东天山中天山构造带喀拉塔格地区早石炭世岛弧火山岩的厘定及其构造意义   总被引：1，自引：0，他引：1  

毛启贵  王京彬  肖文交  方同辉  王宁  余明杰 《地质学报》2014,88(10):1790-1799

本研究以东天山中天山中段喀拉塔格地区的火山岩为研究对象,前人通过区域对比将其时代定为前寒武纪,本文通过锆石SIMS U-Pb定年获得其成岩年龄为347.5±5.9 Ma,同时还发现了一些前寒武纪捕获锆石,显示中天山存在老基底。地球化学研究显示这套火山岩具有相对较低TiO2(0.85%~1.21%)含量,高Mg#(46~64);富集大离子亲石元素(LILE:Rb、Ba、Th、U)、LREE和Pb元素,亏损髙场强元素(HFSE:Nb、Ta、Ti)特征;具明显Eu负异常;具相对较低εNd(t)值(-4.4~-5.7)和高初始Sr比值[(87Sr/86Sr)i=0.70884~0.70920];具有相对高的Th和Pb含量,较低的Ce/Th、Ce/Pb和Ba/Th比值,具俯冲带岛弧钙碱性岩浆特征;同时样品具较低Nb/U和Ce/Pb值,且发育捕获锆石,显示存在陆壳混染作用。这一工作在中天山前寒武地层中分解出古生代岛弧火山岩,综合的区域地质资料分析显示中天山岛弧带在早石炭世时期是类似于现在日本岛弧的岛弧带。  相似文献   

Strategies towards robust interpretations of in situ zircon oxygen isotopes     

《地学前缘(英文版)》2023,14(2):101523

Oxygen isotopes are a versatile tool to address a wide range of questions in the Earth sciences. Applications include geothermometry, paleoclimatology, tracing of geochemical reservoirs, fluid-rock interaction, magmatic petrogenesis, and identification of extra-terrestrial materials. Zircon arguably provides one of the most robust records of primary magmatic O isotope ratio due to low diffusion rates in crystalline grains. The ability to correlate zircon O isotopes with temporal and petrogenetic information (e.g. U-Pb geochronology, Lu-Hf isotopes, and trace elements) makes this mineral a key archive for understanding Earth’s crustal evolution. Consequently, zircon O isotope geochemistry has found widespread usage to address fundamental questions across the earth and planetary sciences. The general apparent ease of O isotopic acquisition through the advancement of rapid in situ techniques (i.e. secondary ion mass spectrometry; SIMS) and associated dedicated national laboratories has led to the generation of large O isotopic data sets of variable quality, highlighting the importance of a coherent workflow for data collection, reduction, and presentation. This paper presents a set of approaches for measurement, assessment, and reporting of zircon O isotope data. The focus in this contribution is on in situ analysis via secondary ion mass spectrometry using large geometry instruments, but other commonly used techniques are briefly reviewed for context. This work aims to provide an analytical framework necessary for geologically meaningful interpretation of O isotope data. In addition, we describe inherent geological (e.g. radiation-induced disturbance of the zircon O isotopic system) and analytical (e.g. fractionation due to sample topography effects) challenges and outline means to identify and avoid such issues as a prerequisite to the generation of robust primary O isotopic signatures for geological interpretation.  相似文献   

Ion Implants as Matrix‐Appropriate Calibrators for Geochemical Ion Probe Analyses          下载免费PDF全文

Donald S. Burnett  Amy J.G. Jurewicz  Dorothy S. Woolum  Jianhua Wang  Julie M. Paque  Larry R. Nittler  Kevin D. McKeegan  Munir Humayun  Richard Hervig  Veronika S. Heber  Yunbin Guan 《Geostandards and Geoanalytical Research》2015,39(3):265-276

