Travel time controls the magnitude of nitrate discharge in groundwater bypassing the riparian zone to a stream on Virginia's coastal plain     

Samuel A. Flewelling  Janet S. Herman  George M. Hornberger  Aaron L. Mills 《水文研究》2012,26(8):1242-1253

Groundwater that bypasses the riparian zone by travelling along deep flow paths may deliver high concentrations of fertilizer‐derived NO₃^? to streams, or it may be impacted by the NO₃^? removal process of denitrification in streambed sediments. In a study of a small agricultural catchment on the Atlantic coastal plain of Virginia's eastern shore, we used seepage meters deployed in the streambed to measure specific discharge of groundwater and its solute concentrations for various locations and dates. We used values of Cl^? concentration to discriminate between bypass water recharged distal to the stream and that contained high NO₃^? but low Cl^? concentrations and riparian‐influenced water recharged proximal to the stream that contained low NO₃^? and high Cl^? concentrations. The travel time required for bypass water to transit the 30‐cm‐thick, microbially active denitrifying zone in the streambed determined the extent of NO₃^? removal, and hydraulic conductivity determined travel time through the streambed sediments. At all travel times greater than 2 days, NO₃^? removal was virtually complete. Comparison of the timescales for reaction and transport through the streambed sediments in this system confirmed that the predominant control on nitrate flux was travel time rather than denitrification rate coefficients. We conclude that extensive denitrification can occur in groundwater that bypasses the riparian zone, but a residence time in biologically active streambed sediments sufficient to remove a large fraction of the NO₃^? is only achieved in relatively low‐conductivity porous media. Instead of viewing them as separate, the streambed and riparian zone should be considered an integrated NO₃^? removal unit. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Field measurements of NO and NO2 emissions from fertilized and unfertilized soils   总被引：3，自引：0，他引：3  

F. Slemr  W. Seiler 《Journal of Atmospheric Chemistry》1984,2(1):1-24

Field measurements of NO and NO₂ emissions from soils have been performed in Finthen near Mainz (F.R.G.) and in Utrera near Seville (Spain). The applied method employed a flow box coupled with a chemiluminescent NO _x detector allowing the determination of minimum flux rates of 2 g N m^-2 h^-1 for NO and 3 g m^-2 h^-1 for NO₂.The NO and NO₂ flux rates were found to be strongly dependent on soil surface temperatures and showed strong daily variations with maximum values during the early afternoon and minimum values during the early morning. Between the daily variation patterns of NO and NO₂, there was a time lag of about 2 h which seem to be due to the different physico-chemical properties of NO and NO₂. The apparent activation energy of NO emission calculated from the Arrhenius equation ranged between 44 and 103 kJ per mole. The NO and NO₂ emission rates were positively correlated with soil moisture in the upper soil layer.The measurements carried out in August in Finthen clearly indicate the establishment of NO and NO₂ equilibrium mixing ratios which appeared to be on the order of 20 ppbv for NO and 10 ppbv for NO₂. The soil acted as a net sink for ambient air NO and NO₂ mixing ratios higher than the equilibrium values and a net source for NO and NO₂ mixing ratios lower than the equilibrium values. This behaviour as well as the observation of equilibrium mixing ratios clearly indicate that NO and NO₂ are formed and destroyed concurrently in the soil.Average flux rates measured on bare unfertilized soils were about 10 g N m^-2 h^-1 for NO₂ and 8 g N m^-2 h^-1 for NO. The NO and NO₂ flux rates were significantly reduced on plant covered soil plots. In some cases, the flux rates of both gases became negative indicating that the vegetation may act as a sink for atmospheric NO and NO₂.Application of mineral fertilizers increased the NO and NO₂ emission rates. Highest emission rates were observed for urea followed by NH₄Cl, NH₄NO₃ and NaNO₃. The fertilizer loss rates ranged from 0.1% for NaNO₃ to 5.4% for urea. Vegetation cover substantially reduced the fertilizer loss rate.The total NO _x emission from soil is estimated to be 11 Tg N yr^-1. This figure is an upper limit and includes the emission of 7 Tg N yr^-1 from natural unfertilized soils, 2 Tg N yr^-1 from fertilized soils as well as 2 Tg N yr^-1 from animal excreta. Despite its speculative character, this estimation indicates that NO _x emission by soil is important for tropospheric chemistry especially in remote areas where the NO _x production by other sources is comparatively small.  相似文献   

