Helium, radon and radiocarbon studies on a regional aquifer system of the North Gujarat-Cambay region, India     

Meetu Agarwal  R.D. Deshpande 《Chemical Geology》2006,228(4):209-232

The study reports the age evolution of groundwater as it flows from the recharge area through a regional alluvial aquifer system in North Gujarat-Cambay region in western India. Radiocarbon (¹⁴C), ⁴He and ⁴He / ²²²Rn dating methods have been employed. Sediments from a drill core in the Cambay Basin were also analysed for uranium (U) and thorium (Th) concentrations and the measured values have been used to estimate the ⁴He and ²²²Rn production rate for groundwater age calculations. Additionally, factors controlling the distribution of ²²²Rn, ⁴He and temperature anomalies in groundwater, vis-à-vis their relation to the tectonic framework and lithology of the study area, have also been examined.The multi-isotope study indicated a reasonable correspondence in groundwater age estimates by the three methods employed. The groundwater ¹⁴C ages increased, progressively, in the groundwater flow direction: from the foothills of Aravalli Mountains in the east, and reached a value of ∼35 ka towards the region of lowest elevation, linking Little Rann of Kachchh (LRK)-Nalsarovar (NS)-Gulf of Khambhat (GK) in the western part of the study area. In this region, groundwater ages obtained for free flowing thermal wells and springs employing ⁴He and ⁴He / ²²²Rn systematics are in the order of million years. Such anomalous ages are possibly due to enhanced mobilisation and migration of ‘excess helium’ from hydrothermal circulation vents along deep-seated faults. Excluding such anomalous cases and considering all uncertainties, presently estimated ⁴He and ⁴He / ²²²Rn groundwater ages are in reasonable agreement with ¹⁴C age estimates in the Cambay Basin for helium release factor (Λ_He) value of 0.4 ± 0.3. The ⁴He method also indicated west-southwards progression of groundwater ages up to ∼100 ka beyond the Cambay Basin.Large ‘excess helium’ concentrations are also seen to be generally associated with anomalous groundwater temperatures (> 35 °C) and found to overlie some of the basement faults in the study area, particularly along the east and the west flanks of the Cambay Basin. Groundwater ²²²Rn activities in most of the study area are 800 ± 400 dpm/l. But, a thermal spring at Tuwa on the east flank of the Cambay Basin, having granitic basement at shallow depth, recorded the highest ²²²Rn activity (∼63,000 dpm/l).  相似文献   

系列^14C样品贝叶斯法日历年龄校正研究进展     

尹金辉郑勇刚  刘粤霞卢演俦 《地球科学进展》2007,22(3):297-304

系列^14C样品贝叶斯法日历年龄校正研究已成为当前^14C年代学中一个热点,系统综述了时序已知、时序间隔已知和时序间隔近似已知系列^14C样品日历年龄校正研究的历史、原理、计算方法及其在树轮、泥炭、地层等领域上应用进展,对影响系列样品贝叶斯分析获得^14C日历年龄区间的主要因素以及未来发展方向作了归纳。大量事例研究结果表明系列样品贝叶斯分析的实质在于贝叶斯方法从统计的角度灵活地把地层信息以概率方式加入到^14C日历年龄校正过程中,获得比单个^14C年代校正精度更高的日历年龄。  相似文献   

丽水市四季起始日期的气候演变特征     

姜燕敏 《沙漠与绿洲气象(新疆气象)》2013,7(6):58-62

根据丽水市国家气象观测站1953-2010年逐日气温资料,运用趋势分析、Morlet小波变化和Mann-Kendall检验对四季起始日期的气候变化特征、趋势演变规律和突变转折情况进行了研究。结果表明：四季起始日期,春季约在3月中旬,夏季在5月底,秋季在9月下旬,冬季在11月下旬,且春、秋季的长度较短,只有2个月左右,夏、冬季的长度较长,长达4个月。Morlet小波分析四季起始日期的周期变化特征,主要体现在年代际时间尺度上,且各周期强度有所差异,预测春、夏季起始日将按照提前趋势发展,秋、冬季起始日继续延后状态。Mann-Kendall检验得出,春、夏两季起始日期在21世纪初发生由推后转向提前的突变,而秋、冬两季起始日突变点都体现在20世纪60年代。  相似文献   

Exploring the dating of “dirty” speleothems and cave sinters using radiocarbon dating of preserved organic matter     

