九龙江河口区表层水铀同位素的粒级分布          下载免费PDF全文

吕娥  张磊  陈敏  邱雨生  邢娜  杨伟锋  李艳平  黄奕普 《海洋学报》2007,29(4):59-68

利用微滤和超滤技术研究了九龙江河口区表层水中铀及其同位素组成的粒级分布和地球化学行为.结果表明,溶解态(<0.4μm)中低分子量组分(<10 000 u)占主要份额,胶体态(10 000 u~0.4μm)238U所占比例不足1%,且随盐度的增加其所占份额逐渐降低.溶解态、低分子量组分和胶体态238U的比活度与盐度之间存在良好的线性正相关关系,证实它们在九龙江河口区呈现保守行为.在颗粒态(>0.4μm)中,各粒级组分238U所占份额主要受控于相应颗粒物的浓度,在盐度小于20的区域,各粒级颗粒组分238U占颗粒态的份额有如下变化次序:10~53μm>2~10μm>0.4~2μm>大于53μm,而在盐度大于30的近外海站位,该次序发生一些变化:0.4~2μm>10~53μm>2~10μm>大于53μm,最小粒级颗粒组分238U的贡献有所增加,反映了自生铀贡献的加强.九龙江河口区表层水中溶解态(包括低分子量组分和胶体态)的234U/238U)_A.R.均大于1,显示出234U过剩的特征,而各粒级颗粒组分中的234U/238U)_A.R.则接近于平衡值(1.0).这一现象与陆地岩石风化过程中水体对铀的淋滤释出量及234U的优先浸出有关.对232Th/238U质量比的研究显示,溶解态及其所包括的低分子量组分和胶体态的232Th/238U质量比均小于1,而颗粒态及其所包括的4个粒级组分中的232Th/238U质量比均大于1,反映了向外海输送过程中铀、钍地球化学行为的差异.  相似文献   

Determination of phospholipid fatty acid structures and stable carbon isotope compositions of deep-sea sediments of the Northwest Pacific, ODP site 1179   总被引：1，自引：0，他引：1  

Christopher T. Mills  Robert F. Dias  Dennis Graham  Kevin W. Mandernack   《Marine Chemistry》2006,98(2-4):197-209

Sediment samples ranging from 0.05 to 278 m below sea floor (mbsf) at a Northwest Pacific deep-water (5564 mbsl) site (ODP Leg 191, Site 1179) were analyzed for phospholipid fatty acids (PLFAs). Total PLFA concentrations decreased by a factor of three over the first meter of sediment and then decreased at a slower rate to approximately 30 mbsf. The sharp decrease over the first meter corresponds to the depth of nitrate and Mn(IV) reduction as indicated by pore water chemistry. PLFA-based cell numbers at site 1179 had a similar depth profile as that for Acridine orange direct cell counts previously made on ODP site 1149 sediments which have a similar water depth and lithology. The mole percentage of straight chain saturated PLFAs increases with depth, with a large shift between the 0.95 and 3.95 mbsf samples. PLFA stable carbon isotope ratios were determined for sediments from 0.05 to 4.53 mbsf and showed a general trend toward more depleted δ¹³C values with depth. Both of these observations may indicate a shift in the bacterial community with depth across the different redox zones inferred from pore water chemistry data. The PLFA 10me16:0, which has been attributed to the bacterial genera Desulfobacter in many marine sediments, showed the greatest isotopic depletion, decreasing from − 20 to − 35‰ over the first meter of sediment. Pore water chemistry suggested that sulfate reduction was absent or minimal over this same sediment interval. However, 10me16:0 has been shown to be produced by recently discovered anaerobic ammonium oxidizing (anammox) bacteria which are known chemoautotrophs. The increasing depletion in δ¹³C of 10me16:0 with the unusually lower concentration of ammonium and linear decrease of nitrate concentration is consistent with a scenario of anammox bacteria mediating the oxidation of ammonium via nitrite, an intermediate of nitrate reduction.  相似文献   

Differences in ratios of stable isotopes of nitrogen in long-finned pilot whales (Globicephala melas) in the western and eastern North Atlantic   总被引：1，自引：0，他引：1  

Abend  Alan G.; Smith  Tim D. 《ICES Journal of Marine Science》1995,52(5):837-841

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麻醉剂丁香酚对黄腊鯵耗氧的影响   总被引：20，自引：1，他引：20       下载免费PDF全文

张朝晖  丛娇日  王波  洪旭光  KjellφMidling 《海洋科学》2003,27(6):11-14

用不同浓度的丁香酚对体质量为 115～ 175 g的黄腊鲹( Trachinotus blochii)麻醉处理 15 min,每 1分钟测定容器内的氧饱和度 1次.实验结果表明,黄腊鲹的耗氧率明显地受到丁香酚的影响,在各处理组中以 10× 10- 6浓度组的耗氧率为最低( 0.33 mg/(g@ h)), 5× 10- 6浓度组次之( 0.42 mg/(g@ h)),而对照组则较高( 0.57 mg/(g@ h)).同时实验还表明经丁香酚麻醉处理的黄腊鲹鳃活动频率显著地比对照组低.此结果表明了在施用麻醉剂以后,鱼体的活动及对氧气的消耗有明显的下降,丁香酚可以作为活鱼运输过程中有效的麻醉剂.  相似文献   