城市污水处理厂污泥利用现状及潜在环境问题   总被引：9，自引：0，他引：9  

陈军 《矿产与地质》2005,19(6):732-734

根据国家环保总局要求,在2010年前全国主要城市的污水处理率要达到70%,这将使我国的水环境得到明显改善,另一方面也带来了污泥的处置和利用问题.污泥是一种优质的有机肥料,有选择地控制使用,既可满足作物生长对养分的需要,又可培育土壤.符合污泥固废“减量化”和“资源化”的处置要求.  相似文献   

Effect of chemical fertilizers on the fractionation of Cu,Cr and Ni in contaminated soil   总被引：1，自引：0，他引：1  

Jie Liu  Chang-Qun Duan  Yi-Nian Zhu  Xue-Hong Zhang  Cheng-Xian Wang 《Environmental Geology》2007,52(8):1601-1606

Effect of chemical fertilizers (urea, NH₄Cl, Ca(NO₃)₂, KCl and KH₂PO₄) on the fractionation of Cu, Cr and Ni was studied by a 4-month incubation experiment. Using sequential extraction procedure, it was found that the application of fertilizers could change the distribution of Cu, Cr and Ni in the fractions of soil. Applying urea (CO(NH₂)₂) significantly decreased the concentrations of Cu, Cr and Ni in water soluble plus exchangeable (WE) fraction, but increased those in Fe–Mn oxides bound (FM) fraction (p < 0.01). However, application of NH₄Cl caused an increase in the WE fraction by 27.7% for Cu, 111.5% for Cr and 20.4% for Ni. The CO(NH₂)₂ raised the soil pH from 4.51 to 4.96, whereas NH₄Cl lowered the pH of soil by 0.44 units. The WE fraction of the three heavy metals was significantly increased, while the FM fraction was significantly decreased by adding KCl (p < 0.01). Moreover, the supply of KH₂PO₄ reduced the WE and carbonate bound (CB) fractions of Cu, Cr and Ni in the soil, however, it raised Cu and Ni in the residual (RS) fraction and Cr in the FM fraction. In addition, the mobility index indicated that KCl and NH₄Cl increased the mobility of Cu, Cr and Ni in the soil, whereas urea and KH₂PO₄ decreased the mobility of the three metals in the soil. These results suggest that applying chemical fertilizers does not only provide plant nutrients, but may also change the speciation and mobility of heavy metals in the soil.  相似文献   

桉树腐殖酸(HA)专用肥区域试验与配方的优选     

钱国钦 《福建地理》2007,(4)

采用随机区组设计,以等价投入的常规化肥为对照,开展专用肥多点施肥试验研究.通过专用肥对林木生长量、林相特征的影响分析,结果表明:与等价投入(肥料成本)的常规化肥相比,施用系列专用肥的林分生长量均显著或极显著地高于常规化肥处理,且叶片浓绿、树势强壮,施后19个月内,树高、胸径、材积分别提高了7.8%~51.8%、9.8%~53.0%和30%以上,叶片叶绿素含量提高26.3%~94.2%,叶面积指数提高41.0%~172.8%.经对HA桉树专用肥的增产性、适应性和稳定性的综合分析与评定,选出基肥专用的优化配方为:有机质≥30.0%、N P2O5 K2O≥6.0%(2.5-2.0-1.5)、腐殖酸总量≥8.0%,并加上适量的"绿滴"复合微生物菌剂(于施用时和基肥按每50 kg∶1 kg的量掺入);追肥专用的优化配方为:有机质≥20.0%、N P2O5 K2O≥20.0%(9-8-3)、腐殖酸总量≥6.0%.  相似文献   

Renewable energy strategies in England, Australia and New Zealand     

Geoff Kelly 《Geoforum》2007,38(2):326-338

The development of renewable energy sources is of prime interest to many countries seeking to pursue greenhouse gas emission reduction obligations. The increased use of renewables offers the possibility of not only contributing to emission reduction, but at the same time improving energy supply diversity and security, and developing employment and business in related supply industries. Two main mechanisms are in common use, one a quota (quantity) instrument often associated with tradable certificates, and the other a prescribed pricing mechanism. This paper considers the renewable energy development strategies of three countries (the UK, Australia, and New Zealand) all using a variant of the quota/certificate approach as the central instrument in their programs. The regulatory frameworks defining the application of the certificate systems differ notably, and the likely differing outcomes suggest that these regulatory settings may be at least as important as the selection of the basic policy instrument, in determining the overall success of programs of this nature.  相似文献   

