Structure refinement of astrophyllite   总被引：1，自引：0，他引：1  

马喆生  李国武  施倪承  周湖云  叶大年 《中国科学D辑(英文版)》2001,44(6):508-516

The crystal structure of astrophyllite K₂Na(Fe, Mn, Mg,□)₇[Ti₂(Si₄O₁₂)₂|O₃](OH, F)₄ has been refined. The dimensions of the triclinic unit cell are: a = 0.5359(2) nm,b = 1.1614(4) nm, c = 1.1861(4) nm, α= 113.16(2)°, β= 103.04(2)°,γ= 94.56(2)°,V = 0.6495(5) nm³, Z= 1, space group P1, R=0.057 for 5308 reflections |F_o|>3σ|F_o|. According to structural and compositional differences the monoclinic astrophyllite K₂NaNa(Fe, Mn)₄Mg₂Ti2[Si₄O₁₂]₂(OH)₄(OH, F)₂ and astrophyllite should be considered as two different mineral species. Astrophyllite, monoclinic astrophyllite, bafertisite and lamprophyllite contain heteropolyhedral sheets which topologically are related with Si, O sheets of mica where one or several SiO₄ tetrahedra are replaced by TiO _n polyhedra. Therefore this heterophyllotitanosilicate series represents a kind of functional substitution in inorganic crystals.  相似文献   

Bestimmung der Phytoplanktonvolumina — Methodik und Ergebnisse am Beispiel Niederrhein     

Marlies Pohlmann  Günther Friedrich 《Limnologica》2001,31(3)

For data treatment of phytoplankton countings in the Lower Rhine the specific biovolume was calculated. The used computer-aided method is described, and the correlation between phytoplankton biomass, cell number and chlorophyll a is presented.  相似文献   

Malaria and related environmental issues in India: a case study of Aligarh city     

Abha Lakshmi Singh  Atiqur Rahman 《GeoJournal》2001,53(1):89-99

Malaria is one of the most widespread diseases in the world. Endemic malaria no longer occurs in many temperate zones as a result of social and economic improvement. At present malaria is the Third World's most dreaded killer. It kills over 1 million people and causes 300–500 million episodes of illness. In India, malaria-reported deaths have shown an upward trend. In 1955, a drive to eradicate malaria was launched in India. But after initial success it failed and malaria made a comeback. Malarial mosquitoes generally prefer unpolluted natural breeding sites but now they have adapted to the changed urban environment. In this paper, an attempt has been made to examine the occurrence of malaria and related environmental issues in a small town of India. Aligarh city, lying in the shadow of the country's capital New Delhi, was selected as a case study. Data were collected mainly from household surveys with the help of questionnaire interviews. About 2,185 households belonging to different income groups were sampled. The differences in the occurrence of malaria in the different income households (in 87% low, 69% lower-middle, 65% middle, 14% upper-middle, and 5% upper) suggest that most of these differences are related to the environmental conditions existing inside and outside their homes, such as poor drainage system, poor sullage disposal, open blocked drains, waterlogging and indoor water storage in open containers. Commitment both by the Government and local residents is needed to improve the environmental conditions and eradicate malaria.  相似文献   