《Quaternary Geochronology》2017

Speleothems and other carbonate deposits such as tufa containing high proportions of detrital material can be difficult to chemically date due to detrital thorium levels causing a high level of error in conventional U-Th disequilibrium dating. Here we investigate the use of an alternative technique centring on radiocarbon dating of organic matter preserved within the detrital fraction. Non-acid soluble humic, particulate and detritally absorbed organic matter was recovered from eight samples from a flowstone sinter formed within a roman aqueduct at Trento in Italy with a maximum age of 100 CE (1850 cal yr BP), and two repeat samples from a dripstone formed within the 20th Century on a wire fence at Lilly-Pilly Cave, Buchan Caves Reserve in Victoria, Australia. In the aqueduct samples the median calibrated ¹⁴C ages ranged from 2232 to 2889 cal yr BP, with 95.4% probability age range in the youngest and oldest samples of 2153–2337 and 2342–3449 cal yr BP respectively. The median age of the more modern dripstone was 336 cal yr BP, with a 95.4% probability age range of 148–486 cal yr BP. These results provide very approximate ball-park estimates of the age of the sample, but are consistently too old when compared to the known maximum ages of formation. It is hypothesised that this offset is due to a combination of the nature of the organic carbon transported from the source organic matter pools, and reworking of both modern and old organic carbon by in situ microbial communities.  相似文献   

Radiocarbon and optically stimulated luminescence dating of sediments from Lake Karakul,Tajikistan     

《Quaternary Geochronology》2017

Lake Karakul in the eastern Pamirs is a large and closed-basin lake in a partly glaciated catchment. Two parallel sediment cores were collected from 12 m water depth. The cores were correlated using XRF analysis and dated using radiocarbon and OSL techniques. The age results of the two dating methods are generally in agreement. The correlated composite core of 12.26 m length represents continuous accumulation of sediments in the lake basin since 31 ka. The lake reservoir effect (LRE) remained relatively constant over this period. High sediment accumulation rates (SedARs) were recorded before 23 ka and after 6.5 ka. The relatively close position of the coring location near the eastern shore of the lake implies that high SedARs resulted from low lake levels. Thus, high SedARs and lower lake levels before 23 ka probably reflect cold and dry climate conditions that inhibited the arrival of moist air at high elevation in the eastern Pamirs. Low lake levels after 6.5 ka were probably caused by declining temperatures after the warmer early Holocene, which had caused a reduction in water resources stored as snow, ice and frozen ground in the catchment. Low SedARs during 23–6.5 ka suggest increased lake levels in Lake Karakul. A short-lived increase of SedARs at 15 ka probably corresponds to the rapid melting of glaciers in the Karakul catchment during the Greenland Interstadial 1e, shortly after glaciers in the catchment had reached their maximum extents. The sediment cores from Lake Karakul represent an important climate archive with robust chronology for the last glacial–interglacial cycle from Central Asia.  相似文献   

High-resolution ∼55 ka paleomagnetic record of Biển Hồ maar lake sediment from Vietnam in relation to detailed 14C and 137Cs geochronologies     

《Quaternary Geochronology》2023

Vietnam's Central Highlands in Pleiku feature numerous volcanic craters (i.e. maars) formed over 0.2 Ma ago that contain continuous high-resolution lacustrine sediment records extending from the Late Pleistocene through the Holocene. Their evolution and sedimentary proxies are potentially powerful archives for interpretation of East-Asian monsoon variability across Vietnam, as well as for local to regional changes in landcover. The focus of this study is to develop a reliable chronology for the Biển Hồ 25-m-long lake sediment sequence in Vietnam's Central Highlands. We present a combined sediment chronology extending back to 55 ka cal BP that is based on ¹³⁷Cs surface sediment chronology, paleomagnetic dating, and 47 ¹⁴C dates distributed evenly throughout the sequence. Based on sedimentary facies analysis and a smooth age-depth model based on ¹³⁷Cs and ¹⁴C data, we infer a long-term stable rate of sedimentation in Biển Hồ lake without unconformities or erosional hiatuses, except for the uppermost section (ca. 100 years) where human activities increase the rate of sedimentation significantly. The Biển Hồ sequence thus provides a complete and uninterrupted record of the lake's depositional history. The present contribution is a geochronologic opening salvo for future contributions from Biển Hồ lake featuring multi-disciplinary evidence for longer-term paleoclimate and environmental changes.  相似文献   

A simulation approach to quantify the parameters and limitations of the radiocarbon wiggle-match dating technique     

《Quaternary Geochronology》2023

Worldwide, radiocarbon (¹⁴C) wiggle-match dating is increasingly used to produce high-resolution, ‘near-absolute’, chronologies in a range of different contexts, yet the exact properties and limitations of the technique are not well understood. Here we present the results of extensive and systematic simulations that allow the precision limits of wiggle-match dating to be quantified for different time periods. We have also been able to quantify the effect of modeling decisions on possible precision in terms of how many measurements to make, how far apart to space them, and which calibration curve to employ. While recent trends towards large numbers of annually spaced measurements can improve precision, the effect is generally small, except when the dated sequence falls on a plateau in the calibration curve. Finally, we demonstrate that wiggle-matching against an unsmoothed record of atmospheric ¹⁴C can provide better precision than wiggle-matching against the smoothed IntCal20 or SHCal20 curves. We argue, however, that until intra-hemispheric variation in ¹⁴C is better understood, the hemispheric averages provided by IntCal20 and SHCal20 will be the more appropriate datasets for most wiggle-match applications.  相似文献   

