Constraints on Cation Order in Calcium-rich Sedimentary Dolomite   总被引：2，自引：0，他引：2  

Richard J. Reeder 《Aquatic Geochemistry》2000,6(2):213-226

Most sedimentary Ca-rich dolomite in pre-Holocenerocks is known to exhibit a fine-scale modulation inTEM images, reflecting a domain structure of which onecomponent is a low-symmetry variant of dolomite. Thevarious structural models proposed for thelow-symmetry component involve Ca–Mg order patternsthat are different from that in dolomite. Caution istherefore required for interpretation of X-raydiffraction data, which average over the entirestructure. The average structures of two Ca-richdolomites having a structural modulation are refinedusing single-crystal intensity data. The resultsindicate a poor fit using a dolomite model, which isconsistent with the findings from TEM and electrondiffraction indicating that one component of thedomain structure is different than dolomite. Resultsalso indicate that average model A and B cation siteshave mixed Ca–Mg occupancy, which provides someconstraints on possible models for the low-symmetrydomains.  相似文献   

Textural evidence for dilatant (shear thickening) rheology of magma at high crystal concentrations     

J. V. Smith   《Journal of Volcanology and Geothermal Research》2000,99(1-4)

Investigation of the rheology of magmas at high crystal concentrations by experimental means has proved problematic. An alternative approach is to study textures of igneous rocks that not only preserve evidence of the kinematics of magma flow, such as flow direction, but can also preserve evidence of rheology. Flow textures in multiply intruded trachyte dykes on Fraser Island, eastern Australia record evidence of dilatant flow during solidification. This conclusion is reached by interpretation of microscopic ductile shear zones that disrupt the groundmass of aligned feldspar laths. Detailed three-dimensional investigation demonstrates that the dihedral angle between conjugate micro-shear zones is approximately 65°. This conjugate angle is equivalent to that observed in dilatant granular materials such as sand. Dilatant behaviour is synonymous with shear thickening rheology indicating that the magma flow is time-dependent and resists high flow rates. Some of the dykes contain autobrecciation fragments that may represent localities where the ductile flow rate threshold was exceeded. Newtonian or pseudoplastic (shear thinning) rheology of crystal-poor magmas must progressively give way to shear thickening rheology during cooling and increasing crystal concentration.  相似文献   

Octahedral cation ordering in olivine at high temperature. I: in situ neutron single-crystal diffraction studies on natural mantle olivines (Fa12 and Fa10)     

R. Rinaldi  G. Artioli  C. C. Wilson  G. McIntyre 《Physics and Chemistry of Minerals》2000,27(9):623-629

Crystallographic determinations on natural olivine single crystals of mantle composition and origin, carried out by in situ neutron diffraction at high temperature, show that the octahedrally co-ordinated Fe²⁺ and Mg cations undergo two successive trends of cation ordering with increasing temperature. An initial slight preference of Fe²⁺ for site M1, up to a temperature of about 850?°C, is followed by a reverse-ordering reaction with a site preference exchange between the two cations. The cross-over between the two regimes of ordering, corresponding to a situation of complete disorder, occurs at about 900?°C. Above this temperature Fe²⁺ progressively and strongly segregates into site M2 up to 1300?°C, the practical limit of the experimental setup utilized in the experiments. Care was taken to ensure that no chemical changes occurred in the crystals (i.e. oxidation), as testified by Mössbauer spectroscopy determinations carried out before and after the heat treatment. The cation-ordering behaviour is reflected in temperature-dependent changes of geometrical and atomic displacement parameters occurring in the octahedral sites M1 and M2. A thermodynamical explanation of this behaviour is proposed in terms of a prevailing vibrational contribution to entropy.  相似文献   

Monte Carlo simulation of scintillation crystal detector for formation element logging     

HAN Ruiyi  WANG Zhuwen 《世界地质(英文版)》2019,22(2):128-132

Formation elements logging is a neutron gamma spectroscopy logging technique used to acquire the content of elements and minerals by recording the gamma ray produced by the reaction of neutron and elemental nucleus in the formation. It has a wide usage in discriminating complex lithology and evaluating unconventional reservoir. The Monte Carlo simulation model of formation elements logging tool is established in this paper, with which the effects of tool parameters including the material and length of the scintillation crystal and source spacing on logging responses are modeled. The results show that the energy response of LaBr_3: Ce crystal is better than others, and the detection efficiency increases with the crystal length but decrease with source spacing. The above results may be used as a reference for optimizing the tool structure design.  相似文献   