Ion microprobe elemental and isotopic determinations can be precise but difficult to quantify. Error is introduced when the reference material and the sample to be analysed have different compositions. Mitigation of such ‘matrix effects’ is possible using ion implants. If a compositionally homogeneous reference material is available which is ‘matrix‐appropriate’ (i.e., close in major element composition to the sample to be analysed, but having an unknown concentration of the element, E, to be determined) then ion implantation can be used to introduce a known amount of an E isotope, calibrating the E concentration and producing a matrix‐appropriate calibrator. Nominal implant fluences (ions cm^?2) are inaccurate by amounts up to approximately 30%. However, ion implantation gives uniform fluences over large areas; thus, it is possible to ‘co‐implant’ an additional reference material of any bulk composition having known amounts of E, independently calibrating the implant fluence. Isotope ratio measurement standards can be produced by implanting two different isotopes, but permil level precision requires postimplant calibration of the implant isotopic ratio. Examples discussed include (a) standardising Li in melilite; (b) calibrating a ²⁵Mg implant fluence using NIST SRM 617 glass and (c) using Si co‐implanted with ²⁵Mg alongside NIST SRM 617 to produce a calibrated measurement of Mg in Si.  相似文献   

内蒙古鸡冠山钼矿流纹斑岩的成岩年龄及地质意义   总被引：1，自引：0，他引：1  

陈伟军 《地质与勘探》2015,51(6):1107-1113

内蒙古鸡冠山钼矿床是近年来发现的一个大型斑岩型钼矿床,位于华北克拉通北缘、西拉沐沦钼矿带的中段,产出于一破火山机构的NW侧。矿床矿石矿物辉钼矿Re-Os同位素等时线法测得成矿年龄为151.1±1.3Ma,为晚侏罗世成矿。本文通过SIMS锆石U-Pb年龄法,测定流纹斑岩成岩年龄为148.5±3.3Ma(U-Pb等时线年龄,2σ,MSWD=2.2),为晚侏罗世成岩。该成岩年龄与成矿年龄在误差范围内一致,说明与流纹斑岩有关的岩浆活动可能形成成矿的母岩浆,成岩与成矿近乎同时发生。  相似文献   

Timing of high-pressure metamorphism and exhumation of the eclogite type-locality (Kupplerbrunn–Prickler Halt, Saualpe, south-eastern Austria): constraints from correlations of the Sm–Nd, Lu–Hf, U–Pb and Rb–Sr isotopic systems     

M. THÖNI  C. MILLER  J. BLICHERT-TOFT  M. J. WHITEHOUSE  J. KONZETT  A. ZANETTI 《Journal of Metamorphic Geology》2008,26(5):561-581

Sm–Nd, Lu–Hf, Rb–Sr and SIMS U–Pb data are presented for meta‐gabbroic eclogites from the eclogite type‐locality ( Haüy, 1822 ) Kupplerbrunn–Prickler Halt and other areas of the Saualpe (SE Austria) and Pohorje Mountains (Slovenia). Mg‐rich eclogites derived from early gabbroic cumulates are kyanite‐ and zoisite rich, whereas eclogites with lower Mg contents contain clinozoisite ± kyanite. Calculated P–T conditions at the final stages of high‐pressure metamorphism are 2.2 ± 0.2 GPa at 630–740 °C. Kyanite‐rich eclogites did not yield geologically meaningful Sm–Nd ages due to incomplete Nd isotope equilibration, whereas Sm–Nd multifraction garnet–omphacite regression for a low‐Mg eclogite from Kupplerbrunn yields an age of 91.1 ± 1.3 Ma. The Sm–Nd age of 94.1 ± 0.8 Ma obtained from the Fe‐rich core fraction of this garnet dates the initial stages of garnet growth. Zircon that also crystallized at eclogite facies conditions gives a weighted mean U–Pb SIMS age of 88.4 ± 8.1 Ma. Lu–Hf isotope analysis of a kyanite–eclogite from Kupplerbrunn yields 88.4 ± 4.7 Ma for the garnet–omphacite pair. Two low‐Mg eclogites from the Gertrusk locality of the Saualpe yield a multimineral Sm–Nd age of 90.6 ± 1.0 Ma. A low‐Mg eclogite from the Pohorje Mountains (70 km to the SE) gives a garnet–whole‐rock Lu–Hf age of 93.3 ± 2.8 Ma. These new age data and published Sm–Nd ages of metasedimentary host rocks constrain the final stages of the eo‐Alpine high‐pressure event in the Saualpe–Pohorje part of the south‐easternmost Austroalpine nappe system suggesting that garnet growth in the high‐pressure assemblages started at c. 95–94 Ma and ceased at c. 90–88 Ma, probably at the final pressure peak. Zircon and amphibole crystallization was still possible during incipient isothermal decompression. Rapid exhumation of the high‐pressure rocks was induced by collision of the northern Apulian plate with parts of the Austroalpine microplate, following Jurassic closure of the Permo‐Triassic Meliata back‐arc basin.  相似文献   