利用牡蛎壳粉制备缓释氮肥的初步研究   总被引：1，自引：0，他引：1  

苗艳丽洪鹏志  宋文东 《广东海洋大学学报》2007,27(6):86-88

目前我国化肥当季利用率中，氮约为30％～35％．磷为10％～25％，钾为35％～50％远低于世界发达国家水平，造成肥料利用率低的主要原因是淋溶损失，尤以氮肥、钾肥为最。人们正在努力寻求提高肥料利用率的方法，其中之一是对肥料本身进行改性，开发适合于作物生长需求的新型肥料。研制缓／控释肥料是世界各国普遍采用的有效措施之一。缓释肥料的优点是利用率高，养分损失少，环境友好。但是，目前所用的作为缓释材料的高分子聚合物一般是难降解或不能降解，长期施用也会引起土壤污染。牡蛎壳为一种新型的天然材料，  相似文献   

Climate policy innovation in the South – Domestic and international determinants of renewable energy policies in developing and emerging countries     

《Global Environmental Change》2014

This article attempts to disentangle the determinants of the adoption of renewable energy support policies in developing and emerging countries. By analyzing policies already implemented in industrialized countries, we focus on the diffusion but not the invention of climate-relevant policies. We look at four different types of policies (renewable energy targets, feed-in tariffs, other financial incentives and framework policies) and consider both domestic factors and international diffusion mechanisms utilizing a discrete-time events history model with a logit link on a self-compiled dataset of grid-based electricity policy adoption in 112 developing and emerging countries from 1998 to 2009. In general, we find stronger support for the domestic determinants of policy adoption, but also substantial influence of international factors. Countries with a larger population and more wealth have a higher probability of adopting renewable energy policies. Only in some specific cases do natural endowments for producing renewable energy encourage governments to adopt policies, and hydro power resources even correlate negatively with the adoption of targets. Among the international determinants, emulation from colonial peers and membership within the EU seem to facilitate policy adoption. International climate finance is less relevant, as the Global Environmental Facility and the Clean Development Mechanism may only increase the adoption of frameworks and targets, but they have no influence on tariffs and incentives.  相似文献   

Does smallholder maize intensification reduce deforestation? Evidence from Zambia     

《Global Environmental Change》2020

Increasing food production to meet growing demand while reducing tropical deforestation is a critical sustainability challenge. This is especially true in sub-Saharan Africa, which faces serious food insecurity issues and where smallholder farming is the main driver of forest conversion. Competing theories imply opposite predictions as to whether deforestation increases or decreases with smallholder agricultural intensification, which can improve food security by increasing crop yields per area cultivated. This research provides new empirical evidence on the association between deforestation and smallholders’ use of modern inputs, in particular inorganic fertilizer on maize and improved maize seeds, using Zambia as a case study. We analyze this association nationwide in a spatially disaggregated manner at the lowest administrative level using machine learning-based small area estimation, which makes use of detailed nationally representative surveys on smallholder farm households for 2011 and 2014, and census data to statistically predict modern inputs use country-wide for 2011, when average maize yields were 1.28 tons/ha. Then, we evaluate the association between improved maize seed and fertilizer inputs and subsequent deforestation, while controlling for key geospatial covariates. The results support the land-sparing hypothesis, finding that smallholder farmers’ use of improved maize seed is negatively associated with deforestation on non-acidic (pH ≥ 5.5) soils, an effect that is enhanced by complementary inorganic fertilizer use. Fertilizer use on its own, however, is weakly associated with increased deforestation. Sustainable intensification via use of improved seeds on adequately fertile soils and improving soil health appears compatible with reducing both deforestation and food insecurity.  相似文献   

Tenders: an option for developing countries to support renewable energies under the CDM     

Sven Bode 《Climate Policy》2013,13(2):221-228

Abstract

Renewable energy sources are generally considered as an important tool on the way towards sustainable development. However, if developing countries want to actively promote renewable energies, they may need to face the problem that current legislation conflicts with the clean development mechanism (CDM) rules, and especially with the additionality concept. Thus, CDM projects may become impossible to implement. This article presents an approach to overcoming these potential difficulties. One solution lies in offering a tender specifically for RE-CDM-projects.  相似文献