Assessment of mercury contamination and human exposure associated with coastal disposal of waste from a cinnabar mining operation, Palawan, Philippines   总被引：2，自引：0，他引：2  

T. M. Williams  J. M. Weeks  A.N. Apostol Jr.  C. R. Miranda 《Environmental Geology》1999,39(1):51-60

 An integrated geochemical and toxicological assessment of environmental mercury contamination and attendant human exposure in Honda Bay, Palawan was undertaken in 1995 following a nationally reported pollution scare centered on a coastal jetty, Sitio Honda Bay, constructed using approximately 1 million tons of tailings and beneficiation waste from a cinnabar mine. Mercury (Hg) data for marine and fluvial sediments, fish tissues and human hair indicate that the toxicological hazard is considerably lower than initially reported by state environment and health officials. Typical Hg concentrations in surficial Honda Bay sediments were found to lie within the global background range (<60 μg/kg). Downcore profiles provide no evidence of enhanced Hg fluxes coincident with the onset of mining and/or coastal tailings disposal. The mean and median Hg concentrations recorded in tissues of six species of Honda Bay fish are compliant with thresholds established by the US Environmental Protection Agency (US-EPA) for marketable stocks. Earlier reports of 'Minamata range' Hg concentrations in fish and shellfish from Honda Bay remain unsubstantiated. Geochemical analyses of samples of the Sitio Honda Bay substrate have confirmed the prevalence of solid-phase Hg concentrations to ca. 340 mg/kg. The speciation of Hg is, however, dominated by secondary oxides of low bioavailability. The mean Hg concentration in hair from Sitio Honda Bay residents (4.41 mg/kg) was found to be statistically analogous to that for a neighbouring coastal community unimpacted by the coastal disposal of mine waste. A negligible residential exposure factor is thus inferred for the former. Relatively high hair Hg burdens prevail throughout the coastal Honda Bay population, consistent with significant methyl Hg ingestion through daily fish consumption. The data presented provide no environmental or toxicological justification for immediate remedial action. Received: 14 May 1998/Accepted: 1 September 1998  相似文献   

菲律宾海沉积物中石英的来源及其搬运方式   总被引：1，自引：0，他引：1  

朱潇  蒋富清  冯旭光  董江  刘喜停  王红莉  李安春 《海洋与湖沼》2018,49(6):1190-1202

为了识别菲律宾海沉积物中风尘信号和源区,以及沉积物的搬运方式,取菲律宾海沉积物中的石英,系统研究了石英的粒度组成、形貌特征、氧同位素特征和结晶度指数。菲律宾海中远离岛弧和海脊的石英粒度较细,西菲律宾海中石英主要由EM1(众数粒径平均为2.9μm)、EM2(众数粒径平均8.17μm)和EM3(众数粒径平均为21.67μm)三个端元组成,东菲律宾海中主要由EM1和EM2两个端元组成。靠近岛弧和海脊的石英粒度较粗,吕宋岛附近的石英具有众数粒径平均为103μm的EM4端元。EM1端元石英表面有明显的碰撞凹坑, EM2端元石英有溶蚀孔洞, EM3端元石英呈棱角状,表面相对光滑。包含EM1端元的石英的δ18O值和结晶度指数与塔克拉玛干沙漠中相同粒级石英的特征相近,不包含EM1端元的石英的δ18O值和结晶度指数与火山岛弧来源的石英特征相近。综合分析表明,EM1端元的石英为主要来自于塔克拉玛干沙漠的风尘石英,经由盛行西风搬运至太平洋,并由南向或西南向的风搬运,最终在菲律宾海沉积。EM2和EM3端元石英主要来源于太平洋火山岛弧,其中, EM2端元的石英经历了强烈的化学风化,经河流或洋流输送到研究区; EM3端元的石英没有经历长距离运输,可能是附近岩石风化的产物。  相似文献   

From community-based to centralised national management—A wrong turning for the governance of the marine protected area in Apo Island,Philippines?     

E.J. Hind  M.C. Hiponia  T.S. Gray 《Marine Policy》2010

Before the mid-1990s, Apo Island, Philippines, was often described as one of the world's best examples of community-based marine management. This paper studies the less-documented transition of the island during the late 1990s from community-based management to centralised national state management. Extensive interviewing of islanders has revealed deep misgivings about the centralised regime—the Protected Area Management Board (PAMB). PAMB's aim of implementing the National Integrated Protected Areas Systems (NIPAS) Act was initially looked upon favourably by islanders, but it has lost that support because of its exclusion of stakeholders from management and its poor institutional performance. The paper's conclusion is that the implementation of the NIPAS Act highlights the limitations of top-down management, and that there is a need to restore an element of local stakeholder participation in the governance of Apo's marine protected area (MPA). A system of co-management between community and national state actors is essential to ensure the long-term sustainability of Apo's marine resources.  相似文献   

Origin of high field strength element enrichment in volcanic arcs: Geochemical evidence from the Sulu Arc, southern Philippines   总被引：1，自引：0，他引：1  