Pitfalls in the AMS radiocarbon-dating of terrestrial macrofossils     

B. Wohlfarth  G. Skog  G. Possnert  B. Holmquist 《第四纪科学杂志》1998,13(2):137-145

The AMS ¹⁴C technique has the advantage that small samples of Late Quaternary age can be dated with high accuracy, and that errors due to reservoir effects can be avoided if specifically determined terrestrial micro- and macrofossils are measured. However, to obtain such high-accuracy measurements, it is important how small samples are handled prior to treatment in the radiocarbon laboratories. Here we present a set of 51 AMS ¹⁴C measurements, of which 31 dates gave expected ages and 20 dates resulted in anomalously young ages, despite the fact that all samples consisted of clearly identified Late Weichselian terrestrial plant macrofossils. To evaluate possible sources of error, we compared these samples in respect to preparation methods, sample storage and sample weight. Our results show that the long-term storage of wet macrofossil samples appears to have a significant effect on the radiocarbon age obtained, even when the samples are kept cool. Fungi or micro-organisms may easily be incorporated into a sample during preparation and identification, and can easily contribute to the contamination of a sample, if stored cool and wet for several months. © 1998 John Wiley & Sons, Ltd.  相似文献   

Methane sources in gas hydrate-bearing cold seeps: Evidence from radiocarbon and stable isotopes   总被引：1，自引：0，他引：1  

J.W. Pohlman  J.E. Bauer  E.A. Canuel  K.S. Grabowski  D.L. Knies  C.S. Mitchell  M.J. Whiticar  R.B. Coffin 《Marine Chemistry》2009,115(1-2):102-109

Fossil methane from the large and dynamic marine gas hydrate reservoir has the potential to influence oceanic and atmospheric carbon pools. However, natural radiocarbon (¹⁴C) measurements of gas hydrate methane have been extremely limited, and their use as a source and process indicator has not yet been systematically established. In this study, gas hydrate-bound and dissolved methane recovered from six geologically and geographically distinct high-gas-flux cold seeps was found to be 98 to 100% fossil based on its ¹⁴C content. Given this prevalence of fossil methane and the small contribution of gas hydrate (≤ 1%) to the present-day atmospheric methane flux, non-fossil contributions of gas hydrate methane to the atmosphere are not likely to be quantitatively significant. This conclusion is consistent with contemporary atmospheric methane budget calculations.In combination with δ¹³C- and δD-methane measurements, we also determine the extent to which the low, but detectable, amounts of ¹⁴C (~ 1–2% modern carbon, pMC) in methane from two cold seeps might reflect in situ production from near-seafloor sediment organic carbon (SOC). A ¹⁴C mass balance approach using fossil methane and ¹⁴C-enriched SOC suggests that as much as 8 to 29% of hydrate-associated methane carbon may originate from SOC contained within the upper 6 m of sediment. These findings validate the assumption of a predominantly fossil carbon source for marine gas hydrate, but also indicate that structural gas hydrate from at least certain cold seeps contains a component of methane produced during decomposition of non-fossil organic matter in near-surface sediment.  相似文献   

Effects of social and climatic factors on building activity in the Czech lands between 1450 and 1950: a dendrochronological analysis     

Tom&#x; Kol&#x;  Petr Dobrovolný  Pter Szab  Tom&#x; Mikita  Tom&#x; Kyncl  Josef Kyncl  Irena Sochov  Ale&#x; Flídr  David Merta  Michal Rybní ek 《第四纪科学杂志》2022,37(1):123-132

The development of settlement and building activity is the result of socioeconomic, political and demographic changes in the past. However, accurate information on temporal variation in building activity is rather limited. Dendrochronological databases containing dated historical wooden constructions provide an important resource. We used 6514 tree-felling dates to reconstruct building activity in the Czech lands for the period 1450–1950. Comparing felling dates with historical events demonstrated that building activity was negatively associated with intense wars, particularly during the Thirty Years' War (1618–1648). After the Peace of Westphalia (1648), socioeconomic renewal and demographic growth were reflected in an upsurge of building activity, especially ecclesiastical buildings. While the construction of ecclesiastical and noble buildings culminated around the 1720s, rural buildings peaked in the 1780s and the 1820s. Although no direct effect of climate was demonstrated, adverse climatic conditions leading to harvest failures and subsequent famines (e.g. the ‘Hunger Years’ 1770–1772) significantly contributed to declines in building activity. In contrast, a higher number of felling dates were detected when strong and/or frequent windstorms occurred. This study provides a comprehensive understanding of building activity in Central Europe and advocates the use of dendrochronological databases for the investigation of human activities in history.  相似文献