Geochemistry of trace elements and Sr-Nd isotopes of foraminifera shell from the Okinawa Trough   总被引：1，自引：0，他引：1  

Meng Xianwei  Du Dewen  Cheng Zhenbo 《海洋学报(英文版)》2001,20(1):95-103

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Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

江苏海域水环境要素分析——江苏海域环境质量分析之二   总被引：3，自引：0，他引：3       下载免费PDF全文

丁贤荣  张鹰 《海洋科学》2003,27(2):8-12

在1981、1991（1990）和1998年3次海洋环境调查的基础上，通过相同水质要素时空比较分析，江苏海域的溶解氧、磷酸盐、硝酸盐和亚硝酸 盐这4种主要海水化学因子具有时空变化特征，其高值区主要分布在灌河口、扁担港口、射阳河口、川东港和长江北支口北侧，且河口、近岸值高，向海含量渐小，不同年份、季节也有变化。沿海水化学性质主要受陆源排污（农田化肥等）影响，主要是入海河流携带污染物、海洋生物作用和本海域水体运动特征的影响，此外，溶解氧变化还受到水温变化的影响。  相似文献   

围隔生态系中叶绿素a浓度、化学耗氧量及透明度之间统计关系的研究     

郑建瑜  袁峻峰 《海洋湖沼通报》1991,(3)

通过对水库中12个围隔两次取样的叶绿素a浓度(单位:μg/L)、化学耗氧量(单位:mg·O_2/L)和塞克透明度(单位:m)的实验数据分析,求得如下回归方程: (1)[Chla]=17.60·[SD]~(-1·86) r=-0.87 (2)[Chla]=-28.85+7.32·[COD] r=0.89 (3)[COD]=6.88·[SD]~(-0·68) r=0.91本文还对这些结果进行了讨论。  相似文献   

Transfer-function modelling between environmental variation and mesozooplankton in the Baltic Sea     

I. Vuorinen  J. Hnninen  G. Kornilovs 《Progress in Oceanography》2003,59(4):339-356

Time series of freshwater runoff, seawater salinity, temperature and oxygen were used in transfer functions (TF) to model changes of mesozooplankton taxa in the Baltic Sea from the 1960’s to the 1990’s. The models were then compared with long term zooplankton monitoring data from the same period. The TF models for all taxa over the whole Baltic proper and at different depth layers showed statistically significant estimates in t-tests. TF models were further compared using parsimony as a criterion. We present models showing 1) r² > 0.4, 2) the smallest residual standard error with the combination of exploratory variables, 3) the lowest number of parameters and 4) the highest proportional decrease in error term when the TF model residual standard error was compared with those of the univariate ARIMA model of the same response variable. Most often (7 taxa out of a total of 8), zooplankton taxa were dependent on freshwater runoff and/or seawater salinity. Cladocerans and estuarine copepods were more conveniently modelled through the inclusion of seawater temperature and oxygen data as independent variables. Our modelling, however, explains neither the overall increase in zooplankton abundance nor a simultaneous decrease found in the neritic copepod, Temora longicornis. Therefore, biotic controlling agents (e.g. nutrients, primary production and planktivore diets) are suggested as independent variables for further TF modelling. TF modelling enabled us to put the controlling factors in a time frame. It was then possible, despite the inherent multiple correlation among parameters studied to deduce a chain-of-events from the environmental controls and biotic feedback mechanisms to changes in zooplankton species. We suggest that the documented long-term changes in zooplankton could have been driven by climatic regulation only. The control by climate could be mediated to zooplankton through marine chemical and physical factors, as well as biotic factors if all of these were responding to the same external control, such as changes in the freshwater runoff. Increased runoff would explain both the increasing eutrophication, causing the overall increase of zooplankton, and the changes in selective predation, contributing to decline of Temora.  相似文献   

ENSO对天目山柳杉树轮同位素的影响   总被引：8，自引：0，他引：8  

陈宝君  钱君龙  濮培民 《海洋地质与第四纪地质》2002,22(4):53-58

在Nin↑～o3,4区SST序列和Jones等的SOI序列基础上，通过主分量分析方法建立了一个ENSO指数序列。并与根据天目山柳杉树轮碳，氢同位素组成比所建立的树轮指数序列进行相关分析。结果表明，天目山树轮指数与ENSO指数有很好的相关性，尤其与前2年的ENSO指数相关显著。说明ENSO对该地区树木的生长和同位素的分馏有影响，也说明天目山地区的树木年轮对于ENSO事件具有一定的记录能力。  相似文献