P.R. Castillo  S.J. Rigby  R.U. Solidum   《Lithos》2007,97(3-4):271-288

Lavas from the Sulu Arc, southern Philippines, exhibit an enrichment in high field strength elements (HFSE) that represents a departure from the typical volcanic arc geochemical signature. It has been postulated that this relative enrichment arises from metasomatism of mantle wedge peridotites by melts derived from the subducting oceanic lithosphere, through formation of amphibole which subsequently breaks down and enriches the mantle source of parental arc magmas in HFSE. Divergent chemical and isotopic characteristics between Sulu Arc HFSE-enriched lavas and the Sulu Sea crust being subducted—the presumed source of slab-derived melts—render it unlikely, however, that HFSE enrichment arises from the influence of such melts. New geochemical data suggest that the varying degrees of HFSE enrichment in Sulu Arc lavas are instead the result of variable amounts of mixing between enriched and depleted mantle end-components—the sources of South China Sea intraplate lavas and Sulu seafloor basalts, respectively—within a compositionally heterogeneous mantle wedge.  相似文献   

Catastrophic rockslide-debris avalanche at St. Bernard, Southern Leyte, Philippines     

Sandra G. Catane  Hillel B. Cabria  Cristituto P. Tomarong Jr  Ricarido M. Saturay Jr  Mark Albert H. Zarco  Winston C. Pioquinto 《Landslides》2007,4(1):85-90

On 17 February 2006, a rockslide-debris avalanche cascaded down the steep slope of Mt. Can-abag, burying the entire village of Guinsaugon in St. Bernard, Southern Leyte, Philippines. Casualties include 139 dead with 980 still missing and presumed dead, making it perhaps the most catastrophic landslide in Philippine history. The landslide started at the ridge top along a fault plane associated with the active Philippine Fault Zone. It started as a block slide that transformed into an avalanche. The entire event lasted for only a few minutes. Estimated maximum landslide velocity is 120–130 m/s. The landslide left behind a deep, wedge-shaped scarp. The central part of the deposit exhibits a hummocky topography typical of avalanches, in contrast to the flatter surface of the debris-flow-type marginal deposit. High amounts of soil in the matrix were derived from the scouring of ancient landslide deposits and rice fields in the valley. The landslide has a total area of 3.2 km² and a runout distance of 4.1 km. Estimated volume of debris is approximately 20 Mm³. At least four streams were dammed by the landslide debris. Intense precipitation and earthquakes preceding the landslide are the potential triggers. Preliminary back analyses assuming a planar and wedge slip surface yielded very low factors of safety even under dry conditions. A more rigorous analysis of the failure mechanism of the landslide is needed.  相似文献   

Behavior of Major and Trace Elements during Ore Deposition: Example from the Low-Sulfidation Pantingan Gold System, Mount Mariveles, Bataan, Philippines     

Betchaida D. Payot    Rodolfo A. Tamayo  Jr  Victor B. Maglambayan    Carla B. Dimalanta    Graciano P. Yumul  Jr  Shigeyuki Suzuki  Mei-Fu Zhou 《Resource Geology》2007,57(2):180-196

The evaluation of the relatively fresh host rock and altered rock samples associated with the Pantingan Gold System exposed in Mount Mariveles, Bataan yield several notable observations that are useful in pinpointing potential gold pathfinder elements. Geochemical and petrologic analysis showed that the altered rocks can be subdivided into rocks that underwent propylitic alteration (group 1), argillized rocks with silica contents similar to those of the fresh host rocks (group 2), argillized but not strongly silicified rocks (group 3) and argillized and strongly silicified rocks (group 4). Selected element ratio patterns in the altered rocks and gold concentrations in gold‐bearing quartz veins vary between the rock groups. Moreover, mass balance calculation also reflected the geochemical observations pertaining to the gains and losses of SiO_2, Fe₂O₃+ MgO, CaO + Na₂O and K₂O, which are believed to be chemical reactions (i.e. breakdown of plagioclase, silica inundation or leaching, sulfide and calcite formation) caused by the influx of hydrothermal fluids.  相似文献   

Temporal Geochemical Evolution of Neogene Magmatism in the Baguio Gold–Copper Mining District (Northern Luzon, Philippines)     

Mireille Polve    Rene C. Maury    Sebastien Jego    Herve Bellon    Ahmed Margoum    Graciano P. Yumul  Jr  Betchaida D. Payot    Rodolfo A. Tamayo  Jr Joseph Cotten 《Resource Geology》2007,57(2):197-218

