7) A group of NW-trending faults occur in eastern Tibet, which is intersected rather than connected by the nearly EW trending that develop in middle-west Tibet. (8) As for the central uplift zone that occurs through the Qiangtang Basin, its metamorphic basement tends to gradually descend from west to east, showing the form of steps. The Qiangtang Basin is divided into the northern and southern part by the central uplift zone in it. The basement in the Qiangtang Basin is deep in the north and west and shallow in the south and west. The basement in the northern Qiangtang Basin is deep and relatively stable and thus is more favorable for the generation and preservation of oil and gas. Up to now, 19 favorable tectonic regions of oil and gas have been determined in the Qiangtang Basin. (9) A total of 21 prospecting areas of mineral resources have been delineated and thousands of ore-bearing (or mineralization) anomalies have been discovered. Additionally, the formation and uplift mechanism of the Plateau are briefly discussed in this paper.©2021 China Geology Editorial Office.  相似文献   

Molecular and isotopic compositions of bitumens in Silurian tar sands from the Tarim Basin,NW China: Characterizing biodegradation and hydrocarbon charging in an old composite basin   总被引：1，自引：0，他引：1  

Wanglu Jia  Zhongyao Xiao  Chiling Yu  Ping'an Peng 《Marine and Petroleum Geology》2010

Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in ¹³C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C₂₈ regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.  相似文献   

Laboratory simulation of natural leaching processes of eastern USA oil shale     

M. Shirav  T. L. Robl 《Environmental Geology》1993,22(1):88-94

Raw and retorted spent oil shales from Kentucky, as well as soil and overburden materials, were subjected to laboratory and field leaching tests. Standard batch leaching tests grossly undervalue the amount of dissolved ions as measured in the field, being too brief to enable slow reactions of the mineral matrix, such as hydrolysis and oxidation of sulfides or reactions of acidic leachates with soluble components of the clays. Laboratory column tests, devised to closely simulate natural leaching processes, achieved concentration levels and elemental release patterns similar to those found in field tests. The column tests provide a reliable means to assess the leachability of metals in these materials.  相似文献   

中国油气区大地构造的历史因果论分析   总被引：2，自引：0，他引：2  

魏洲龄 《大地构造与成矿学》1993,17(1):1-12,38

依历史因果论大地构造学观点,就体现历史特点的大地构造体制来说,可将中国的油田划分为地槽型,地台型及地洼型三种类型,以现阶段的动力环境而论,则可将中国油气区划分为地幔汇聚型油气域和地幔扩散型油气域,并可进一步暂分为四大油气区,即陆缘海扩张型壳体油气大区,东部拉张型壳体油气大区,中部张一压型壳体油气大区和西部挤压型壳体油气大区,各大区成油气建造组合的大地构造类型,油气形成条件、油气藏类型、产出特点及分布规律等方面均有较大的差异。这些差异与各壳体的大地构造演化历史、壳体运动过程和动力学性质,以及各壳体的深部地质条件有密切关系。  相似文献   

用油田压裂资料估算应力值     

刘建中  李自强 《地震研究》1990,13(3):298-307

本文比较了从油田压裂资料获得的应力值与专门的水压致裂应力测量结果。研究结果表明,前者的最小水平主应力可以和后者的精度相当,最大水平主应力的精度略低。以长庆油田岭261—2井1985年11月15日实际压裂记录结果和吉林油田东33—35井的压裂记录为例,提出了处理油田资料的方法,给出了相应的处理结果  相似文献   

油气资源遥感勘查新方法     

朱振海  赵立平 《湖南地质》1991,10(3):259-262

地下深处的油气藏中的烃类物质,在压力梯度下会向地表产生微渗漏,导致地表物质产生一系列理化异常,在地表形成吸附烃异常、红层退色、粘土化、碳酸盐化、放射性异常和地植物异常等标志。根据这些地表标志的地物波谱特征,选择出油气资源遥感勘查的最佳工作波段,在此基础上,以机载遥感信息为主,以星载遥感信息为辅,以地表地球化学、地植物学、地面遥感勘查作为验证手段,最终施行多元信息复合分析,可达到寻找油气藏的目的。  相似文献   

电阻率-孔隙度、电阻率-含油（气）饱和度关系的一般形式及其最佳逼近函数类型的确定（Ⅰ）   总被引：4，自引：0，他引：4       下载免费PDF全文

李宁 《地球物理学报》1989,32(5):580-592

本文导出了电阻率-孔隙度、电阻率-含油（气）饱和度关系的一般形式--两个对称的表达式,并给予了实验证明。同时,本文指出,Archie公式、Winsauer公式和双水公式都是一般形式在一定条件下的特例。在一般情况下,本文给出了14个能够逼近这两个表达式的函数类型,通过岩芯数据进行选优,可以得到适合不同地区或地层的最优方程。根据本文理论建立的解释方法和研制的软件已经在油田生产中推广应用并取得了良好效果。 由于涉及内容较多,全文分两部分撰写。以下是本文的第（Ⅰ）部分,即一般形式的导出及实验验证;而最佳函数类型的确定及其在生产中的应用将作为本文的第（Ⅱ）部分发表。  相似文献