On Rhythmical Layering of Rocks Formed from Basaltic Magma     

A. B. Vistelius  V. M. Pavlov 《Mathematical Geology》2003,35(4):399-404

Formation of rhythmical layering in intrusive basic and ultrabasic rock bodies is explained in different ways, in particular, by the movement of microparticles (mineral clusters) of plagioclase and pyroxene within the basalt melt under the influence of thermal and gravitational forces. A model of cluster movement is proposed as a consequence of the forces appearing when ultrasonic elastic fluctuations pass through the melt. The model is based on fundamental dynamic equations. Depending on cluster density, wave parameters, and magmatic chamber size, in the melt there can form different combinations of rhythmically alternating layers of different composition.  相似文献   

声波测试中振子衰减的线列阵模型     

易南概  赵俭斌 《地震工程与工程振动》2003,23(2):81-84

从声波在岩体中传播产生衰减的基本原理出发，建立了声波衰减振子的线列阵模型。该模型是将传播声波路径的岩体分为若干个振子，从波动概念出发，以振动原理作依据建立波动方程．为探讨岩体声波衰减机制提供了一种新的研究方法，把振动和波动直观地联系起来．单一方向上有限点的声波测试技术有可能被多方向的声测技术所代替．该模型的建立，使模态分析和参数识别方法应用到岩体声波测试技术中成为可能。  相似文献   

Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994     

TH. Blumenstock  H. Fisher  A. Friedle  F. Hase  P. Thomas 《Journal of Atmospheric Chemistry》1997,26(3):311-321

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.  相似文献   

The glacilacustrine sedimentary environment of Bowser Lake in the northern Coast Mountains of British Columbia, Canada     

Robert Gilbert  Joseph R. Desloges  John J. Clague 《Journal of Paleolimnology》1997,17(3):331-346

Bowser Lake, a fiord lake in the northern Coast Mountains of British Columbia, contains a thick Holocene fill consisting mainly of silt and clay varves. These sediments were carried into the lake by proglacial Bowser River which drains a high-energy, heavily glacierized basin. Sedimentation in the lake is controlled by seasonal snow and ice melt, by autumn rainstorms, and by rare, but very large jökulhlaups from glacier-dammed lakes in the upper Bowser River basin which complicate environmental inferences from the sedimentary record. Sediment is dispersed through the deep western part of the lake by energetic turbidity currents. The turbidity currents apparently do not overtop a sill that separates the western basin from much shallower areas to the east. Large amounts of silt and clay are deposited from suspension in the eastern part of the lake, but sediment accumulation rates there are much lower than to the west. Several strong acoustic reflectors punctuate the varved fill in the western basin; these may be thick or relatively coarse beds deposited during jökulhlaups or exceptionally large storms. The contemporary sediment yield to Bowser Lake, estimated from sediments in the lake, is about 360 t km^-2a^-1. This is a relatively high value, but it is less than yields insome other, similar montane basins with extensive snow and ice cover.The most likely explanation for the difference is that large amounts of sediment have been, and continue to be, stored on the Bowser delta andin small proglacial lakes.  相似文献   

The S reflector west of Galicia: the seismic signature of a detachment fault     

T. J. Reston 《Geophysical Journal International》1996,127(1):230-244

The so-called S reflector is a group of bright, continuous reflections underlying the landward-tilted fault blocks of the west Galicia rifted margin, S has been interpreted as the brittle-ductile transition, the lop of an intrusion, a detachment fault, and the crust-mantle boundary. To constrain the internal structure of the reflector, we have carried out detailed analyses of these reflections. We compare the waveforms of the seafloor reflection and its first multiple, both to determine the amplitude of the seafloor reflection and to show (hat the seafloor is in effect a spike in the reflectivity series so that the seafloor reflection can be used as the far-field wavelet, including both source and receiver ghosts. We compare (he waveform of the seafloor and 5 and show that, within the resolution of our data, S is a reflection from a step increase in acoustic impedance. This result is confirmed through complex trace analysis, and in particular the determination of the apparent polarity of S, and the examination of the instantaneous frequency function: S is consistently positive polarity, and shows no significant frequency anomaly. Simple modelling shows that S is very unlikely to be a reflection from a thin layer. We thus conclude that S is probably a single steplike interface. From the varying frequency content of the data, we determine a value for the effective Q between S and the seafloor, and use this to assess the amplitude loss due to attenuation and scattering. We use a comparison between the seafloor and the S reflection to constrain the amplitude of S, and estimate a reflection coefficient for S of at least 0.2 in places, decreasing landwards. By analogy with structures developed in the highly extended regions of the western United States, we consider that the most likely interpretation of S is as a sharp west-dipping detachment fault separating a 'granitic' upper plate from a higher-velocity lower plate, locally probably serpentinized mantle.  相似文献   