Baguio, in the Central Cordillera of Northern Luzon, is a district that displays porphyry copper and epithermal gold mineralization, associated with Early Miocene–Pliocene–Quaternary calc‐alkaline and adakitic intrusions. Systematic sampling, K‐Ar dating, major and trace elements, and Sr, Nd, Pb isotopic analyses of fresh magmatic rocks indicate three magmatic pulses: an Early Miocene phase (21.2–18.7 Ma), a Middle–Late Miocene phase (15.3–8 Ma) and finally a Pliocene–Quaternary event (3–1 Ma). The first phase emplaced evolved calc‐alkaline magmas, essentially within the Agno Batholith complex, and is thought to be related to the westward‐dipping subduction of the West Philippine Basin. After a quiescence period during which the Kennon limestone was deposited, magmatic activity resumed at 15.3 Ma, in connection with the start of the subduction of the South China Sea along the Manila Trench. It emplaced first petrogenetically related and relatively unradiogenic low‐K calc‐alkaline lavas and intermediate adakites. Temporal geochemical patterns observed from 15.3 to 1 Ma include progressive enrichment in K and other large ion lithophile elements, increase in radiogenic Sr and Pb and corresponding decrease in radiogenic Nd. These features are thought to reflect the progressive addition to the Luzon arc mantle wedge of incompatible elements largely inherited from South China Sea sediments. The origin of the long quiescence period, from 8 to 3 Ma, remains problematic. It might represent a local consequence of the docking of the Zambales ophiolitic terrane to Northern Luzon. Then, magmatic activity resumed at 3 Ma, emplacing chemically diversified rocks ranging from low K to high K and including a large proportion of adakites, especially during the Quaternary (dacitic plugs). The authors tentatively relate this diversity to the development of a slab tear linked with the subduction of the fossil South China Sea ridge beneath the Baguio area.  相似文献   

Geologically Constrained Probabilistic Mapping of Gold Potential, Baguio District, Philippines   总被引：1，自引：0，他引：1  

Emmanuel John M. Carranza  Martin Hale 《Natural Resources Research》2000,9(3):237-253

Binary predictor patterns of geological features are integrated based on a probabilistic approach known as weights of evidence modeling to predict gold potential. In weights of evidence modeling, the log _e of the posterior odds of a mineral occurrence in a unit cell is obtained by adding a weight, W ⁺ or W ^– for presence of absence of a binary predictor pattern, to the log _e of the prior probability. The weights are calculated as log _e ratios of conditional probabilities. The contrast, C = W ⁺ – W ^–, provides a measure of the spatial association between the occurrences and the binary predictor patterns. Addition of weights of the input binary predictor patterns results in an integrated map of posterior probabilities representing gold potential. Combining the input binary predictor patterns assumes that they are conditionally independent from one another with respect to occurrences.  相似文献   

黄岩海山链俯冲与吕宋岛斑岩铜金成矿     

詹美珍  孙卫东  凌明星  李贺 《岩石学报》2015,31(7):2101-2114

菲律宾吕宋岛上约5Ma以来的斑岩铜金矿床主要集中在北部的Baguio和Mankayan地区,它们在时空上与黄岩海山链密切相关。1907~2013年间的地震数据表明,在吕宋岛中部(16°N)附近存在地震稀疏带。吕宋岛上的斑岩铜金矿床分布在该地震稀疏带的两侧。收集到的相应时期埃达克岩的Sr/Y-(La/Yb)N、Sr/Y-Y和La/Yb-Yb图解表明,这些埃达克岩几乎都是洋壳部分熔融形成的。与吕宋岛北部侵入型埃达克岩相比,位于16°N附近的埃达克岩具有更高的Sr含量,这可能与南海古扩张脊俯冲撕裂形成的板片窗有关。斜长石是辉长岩的主要矿物之一,因此,撕裂的洋壳边缘的辉长岩层部分熔融,形成具有更高Sr含量的埃达克质岩浆。而位于吕宋岛南部Bataan弧中的埃达克质火山岩,可能是在南海古扩张脊俯冲之前形成的。根据已发表的斑岩铜金矿床数据,Mankayan地区的成矿年龄在约3.5~1.4Ma,Baguio地区的成矿年龄在约3.1~0.5Ma之间,有从北向南变年轻的趋势,这与黄岩海山链沿马尼拉海沟向南迁移一致。此外,吕宋岛北部Mt.Cagua到Baguio之间存在一个延伸了220km的第四纪火山活动的空隙,该区域大部分火山已经在中新世停止活动。这可能是黄岩海山链的俯冲使得俯冲倾角逐渐变缓、挤压加强而导致的。同时期的斑岩铜矿床正好分布在这一火山空隙中,是俯冲洋壳部分熔融的产物。  相似文献   

83 Ma rhyolite from Mindoro – evidence for Late Yanshanian magmatism in the Palawan Continental Terrane (Philippines)     

Ulrich Knittel 《Island Arc》2011,20(1):138-146

The discovery of a low‐grade meta‐rhyolite with an age of 83 ± 1 Ma documents a so‐far unknown episode of magmatism in northern Mindoro Island, which is located at the northeastern edge of the Palawan Continental Terrane. This terrane is thought to have rifted from Southeast China in the Oligocene as a result of the opening of the South China Sea. Rhyolite volcanism was widespread in southeastern China in the Cretaceous; hence this discovery provides the first direct link between the geological evolution of the Palawan Continental Terrane and Southeast China in Cretaceous time. In addition, it provides further evidence that the northeastern part of Mindoro is indeed part of the Palawan Continental Terrane and not part of the Philippine Mobile Belt to the east, a previously contentious issue.  相似文献