An evaluation of metal bioaccessibility in estuarine sediments using the commercially available protein, bovine serum albumin   总被引：2，自引：0，他引：2  

Judit Kalman  Andrew Turner   《Marine Chemistry》2007,107(4):486-497

The bioaccessibility of metals (Al, Ca, Fe, Mn, Ag, Cd, Co, Cu, Ni, Pb, Sn, Zn) in oxic estuarine sediments has been evaluated using solutions of a commercially available protein (bovine serum albumin; BSA) that mimic the chemical conditions encountered in the gut environment of many deposit-feeding organisms. Over a 20 h incubation period with 5 g L^− 1 BSA, metal mobilisation was generally biphasic in that a relatively short period of rapid release was succeeded by more gradual release or approach to equilibrium, although in some cases metal readsorption was evident during the time-courses. Availability to BSA, defined as metal released after 20 h relative to metal extracted by boiling aqua regia, was greatest for Cd, Ni, Ca and Zn and lowest for Fe and Mn, and correlated well with, but was an order of magnitude lower than, metal digested by acidified hydrogen peroxide. Time-courses conducted in the absence of the protein revealed that significant quantities of Ca and Mn were water-soluble, reflecting the partial dissolution of carbonates and hydrous Mn oxides, respectively. Additional experiments indicated a net increase in metal release with increasing BSA concentration and, with the exception of Ca and Mn, a substantial increase in metal mobilisation after sediment organic matter had been digested by peroxidation. These observations suggest that, apart from Ca and Mn, metal release proceeds via complexation with component amino acids of the protein, denudation of organic host phases, and exposure of inorganic, metal-bearing minerals. Accordingly, the bioaccessibility of a metal is predicted to be dependent on its (i) affinity for proteinaceous ligands, (ii) association with components of digestible sediment organic matter, and (iii) degree of binding at relatively weak sites on sediment phases that are exposed or modified by the action of proteins and other chemical constituents of the gut environment.  相似文献   

廉州湾南部海域泥沙来源及运移趋势分析     

谷东起  吴桑云 《海洋科学进展》2001,19(1):25-31

重矿物组合、含量变化和特征矿物的分布及变化规律是沿海泥沙来源和运移趋势判断的重要手段之一。通过对廉州湾南部海域海底表层沉积物的重矿物分析 ,发现该区重矿物分布以北海地角为界 ,其百分含量和特征矿物南北有别 ,可能分别代表不同的物质来源区。其中廉州湾北部南流江流域来沙是该区主要物源 ,运移趋势为自 NE向 SW;地角西南岸段、岭南侧海岸侵蚀及银滩来沙也为该区提供了部分物源 ,运移趋势为绕过冠头岭沿海岸向 N方向运移。由于缺乏北海陆域陆相地层重矿物含量等相关资料 ,暂未做物质来源区的具体判断  相似文献   

东海黑潮热输送及其与黄淮平原区汛期降水的关系   总被引：22，自引：0，他引：22  

翁学传  张启龙  杨玉玲  颜廷壮 《海洋与湖沼》1996,27(3):237-245

根据日本气象厅1956—1990年PN（G）断面观测资料分析东海黑潮热输送的变异特征，并探讨其冬季热输送与黄淮平原区汛期（6－8月）降水的关系。结果表明，黑潮通过PN（G）断面多年平均的热输送达15．74×1014W，其中冬季热输送的年际和长期变化特别明显；冬季热输送年际变化的周期主要为对．23.4a、3.5a、和2.6a，长期变化总趋势是70年代末以前各年热输送距平均为负值，对年代末接近多年平均值，进入80年代各年距平值不仅为正且逐年增大；东海黑潮冬季热输送与黄淮平原区汛期降水具有相近的长期变化趋势，两者间存在较好的负相关关系。  相似文献   

长江口拦门沙地区的泥沙运动规律   总被引：12，自引：0，他引：12  

潘定安  孙介民 《海洋与湖沼》1996,27(3):279-286

依据１９８８年７月和１２月水文观测资料，通过流，盐，沙的综合分析，认识到长江口拦门沙地区的泥沙运动有与河口其他地区不同的特点，泥沙输移在水平面上和垂直面上存在着多种循环，潮流和盐水截留大量泥沙积聚的拦门沙地区，河口在盐淡水交锋地带，除了涨，落急时段外，发现在转流时期泥沙也可能产生再悬浮，从而形成一个潮周期中出现３次或４次再悬浮的特殊规律。  相似文献   

Comparative tolerance of two estuarine annelids to fluoranthene under normoxic and moderately hypoxic conditions     

Weinstein JE  Sanger DM 《Marine environmental research》2003,56(5):637-648

The tolerance of the oligochaete Monopylephorus rubroniveus and the polychaete Streblospio benedicti to sediment-associated fluoranthene was characterized under normoxic (>80% dissolved oxygen saturation) and moderately hypoxic ( approximately 50% dissolved oxygen saturation) conditions. Under both conditions, M. rubroniveus was highly tolerant of fluoranthene. Streblospio benedicti was considerably less tolerant of fluoranthene compared with M. rubroniveus. In addition, S. benedicti was less tolerant to fluoranthene under moderately hypoxic conditions, although no differences in sensitivity between the two oxygen conditions were observed based upon median lethal tissue residues. Bioaccumulation factors were higher for S. benedicti exposed to moderate hypoxia, suggesting that behavioral adaptations to compensate for the lower dissolved oxygen increased its bioaccumulation of fluoranthene. The results of the present laboratory study demonstrate that (1). changes in annelid tolerance to fluoranthene under varying oxygen conditions is a species-dependent phenomenon and (2). the differential tolerance of these two annelids to these combined stressors is consistent with their relative abundances in the field.  相似文献   