碱性玄武岩中的某些巨晶单斜辉石──Ⅱ:穆斯堡尔谱──兼论单斜辉石的异常穆斯堡尔谱和铁结构态的测定     

章礼明  傅平秋  张恩林 《矿物学报》1996,(1)

本文对辽宁宽甸碱性玄武岩中巨晶单斜辉石进行穆斯堡尔谱研究。应用晶体结构研究结果较合理地解释了单斜辉石的异常穆斯堡尔谱。结合XRD讨论了单斜辉石中Fe结构态的测定以及穆斯堡尔谱的可应用性。巨晶应结晶于相当氧化的环境。  相似文献   

伊利石层间钾释放的远红外光谱研究   总被引：1，自引：0，他引：1  

刘耘 《矿物学报》1996,16(4):340-348

本文介绍了新近研究层间交换的远红外方法，并用该方法研究了金砂伊早石层间交换的性质，随着温度的升高，伊利石的远红外谱段从１０８ｃｍ＾－１向低波数方向偏移，３００Ｃ时为１０７ｃｍ＾－１，５００℃时为１０００ｃｍ＾－１，７００℃时为９８ｃｍ＾－１，同时，伊利石的释钾程度也伴随着增加，远红外谱同释放钾的能力有一清楚对比，因此可以用远红外方法预言伊利石释钾的能力，最后，利用量子化学计算的ＰＭ３方法首次从理论  相似文献   

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

Iron oxidation state in lower mantle mineral assemblages: II. Inclusions in diamonds from Kankan, Guinea     

C.A McCammon  T Stachel 《Earth and Planetary Science Letters》2004,222(2):423-434

Inclusions of ferropericlase and former (Mg,Fe)(Si,Al)O₃ perovskite in diamonds from Kankan, Guinea believed to originate in the lower mantle were studied using Mössbauer spectroscopy to determine Fe³⁺/ΣFe. Fe³⁺ concentration in the (Mg,Fe)(Si,Al)O₃ inclusion is consistent with empirical relations relating Fe³⁺/ΣFe to Al concentration, supporting the inference that it crystallised in the perovskite structure at lower mantle conditions. In ferropericlase there is a nearly linear variation of trivalent cation abundance with monovalent cation abundance, suggesting a substitution of the form Na_0.5M_0.5³⁺O (M=Fe³⁺, Cr³⁺, Al³⁺). Excess positive charge is likely balanced by cation vacancies, where their abundance is observed to increase with increasing iron concentration, consistent with high-pressure experiments. The abundance of cation vacancies is related to oxygen fugacity, where ferropericlase inclusions from Kankan and São Luiz (Brazil) are inferred to have formed at conditions more oxidising than Fe-(Mg,Fe)O equilibrium, but more reducing than Re-ReO₂ equilibrium. Fe²⁺/Mg partition coefficients between (Mg,Fe)(Si,Al)O₃ and ferropericlase were calculated for inclusions co-existing in the same diamond using Mössbauer data and empirical relations based on high-pressure experimental work. Most values are consistent with high-pressure experiments, suggesting that these inclusions equilibrated at lower mantle conditions. The measured ferropericlase Fe³⁺ concentrations are consistent with diamond formation in a region of redox gradients, possibly arising from the subduction of oxidised material into reduced lower mantle. Reduction of carbonate to form ferropericlase and diamond is consistent with a slight shift of Kankan δ¹³C values to isotopically heavy compositions compared to the worldwide dataset, and could supply the oxygen necessary to satisfy the high Fe³⁺ concentration in (Mg,Fe)(Si,Al)O₃ perovskite, as well as account for the high proportion of ferropericlase in the lower mantle paragenesis. The heterogeneity of lower mantle diamond sources indicates that the composition of lower mantle diamonds do not necessarily reflect those of the bulk mantle.  相似文献   

近红外反射光谱学在岩石矿物研究中的应用Ⅱ.快速测定地质样品中有机质     

龙梅  裴世桥 《岩矿测试》2004,23(1):6-10

利用偏最小二乘法回归的多变量校正方式,建立了应用近红外反射光谱学方法无损快速测定各种地质样品中有机质的模型.设计了多重散射光校正、标准正常变量转换及导数光谱,扣除额外基线和重叠信号的影响,分离出与有机质含量有关的光谱信息.大多数地质样品的有机质近红外反射光谱估算结果与化学法符合.  相似文献