地壳浅部导电性矿物的一种新的压溶机制：应力原电池过程   总被引：3，自引：0，他引：3  

李和平 《矿物学报》1998,18(1):80-83

以黄铁矿为例,通过导电性矿物的力学-电化学相互作用实验,得出：导电性矿物的电极电位与弹性轴压应力是较好的负线性相关关系。以此为基础,通过电化学理论分析,得出：地壳浅部与溶液接触的导电性矿物颗粒内部存在各种各样的应力原电池,通过应力原电池过程,压溶作用得以实现。导电性矿物应力原电池引起压涛作用的发现,无疑对诸如构造地球化学、地电化学甚至湿法冶金等领域的有关研究具有重要意义。  相似文献   

Oxygen isotope fractionation in mantle minerals     

Yongfei Zheng  Chunsheng Wei  Gentao Zhou  Baolong Xu 《中国科学D辑(英文版)》1998,41(1):95-103

The increment method is adopted to calculate oxygen isotope fractionation factors for mantle minerals, particularly for the polymorphic phases of MgSiO₃ and Mg₂SiO₄. The results predict the following sequence of¹⁸O-enrichment:pyroxene (Mg, Fe, Ca)₂Si₂O₆>olivine (Mg, Fe)₂SiO₄ > spinel (Mg, Fe)₂SiO₄> ilmenite (Mg, Fe, Ca) SiO₃>perovskite (Mg, Fe, Ca) SiO₃. The calculated fractionations for the calcite-perovskite (CaTiO₃) System are in excellent agreement with the experimental calibrations. If there would be complete isotopic equilibration in the mantle, the spinel-structured silicates in the transition zone are predicted to be enriched in¹⁸O relative to the perovskite-structured silicates in the lower mantle but depleted in¹⁸O relative to olivines and pyroxenes in the upper mantle. The oxygen isotope layering of the mantle might result from differences in the chemical composition and crystal structure of mineral phases at different mantle depths. Assuming isotopic equilibrium on a whole earth scale, the chemical structure of the Earth’s interior can be described by the following sequence of¹⁸O-enrichment:upper crust>lower crust>upper mantle>transition zone>lower mantle>core. Project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences.  相似文献   

浅论马鞍山地区的膨胀土     

简河清 《世界地质》1998,17(3):83-85

膨胀土由于粘土矿物含量较多,在一定气候条件下其体积随含水量的增加而膨胀,随含水一的减少而收缩,以膨胀土为地基的低层建筑物常常成群开裂,笔者首次报道了马鞍山地区的膨胀土,并对该区膨胀土的分布,成因,评价方法和防治措施等提出了初步看法。  相似文献   

河流泥沙输移过程中矿物风化的碳汇效应初探——以长江干流为例     

张信宝  罗景城  王小国  唐家良  彭韬  朱波 《地质学报》2023,97(7):2378-2385

本文首先提出了河流泥沙输移过程中泥沙中的钙镁矿物溶蚀消耗水体中的CO2并具有碳汇功能的观点。基于前人长江干流从源头到入海口和支流2003~2007年期间4次河流悬移质泥沙的化学元素组成和矿物组成资料,分析悬移质中CaO、MgO含量和方解石、白云石含量变化特征,定量计算了这些取样点悬移质泥沙的CO2总碳汇能力和非永久性、永久性碳汇能力,分析了不同碳汇能力沿程变化规律及其原因。碳汇计算结果表明：寸滩—大通河段1956~2000年期间泥沙输移过程中钙镁矿物溶蚀产生的总碳汇量、非永久性和永久性碳汇量分别为2572万t/a、1700万t/a和872万t/a。由于输沙量减少,寸滩站—大通站河段的总碳汇量、非永久性和永久性碳汇量2006~2019年期间较1956~2000年期间相应分别减少了1852万t、1224万t和872万t。三峡水库年均淤积量1. 145亿t,损失总碳汇量675. 6万t,相当于三峡电站减排二氧化碳8580万t的7. 9%。全球河流入海年输沙量126. 1亿t,以寸滩- 吴淞口河段碳汇功能0. 060 t/t计,总碳汇量7. 57亿t相当于全球岩石风化碳汇总量10. 56亿t CO2的71. 6%。河流泥沙输移过程中钙镁矿物溶蚀的碳汇量具有重要的作用,其溶蚀速率大于原地风化。  相似文献   