Geochronology and Ore‐Forming Fluids of the Baizhangyan W–Mo Deposit in the Chizhou Area,Middle‐Lower Yangtze Valley,SE‐China     

Guoxue Song  Kezhang Qin  Guangming Li  Xianhua Li  Wenjun Qu 《Resource Geology》2013,63(1):57-71

The Baizhangyan skarn‐porphyry type W–Mo deposit is located in a newly defined Mo–W–Pb–Zn metallogenic belt, which is in the south of Middle‐Lower Yangtze Valley Cu–Fe–Au polymetallic metallogenic belt in SE China. The W–Mo orebodies occur mainly within the contact zone between fine‐grained granite and Sinian limestone strata. There are two types of W–Mo mineralization: major skarn W–Mo mineralization and minor granite‐hosted disseminated Mo mineralization which was traced by drilling at depth. Eight molybdenite samples from Mo‐bearing ores yield Re–Os dates that overlap within analytical error, with a weighted average age of 134.1 ± 2.2 Ma. These dates are in close agreement with SIMS U–Pb concordant zircon age for fine‐grained granite at 133.3 ± 1.3 Ma, indicating that crystallization of the granite and hydrothermal molybdenite formation were coeval and likely cogenetic. The Baizhangyan W–Mo deposit formed in the Early Cretaceous extensional tectonic setting at the Middle‐Lower Yangtze Valley metallogenic belt and the Jaingnan Ancient Continent. Based on mineral compositions and crosscutting relationships of veinlets, hydrothermal alteration and mineralization, the ore mineral paragenesis of the Baizhangyan deposit is divided into four stages: skarn stage (I), oxide stage (II), sulfide stage (III), and carbonate stage (IV). Fluid inclusions in garnet, scheelite, quartz and calcite from W–Mo ores are mainly aqueous‐rich (L + V) type inclusions. Following garnet deposition at stage I, the high‐temperature fluids gave way to progressively cooler, more dilute fluids associated with tungsten–molybdenite–base metal sulfide deposition (stage II and stage III) (162–360°C, 2.7–13.2 wt % NaCl equivalent) and carbonate deposition (stage IV) (137–190°C, 0.9–5 wt % NaCl equiv.). Hydrogen‐oxygen isotope data from minerals of different stages suggest that the ore‐forming fluids consisted of magmatic water, mixed in various proportions with meteoric water. From stage I to stage IV, there is a systematic decrease in the homogenization temperature of the fluid‐inclusion fluids and calculated δ¹⁸O values of the fluids. These suggest that increasing involvement of formation water or meteoric water during the fluid ascent resulted in successive deposition of scheelite and molybdenite at Baizhangyan.  相似文献   

二次离子质谱微区原位牙形石氧同位素分析及其在古海表水温记录中的应用     

王润  陈剑波  赵来时  陈泳霖  唐国强  李献华 《世界地质》2013,32(4):652-658

利用生物成因磷灰石的氧同位素信息能够重建古海水温度,尤其是牙形石,结合其在生物地层学上的研究,它的数据解释具有明确的古环境意义。牙形石微小的个体一直是其精确地球化学分析的限制因素。作为对牙形石微区原位氧同位素测试方法的探索研究,本文利用Cameca IMS--1280 型二次离子质谱仪对牙形石进行了微区原位氧同位素组成测试,通过分析得到可靠的古表层海水温度 ( SST) 记录,表明从晚二叠世到早三叠世SST 存在明显的上升过程。相比常规Ag3PO4 实验方法,牙形石微区原位氧同位素分析方法更加快速,而且能够有效避免牙形石易受到污染的部位,获得更为可靠的牙形石氧同位素组成的测定结果。  相似文献   