基于闪锌矿晶体中受激电磁耦子散射产生可调谐太赫兹波的理论研究     

李忠洋  姚建铨  李俊  邴丕彬  徐德刚  王鹏 《海洋学报》2010,32(9):6237-6242

基于受激电磁耦子散射原理,采用已报道的利用非线性光学参量振荡方法产生可调谐太赫兹波的实验条件作为理论分析的实验模型,以GaAs,GaP, InP,ZnTe晶体为代表,计算分析了在闪锌矿晶体中参量振荡产生太赫兹波的吸收、增益特性,对输出THz波的调谐特性给出了详尽分析.分析太赫兹波高效耦合输出的腔型结构,并与掺氧化镁铌酸锂晶体组成的太赫兹波参量振荡器做对比.  相似文献   

局域椭圆偏振光束强聚焦性质的研究   总被引：2，自引：0，他引：2  

徐凯  杨艳芳  何英  韩小红  李春芳 《海洋学报》2010,32(9):6125-6130

数值计算了局域椭圆偏振光束强聚焦时在焦平面上的横向场强分布、纵向场强分布、横向能流以及纵向角动量分布.结果显示在焦平面上光束总的纵向角动量为零,但在不同象限光束具有不同方向的纵向角动量.当相位延迟角度在0到π之间变化时横向场强分布基本不变,但纵向场强分布有很明显的变化.液晶相位延迟器由外部电压控制,使其相位延迟角度能在0到π之间可以连续取值.因而液晶相位延迟器的外接电压可以实现对焦平面上的纵向场强以及纵向角动量的实时调控.  相似文献   

彩色全息显示中液晶空间光调制器位相调制偏差的矫正方法   总被引：2，自引：0，他引：2  

郑华东  于瀛洁  代林茂  王涛 《海洋学报》2010,32(9):6145-6151

采用三基色激光照明并结合时分复用或空间复用技术,可实现基于液晶空间光调制器(LC-SLM)的彩色全息显示. 但由于在不同激光波长入射条件下LC-SLM的位相调制特性曲线不同,难以同时满足多波长入射条件下2π线性位相调制的要求,致使彩色全息再现结果受到共轭像和零级斑的干扰. 针对该问题,本文通过实验测试获得LC-SLM在不同波长入射时的位相调制特性曲线,并分析了RGB激光器各分量的位相调制特性曲线非线性偏差和调制幅度偏差对多阶位相型傅里叶变换相息图再现效果的影响. 根据"查表法"建立了各波长入射条件下满足2  相似文献   

相变前的热力学平衡态对铁电液晶排列的影响     

唐先柱  彭增辉  刘永刚  鲁兴海  宣丽 《海洋学报》2010,32(9):6261-6265

本实验选用ZLI-3654型铁电液晶(FLC)以及SE-3140型取向剂制备FLC器件样品,通过改变FLC相变过程中的降温速率以及相变前的热力学平衡态来研究FLC相变前的热力学平衡态对FLC排列的影响,共进行了十组实验.实验后,将FLC器件静态对比度进行比较,得出手性向列相到近晶A相(N^*-SmA)相变前的热力学平衡态对FLC实现均匀排列起着极其重要的作用的结论.实验结果表明:器件的静态对比度可高达620 ∶1, N^*-SmA相变前的热力学平衡态有利于形成高对比  相似文献   

高效异质结构四波长波分复用器的设计与优化     

叶涛  徐旭明 《海洋学报》2010,32(9):6273-6278

将两光子晶体单模波导平行、邻近放置构成一个光子晶体波导耦合结构.根据耦合和解耦合理论,设计了一种新型的高效异质结构四波长波分复用器.应用时域有限差分法模拟了该器件的效率,并通过改变一排介质柱的折射率,实现了较高的透射率.进一步发现在入射口处添加三对介质柱,可以有效地降低系统的反射,实现了四个波长的高效传输,四个波长的透射率均超过了90%.该器件不仅具有较高的透射率,而且其尺寸仅为36 μm×17 μm,在未来的光子集成回路中具有潜在的应用价值.  相似文献   

一种胶体光子晶体修饰的光纤     

刘青  王鸣  郭文华  闫海涛  喻平 《海洋学报》2010,32(10):7086-7090

设计了一种胶体光子晶体修饰的光纤. 采用恒温快速蒸发法直接在经切割刀处理后的光纤端面生长胶体晶体,再与另一根切割后的光纤在毛细玻璃管中完成对接,制备成胶体光子晶体修饰的光纤. 用扫描电子显微镜和光谱分析仪对样品的形貌、结构以及光学特性进行分析. 实验结果表明,粒径为640 nm、体积分数约为0.5%的SiO₂胶体微球溶液在60 ℃的情况下沉积,大约12 h后可得到质量较高的胶体光子晶体. 在SEM下,观察到端面的胶体晶体为面心立方(fcc)结构. 透射光谱证明,该结构在(111)面上  相似文献