现代河流沉积物碎屑及矿物组分研究新进展     

梁文栋  胡修棉 《地质学报》2023,97(9):2975-2991

现代河流沉积物忠实地记录了流域盆地内的母岩、风化、搬运和沉积过程中的化学、物理过程以及人类活动的改造作用,是探索和验证源- 汇系统等理论的重要媒介。本文以全球现代河流砂组分数据库为基础,总结了碎屑组分、重矿物组分在不同大陆的分布特征,探讨了其在物源识别、源区贡献率计算、沉积物产生及搬运过程中气候- 构造等影响因素的评估、对源- 汇系统的研究启示等方面的应用。今后建议加强基于大数据的沉积物组分对气候- 构造- 人类活动的响应、沉积物产生及通量、高时间分辨率的沉积物组分变异性、不同物源定量化方法的差异等方面的研究。  相似文献   

末次盛冰期末期以来南海北部陆坡的陆源物质输入及其控制因素     

黄杰  李安春  万世明  徐方建  孟庆勇 《海洋与湖沼》2013,44(4):882-889

通过对南海北部陆坡KNG5孔沉积物粒度、粘土矿物和14C年龄的综合分析, 探讨了南海北部陆坡的沉积物来源及其控制因素。物源分析表明, KNG5孔17.5-12.5ka BP的沉积物主要来源于珠江, 12.5ka BP 时粘土矿物组合突然发生改变, 并且自12.5ka BP以后, 高岭石含量总体稳定, 说明12.5ka BP时海平面已上升到相当的高度, 并且可能当时南海的现代环流系统已开始形成, 西行的广东沿岸流导致向外扩散的珠江物质减少, 由于受北太平洋深层水(NPDW)和黑潮(KC)南海分支的作用, 台湾成为此时沉积物的主要贡献者。KNG5孔17.5-11ka BP时期的粘土矿物和粒度变化主要受控于海平面和洋流系统的变化。全新世早期(11.0-8ka BP)平均粒径达到最细和1-2.2m 粒级含量达到最高值可能是强盛的夏季风作用的结果。全新世中晚期(8—0ka BP) 1-2.2?m组分含量的减少是8ka BP以来东亚夏季风减弱的具体体现, 1-2.2m 粒级含量指示的东亚夏季风变化能和北半球其它季风指标能很好地对应起来, 说明这次季风减弱是北半球各个季风系统的共同现象。  相似文献   

包气带土壤组成对三氯乙烯的吸附影响研究   总被引：1，自引：0，他引：1  

张晶  何江涛  曲雪妍  张坤峰  韩璐 《岩石矿物学杂志》2010,29(4):439-444

有机质和矿物质是包气带土壤中的主要吸附介质,其吸附特性直接影响有机污染物在环境中的迁移、转化等过程。分别采用分析纯石英砂和典型粘土矿物高岭石模拟土壤的原生矿物和粘土矿物,利用批实验的方法研究土壤中各组成部分对三氯乙烯(TCE)的吸附行为。土壤有机质的吸附行为通过全土样和矿物质的对比得出。结果表明,粘土矿物是吸附氯代烃的主要矿物质,原生矿物对氯代烃的吸附量很小;土壤有机质含量和土壤吸附量之间有很好的正相关性;土壤有机碳含量与土壤粘土矿物含量的比值是影响吸附行为的另一重要因素,比值越小,Koc值越大,土壤对TCE的亲和力就越强。由于自然界中的土壤有机质大都与矿物质形成有机质-粘土矿物结合体,据此推测有机质-矿物质结合体会影响有机质的组成和形态,从而对其吸附行为有重要作用。  相似文献   

Provenance of freshwater pulses in the Gulf of Mexico during the last deglaciation     

T. Sionneau  V. Bout-Roumazeilles  N. Tribovillard 《Quaternary Research》2010,74(2):235-245

During the last deglaciation, the decaying Laurentide Ice Sheet (LIS) delivered huge volumes of meltwater toward the Gulf of Mexico. The present investigation of clay mineralogy and grain-size characteristics of terrigenous sediments deposited in the Orca Basin (Gulf of Mexico) offers a unique opportunity to link the marine record of these meltwater floods with the reconstructed continental glacial history and the modeled drainage patterns. Five peculiar sedimentary levels, characterized by high smectite content and low CaCO₃ content, were identified and occurred simultaneously with major meltwater floods. According to recently published clay mineral distribution maps for North America, these results help to pinpoint the southwestern margin of the LIS as a main contributor to most of the meltwater discharges. In addition, the peculiar mineralogical composition (illite and chlorite-rich) of the sediments characterizing the meltwater episode associated with Heinrich event 1 suggests a provenance from the Great Lakes area, supporting the interpretation of destabilization of the LIS southeastern margin during this event. Decreased terrigenous contribution associated with changing provenance of sediments after 12.9 cal ka BP suggests strong modifications of the continental hydrography in relation to Lake Agassiz history and changes in the morphology of Mississippi delta due to rising sea level.  相似文献   