Location and quantitative analysis of OH in coesite     

M. Koch-Müller  Y. Fei  E. Hauri  Z. Liu 《Physics and Chemistry of Minerals》2001,28(10):693-705

 The incorporation of hydrogen (deuterium) into the coesite structure was investigated at pressures from 3.1 to 7.5 GPa and temperatures of 700, 800, and 1100 °C. Hydrogen could only be incorporated into the coesite structure at pressures greater 5.0 GPa and 1100 °C . No correlation between the concentration of trace elements such as Al and B and the hydrogen content was observed based on ion probe analysis (1335 ± 16 H ppm and 17 ± 1 Al ppm at 7.5 GPa, 1100 °C). The FTIR spectra show three relatively intense bands at 3575, 3516, and 3459 cm⁻¹ (ν₁ to ν₃, respectively) and two very weak bands at 3296 and 3210 cm⁻¹ (ν₄ and ν₅, respectively). The band at 3516 cm⁻¹ is strongly asymmetric and can be resolved into two bands, 3528 (ν_2a) and 3508 (ν_2b) cm⁻¹, with nearly identical areas. Polarized infrared absorption spectra of coesite single-crystal slabs, cut parallel to (0 1 0) and (1 0 0), were collected to locate the OH dipoles in the structure and to calibrate the IR spectroscopy for quantitative analysis of OH in coesite (ɛ _{i ,tot}=190 000 ± 30 000 l mol⁻¹ _H2O cm⁻²). The polarized spectra revealed a strong pleochroism of the OH bands. High-pressure FTIR spectra at pressures up to 8 GPa were performed in a diamond-anvil cell to gain further insight into incorporation mechanism of OH in coesite. The peak positions of the ν₁, ν₂, and ν₃ bands decrease linearly with pressure. The mode Grüneisen parameters for ν₁, ν₂, and ν₃ are −0.074, −0.144 and −0.398, respectively. There is a linear increase of the pressure derivatives with band position which follows the trend proposed by Hofmeister et al. (1999). The full widths at half maximum (FWHM) of the ν₁, ν₂, and ν₃ bands increase from 35, 21, and 28 cm⁻¹ in the spectra at ambient conditions to 71, 68, and 105 in the 8 GPa spectra, respectively. On the basis of these results, a model for the incorporation of hydrogen in coesite was developed: the OH defects are introduced into the structure by the substitution Si^4+(Si2)+4O²⁻= ^[4]□^(Si2) + 4OH⁻, which gives rise to four vibrations, ν₁, ν_2a, ν_2b, and ν₃. Because the OH(D)-bearing samples do contain traces of Al and B, the bands ν₄ and ν₅ may be coupled to Al and/or B substitution. Received: 19 December 2000 / Accepted: 23 April 2001  相似文献   

在概括平差模型下的粗差检验理论     

于宗俦 《测绘学报》1992,21(4):241-248

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一个世界最早光象分类体系的探讨——复原先秦“十煇”的研究     

王鹏飞 《南京气象学院学报》1992,(2)

《周礼》十煇为世界最早的光象分类体系。其含义历来众说纷纭。有探讨、重建并评价的必要。本文比照历史上有影响的五家十煇定义,分析其含糊矛盾之处,提出复原十煇原义的三条原则,从而重建了十煇原义表,介绍了古代观测十煇的方法。最后对《周礼》十煇这个光象分类体系进行了评价。  相似文献   

Estimation and improvement in the geolocation accuracy of rational polynomial coefficients with minimum GCPs using KOMPSAT-3A     

Namhoon Kim  Yoonjo Choi  Junsu Bae 《地理信息系统科学与遥感》2020,57(6):719-734

ABSTRACT

In this paper, we propose a method to regenerate Rational Polynomial Coefficients (RPCs) using KOMPSAT-3A imagery and to reduce the geolocation error using minimum ground control points (GCPs). To estimate the new RPCs, the physical sensor model fitted to KOMPSAT-3A imagery was utilized and virtual GCPs over the study area were created. The size of the virtual grid used was 20x20x20. To remove the sensor-related errors in physical sensor model, three different image correction models (image coordinate translation model, shift and drift model, and affine transformation model) were additionally applied. We evaluated our proposed method in two areas within Korea, one in urban (Seoul) and one in rural (Goheung) areas. The results showed that there was a significant improvement after applying the suggested approach in the two areas. The image coordinate translation model is suggested in terms of GCP requirement and expected errors estimated from the error propagation analysis using Gauss–Markov Model (GMM).  相似文献   

A unified theory of the formation of galactic bars     

V. L. Polyachenko  E. V. Polyachenko 《Astronomy Letters》2003,29(7):447-462

We give arguments for a basically unified formation mechanism of slow (Lynden-Bell) and fast (common) galactic bars. This mechanism is based on an instability that is akin to the well-known instability of radial orbits and is produced by the mutual attraction and alignment of precessing stellar orbits (so far, only the formation of slow bars has been explained in this way). We present a general theory of the low-frequency modes in a disk that consists of orbits precessing at different angular velocities. The problem of determining these modes is reduced to integral equations of moderately complex structure. The characteristic pattern angular velocities Ω_p of the low-frequency modes are of the order of the mean orbital precession angular velocity \(\bar \Omega _{pr}\). Bar modes are also among the low-frequency modes; while \(\Omega _p \approx \bar \Omega _{pr}\) for slow bars, Ω_p for fast bars can appreciably exceed even the maximum orbital precession angular velocity in the disk Ω _pr ^max (however, it remains of the order of these precession angular velocities). The possibility of such an excess of Ω_p over Ω _pr ^max is associated with the effect of “repelling” orbits. The latter tend to move in a direction opposite to the direction in which they are pushed. We analyze the pattern of orbital precession in potentials typical of galactic disks. We note that the maximum radius of an “attracting” circular orbit r_c can serve as a reasonable estimate of the bar length l_b. Such an estimate is in good agreement with the available results of N-body simulations.  相似文献   