云南个旧西区贾沙辉长-二长岩体SIMS锆石U-Pb定年及地球化学研究   总被引：2，自引：0，他引：2  

张颖  黄智龙  罗泰义  钱志宽  张嘉玮  孙建博 《地球化学》2013,(6):523-543

为确定云南省个旧地区晚中生代大规模岩浆活动过程中基性端元的时限、地幔源区特点及大地构造环境,选取贾沙辉长．二长岩体为对象进行年代学和地球化学研究。贾沙辉长．二长岩体位于个旧西区,岩性主要为辉长岩和二长岩。锆石U．Pb同位素测年结果表明,岩石侵位时代为（84．0＋0．6）Ma,属于晚白垩世,与个旧地区花岗岩、碱性岩和煌斑岩形成年代范围一致（76～85Ma）。贾沙岩体的辉长岩和二长岩Si02为47．3％～60．O％,K20＋Na20为7．31％～10．1％。稀土含量较高,轻稀土富集重稀土亏损,Eu异常不明显。相对于原始地幔,贾沙岩体富集轻稀土和大离子亲石元素Rb、K、Pb,亏损高场强元素Nb、Ta、Ti和P。地球化学研究显示贾沙岩体母岩浆起源于与俯冲有关的交代地幔,由石榴子石二辉橄榄岩经历了较低程度的（〈5％）部分熔融形成。原始岩浆在就位过程中经历了广泛的地壳混染和橄榄石、辉石的分离结晶作用。二长岩由辉长岩浆结晶分异作用形成。研究显示,贾沙辉长．二长岩体是晚白垩世滇东南．桂西地区大规模岩浆活动的产物,表明这些岩浆岩形成于统一的岩石圈伸展的动力学背景下。  相似文献   

Early Carboniferous intra-oceanic arc and back-arc basin system in the West Junggar,NW China     

《International Geology Review》2012,54(16):1991-2007

A series of Lower Carboniferous volcanic rocks occur in the Hatu, Darbut, and Baogutu areas of Xinjiang Province. Secondary ion mass spectrometry (SIMS) zircon U–Pb isotopic data indicate that two samples of these rocks coevally erupted at 324.0 ± 2.8 Ma and 324.9 ± 3.4 Ma. Three detailed profile measurements show that the volcanics include the Hatu basalt, the Baogutu andesite and dacite, and the Darbut andesite. Whole-rock compositions suggest that the Hatu volcanics are tholeiites and have a mid-ocean ridge basalt (MORB)-like signature with a small negative Nb anomaly, suggesting formation in a back-arc basin. Their isotopic compositions (?Nd(t) = +2.2 to +4.0, (⁸⁷Sr/⁸⁶Sr)i = 0.70414 to 0.70517) suggest a mixing origin from depleted to enriched mantle sources. In contrast, the Baogutu and Darbut rocks are andesite and dacite possessing a transitional tholeiite to calc–alkaline character and have E-MORB-like and OIB signatures, with a marked negative Nb anomaly and Th/Yb-enrichment, indicating that they were generated in a subduction zone setting. Isotopically, they display consistently depleted Sr–Nd isotopic compositions [(⁸⁷Sr/⁸⁶Sr)i = 0.70377–0.70469, ?Nd(t) = 1.0–5.2], suggesting that they were derived from a depleted mantle, and that fluid and sediments were involved in their petrogenesis. These features suggest that an early Carboniferous intra-oceanic arc and back-arc basin system generated the studied volcanic units in the West Junggar.  相似文献   

新疆香山杂岩体的成岩与成矿时序   总被引：6，自引：2，他引：4  

李德东  王玉往  王京彬  王莉娟  龙灵利  廖震 《岩石学报》2012,28(7):2103-2112

新疆东天山香山地区镁铁-超镁铁杂岩体中产有香山中中型铜镍矿和香山西大型铜镍-钛铁矿床.杂岩体可分为辉长岩类、超镁铁质岩类和钛铁辉长岩类.野外证据表明三者具有先后侵位关系.本文通过对香山杂岩体不同岩相年代学资料梳理,补充了定年数据,获得香山杂岩体侵位年龄为283.2±2.1Ma,验证了不同岩石系列的侵位时序.此外,锆石年龄数据还记录了本地区曾经发生过的构造-岩浆热事件.利用角闪石40Ar/39Ar测年结果,并结合锆石U-Pb测年结果推测香山西岩体侵位较深,香山中岩体侵位较浅,进一步推测西岩体剥蚀量较大,而中岩体剥蚀量较小.结合野外穿插关系,厘定了杂岩体侵入-成矿事件的时序.  相似文献