洞庭盆地两护村孔重矿物特征及其对第四纪构造活动与环境演变的响应   总被引：12，自引：1，他引：11  

柏道远  李长安  陈渡平  周柯军  马铁球  王先辉  彭云益  李纲 《地质论评》2010,56(2):246-260

第四纪洞庭盆地主体自西向东分为安乡凹陷、赤山隆起和沅江凹陷等3个次级构造单元。在安乡凹陷东南部两护村新施工揭穿第四系的ZKC1孔,其地层组成自下而上依次为早更新世华田组、汨罗组,中更新世早期—中期洞庭湖组,晚更新世坡头组以及全新统等。对钻孔岩芯进行了系统的重矿物分析,进而根据特征重矿物来源和含量变化,结合钻孔岩性和岩相变化以及区域地质和地理背景,探讨洞庭盆地南部早—中更新世沉积环境暨河湖变迁以及构造沉降过程。研究表明,洞庭盆地存在幕式断陷活动,早更新世早期、早更新世末期和中更新世中—后期等3个时期强烈断陷沉降,相对湖平面上升,来源于盆地南缘中段的资江河水部分向西注入安乡凹陷,导致ZKC1孔华田组下段下部、汨罗组顶部、洞庭湖组上段等相应层位中的锆石、金红石、锐钛矿和菱铁矿等(主要来源于资江流域)含量显著增高。其它时期断陷作用较弱,河湖水位低,沅水和资江分别沿其主水道于赤山隆起西侧和东侧向北汇入长江,导致ZKC1孔相应沉积层位中锆石、金红石、锐钛矿和菱铁矿的含量明显偏低。对重矿物特征指数变化与孢粉和化学蚀变指数所反映的气候变化的相关性研究,暗示上述3次相对湖平面上升的主要原因不是降水增加,而是构造沉降增强。  相似文献   

Ag-rich Tetrahedrite in the El Zancudo Deposit,Colombia: Occurrence,Chemical Compositions and Genetic Temperatures     

Alba Nury Gallego Hernández  Masahide Akasaka 《Resource Geology》2010,60(3):218-233

Chemical compositions of tetrahedrite—Ag-rich tetrahedrite—freibergite solid solutions (Ag-rich tetrahedrite_ss) and homogenization temperatures of fluid inclusions in quartz and carbonates of seventeen samples from nine veins in the El Zancudo deposit, Antioquia, Colombia, were investigated to reveal the origin of silver in Ag-rich tetrahedrite_ss, to derive their crystallization temperatures and to examine the relationship between chemical compositions of Ag-rich tetrahedrite_ss and their crystallization temperatures. The ores consist of arsenopyrite, pyrite, sphalerite, Ag-rich tetrahedrite_ss, galena, boulangerite, andorite, owyheeite, diaphorite, jamesonite, miargyrite, bournonite, chalcopyrite, and electrum. Ag-rich tetrahedrite_ss forms about 10 volume % of the total ores and is one of the most common and widely distributed sulfosalts in this deposit. Ag-rich tetrahedrite_ss is rich in Ag (1.13 to 31.02 wt%) and Sb (22.93 to 29.82 wt%), and poor in As (0.06 to 2.43 wt%), consistent with the reported incompatibilities of Ag and As in Ag-rich tetrahedrite_ss. The Zn/(Zn + Fe)-, Ag/(Ag + Cu)- and Sb/(Sb + As + Bi)-atomic ratios exhibit some variations among the veins. Ag-rich tetrahedrite_ss with higher Ag/(Ag + Cu) ratios coexist with diaphorite, whereas those with lower ratios are not associated with this sulfosalt. Ag-rich tetrahedrite_ss in the assemblages of Ag-rich tetrahedrite_ss+ sphalerite and of Ag-rich tetrahedrite_ss+ bournonite + galena shows no Zn ↔ Fe and Cu ↔ Ag variations between core and rim, respectively, negating the possibility of solid state reaction during cooling. Ag-rich tetrahedrite_ss is thus regarded as primary phase. Homogenization temperatures of primary fluid inclusions in quartz and carbonates co-existing with Ag-rich tetrahedrite_ss define the mineralization temperatures of 134 to 263°C. Independent crystallization temperatures of Ag-rich tetrahedrite estimated based on Zn/(Zn + Fe) and Ag/(Ag + Cu) ratios of the Ag-rich tetrahedrite_ss associated with silver minerals such as miargyrite, andorite and diaphorite using Sack's thermochemical database lie in a range between 170 and ∼250°C. Both results are thus in good agreement.  相似文献