The inhibition of marine nitrification by ocean disposal of carbon dioxide   总被引：1，自引：0，他引：1  

Huesemann MH  Skillman AD  Crecelius EA 《Marine pollution bulletin》2002,44(2):142-148

In an attempt to reduce the threat of global warming, it has been proposed that the rise of atmospheric carbon dioxide concentrations be reduced by the ocean disposal of CO2 from the flue gases of fossil fuel-fired power plants. The release of large amounts of CO2 into mid or deep ocean waters will result in large plumes of acidified seawater with pH values ranging from 6 to 8. In an effort to determine whether these CO2-induced pH changes have any effect on marine nitrification processes, surficial (euphotic zone) and deep (aphotic zone) seawater samples were sparged with CO2 for varying time durations to achieve a specified pH reduction, and the rate of microbial ammonia oxidation was measured spectrophotometrically as a function of pH using an inhibitor technique. For both seawater samples taken from either the euphotic or aphotic zone, the nitrification rates dropped drastically with decreasing pH. Relative to nitrification rates in the original seawater at pH 8, nitrification rates were reduced by ca. 50% at pH 7 and more than 90% at pH 6.5. Nitrification was essentially completely inhibited at pH 6. These findings suggest that the disposal of CO2 into mid or deep oceans will most likely result in a drastic reduction of ammonia oxidation rates within the pH plume and the concomitant accumulation of ammonia instead of nitrate. It is unlikely that ammonia will reach the high concentration levels at which marine aquatic organisms are known to be negatively affected. However, if the ammonia-rich seawater from inside the pH plume is upwelled into the euphotic zone, it is likely that changes in phytoplankton abundance and community structure will occur. Finally, the large-scale inhibition of nitrification and the subsequent reduction of nitrite and nitrate concentrations could also result in a decrease of denitrification rates which, in turn, could lead to the buildup of nitrogen and unpredictable eutrophication phenomena. Clearly, more research on the environmental effects of ocean disposal of CO2 is needed to determine whether the potential costs related to marine ecosystem disturbance and disruption can be justified in terms of the perceived benefits that may be achieved by temporarily delaying global warming.  相似文献   

Influence of wave groups on SSC patterns over vortex ripples     

Paul V. Villard  Philip D. Osborne  Christopher E. Vincent 《Continental Shelf Research》2000,20(17):1

Estimates of spatial and temporal variations in suspended sand concentrations (SSC) made with a multi-transducer Acoustic Backscatter Sensor (ABS) under a repeated wave group over a mobile rippled bed in the wave research flume at the National Hydraulics Laboratory in Ottawa, Canada, reveal an number of complex and intriguing patterns. Ensemble averages of 8 nearly identical wave groups provided much more robust estimates of SSC and allowed a detailed examination of the wave group effects. The largest SSC near the bed (< 0.10 m) occurs in phase with the largest waves in the group. Above approximately 0.10 m elevation, SSC lags behind the near bed SSC by as much as 2–3 waves; introducing significant curvature (on a semi-log plot) to the SSC profile. The log linear segments of the SSC profile grow and decay systematically on the scale of the wave group. The range in lengths of log-linear profile segments ( 0.03–0.355 m) suggest that the boundary layer thickness also fluctuates throughout the passage of the wave group. Furthermore, there are significant variations in the patterns of SSC, which occur under the largest and smallest waves in the group. Under the largest waves vertical bands of alternating high and low SSC produce an intra-wave modulation in the upper water column ( 0.075–0.30 m). The equivalent horizontal excursion of these bands scales to the ripple length. Under the smaller waves the intra-wave modulation of the SSC disappears and is replaced by temporally homogenous suspension that expands vertically through several individual wave cycles. The former pattern of homogenous suspension appears to be associated with growth of a boundary layer due to the persistent uni-directional horizontal flow during this part of the group together with the persistence of antecedent bed generated turbulence and vorticity which maintains the suspension. The latter pattern of bands of high and low SSC indicates a strong temporal and spatial constraint on the SSC (phase coupling) induced by the presence of the bedforms which may be enhanced by strong reversals in both flow and vorticity under the large waves in the group.  相似文献