底部浮泥表层推移速度分布的ADCP—GPS估测方法   总被引：3，自引：0，他引：3  

吴中  陈力平等 《海洋工程》2002,20(4):85-88

ADCP对底跟踪走航观测的流速数据中包含水体底部浮泥、底沙运动信息,对比GPS定位方法算出的水体流速数据可以分离出浮泥相对于GPS定位的运动信号,从而达到对底质推移观测的目的。  相似文献   

The dimensions of sand ripples in full-scale oscillatory flows   总被引：1，自引：0，他引：1  

T. O'Donoghue  J.S. Doucette  J.J. van der Werf  J.S. Ribberink 《Coastal Engineering》2006,53(12):997-1012

New large-scale experiments have been carried out in two oscillatory flow tunnels to study ripple regime sand suspension and net sand transport processes in full-scale oscillatory flows. The paper focuses on ripple dimensions and the new data are combined with existing data to make a large dataset of ripple heights and lengths for flows with field-scale amplitudes and periods. A feature of the new experiments is a focus on the effect of flow irregularity. The combined dataset is analysed to examine the range of hydraulic conditions under which oscillatory flow ripples occur, to examine the effects of flow irregularity and ripple three-dimensionality on ripple dimensions and to test and improve existing methods for predicting ripple dimensions.The following are the main conclusions. (1) The highest velocities in a flow time-series play an important role in determining the type of bedform occurring in oscillatory flow. Bedform regime is well characterised by mobility number based on maximum velocity in the case of regular flow and based on the mean of the highest one tenth peak velocities in the case of irregular flow. (2) For field-scale flows, sand size is the primary factor determining whether equilibrium ripples will be 2D or 3D. 2D ripples occur when the sand D₅₀ ≥ 0.30 mm and 3D ripples occur when D₅₀ ≤ 0.22 mm (except when the flow orbital diameter is low). (3) Ripple type (2D or 3D) is the same for regular and irregular flows and ripple dimensions produced by equivalent regular and irregular flows follow a similar functional dependence on mobility number, with mobility number based on maximum velocity in the case of regular flow and based on the mean of the highest one tenth velocities in the case of irregular flow. For much of the ripple regime, ripple dimensions have weak dependency on mobility number and ripple dimensions are similar for regular and irregular flows with the same flow orbital amplitude. However, differences in ripples produced by equivalent regular and irregular flows become significant at the high mobility end of the ripple regime. (4) Ripple dimensions predicted using the Wiberg and Harris formulae are in poor agreement with measured ripple dimensions from the large-scale experiments. Predictions based on the Mogridge et al. and the Nielsen formulae show better overall agreement with the data but also show systematic differences in cases of 3D ripples and ripples generated by irregular flows. (5) Based on the combined large-scale data, modifications to the Nielsen ripple dimension equations are proposed for the heights and lengths of 2D ripples. The same equations apply to regular and irregular flows, but with mobility number appropriately defined. 3D ripples are generally smaller than 2D ripples and estimates of 3D ripple height and length may be obtained by applying multipliers of 0.55 and 0.73 respectively to the 2D formulae. The proposed modified Nielsen formulae provide an improved fit to the large-scale data, accounting for flow irregularity and ripple three-dimensionality.  相似文献   

湄洲湾泥沙活动及海底冲淤变化   总被引：1，自引：0，他引：1  

郭允谋  杨顺良 《台湾海峡》1993,12(1):8-15

湄洲湾沙源少,海水含沙量低,平均值10～20g/m~3。冬季受东北季风及浙闽沿岸流影响,湾口含沙量高,达到34g/m~3;夏季受径流影响,湾内含沙量相对偏高,达到16g/m~3。泥沙的运移趋势:主航道基本朝外,两侧朝里。受强潮流作用,深槽及水下潮流冲沟受到冲刷,斜坡及潮坪略有淤积。  相似文献   

Modelling morphological processes in the vicinity of shore-parallel breakwaters     

Julio A. Zyserman  Hakeem K. Johnson 《Coastal Engineering》2002,45(3-4)

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黄茅海河口湾现代动力地貌体系和冲淤过程分析     

杨雪舞  于红兵  孙宗勋  梁添明 《热带海洋学报》1997,(1)

1980—1993年对黄茅海河口湾进行沉积物采样和水流测定及水深测量。根据水动力和地形条件，冲淤分析及Mclaren模型研究河口湾的动力地貌体系、冲淤特征和现代沉积物运移。结果表明：（1）水下地形主要为下泄流或上溯流控制的“深槽－槽沟－浅滩－湾口”的动力地貌体系，反映了河口湾“东进西出”的水流格局；（2）整个河口湾以淤积为主，只有崖门深槽有较明显的优势冲刷特征，并随着崖门深槽向海推移和河口湾“东进西出”水动力作用，黄茅海落潮三角洲相应向西南进积；（3）应用Mclaren模型揭示了黄茅海河口湾现代沉积物运移规律，同样反映了河口湾具有“东进西出”的运移趋势。  相似文献