Mn K-edge EXAFS spectroscopy of solid-solution samples encompassing the complete MnCO3–CaCO3 series shows that first-shell Mn–O distances deviate little from the 2.19-Å distance observed in pure MnCO3. Very slight lengthening is observed only in the limiting case of dilute Mn(II) calcite solid solutions, where the Mn–O distance is 2.21 Å. The observed nearly complete structural relaxation and the composition independence of the Mn–O distance are consistent with the Pauling model behavior of solid solutions, and agree with previous studies showing a high degree of relaxation around hetero-sized substituents in the calcite structure. Strain occurs through bond bending, which is facilitated by the exclusively corner-sharing topology of calcite. Observed distances from Mn to more distant neighbors show significant variation across the solid-solution series that resembles Vegard's law-type behavior but reflects averaging. The high degree of relaxation suggests modest enthalpies of mixing in the solution, consistent with calorimetric studies. 相似文献
An Mw 5.9 earthquake occurred in the Lake Rukwa rift, Tanzania, on 1994 August 18, and was well recorded by 20 broad-band seismic stations at distances of 160 to 800 km and 21 broad-band stations at teleseismic distances. The regional and teleseismic waveforms have been used to investigate the source characteristics of the main shock, and also to locate aftershocks that occurred within three weeks of the main shock. Teleseismic body-wave modelling yields the following source parameters for the main shock: source depth of 25 ± 2 km, a normal fault orientation, with a horizontal tension axis striking NE-SW and an almost vertical pressure axis (Nodal Plane I: strike 126°–142°, dip 63°–66°, and rake 280°–290°; Nodal Plane II: strike 273°–289°, dip 28°–31°, and rake 235°–245°), a scalar moment of 4.1 times 1017 N m, and a 2 s impulsive source time function. Four of the largest aftershocks also nucleated at depths of 25 km, as deduced from regional sPmp–Pmp times. The nodal planes are broadly consistent with the orientation of both the Lupa and Ufipa faults, which bound the Rukwa rift to the northeast and southwest, respectively. The rupture radius of the main shock, assuming a circular fault, is estimated to be 4 km with a corresponding stress drop of 6.5 MPa. Published estimates of crustal thickness beneath the Rukwa rift indicate that the foci of the main shock and aftershocks lie at least 10 km above the Moho. The presence of lower-crustal seismicity beneath the Rukwa rift suggests that the pre-rift thermal structure of the rifted crust has not been strongly modified by the rifting, at least to depths of 25 km. 相似文献
Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl2[AlSi3O10](OH,F)2 series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H3BO3 contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B2O3, 3.64–5.20 wt.% Cs2O, 0.54 wt.% Li2O, 0.57 wt.% Ta2O5, 0.10 wt.% Nb2O5, 0.12 wt.% BeO. The H2O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H2O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.
Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H2O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets. 相似文献
The present study investigates the combined wave field that is induced by the continuous interaction of plane waves with an array of truncated circular cylinders in front of a rigid wall. The long-term goal of the study is the investigation of possible increase in the efficiency of cylindrical Wave Energy Converters (WECs) by putting in the vicinity of the array a barrier to propagation, a wall, that could assist the reflection of the incoming waves. The main task is to develop a generic solution method that is free of conceptual simplifications employed, e.g. by the method of images and the assumption of “pure” wave reflection. To cope with the set task, the proposed method relies on the semi-analytical formulation of the velocity potentials, while the solution is sought by combined expressions that involve polar and elliptical harmonics. The wall is represented as an elliptical cylinder with zero semi-minor axis. This assumption has eventually a beneficial effect to the underlying formulation given that it simplifies significantly the expansions of the involved diffraction potentials. 相似文献
Nature‐based approaches to flood risk management are increasing in popularity. Evidence for the effectiveness at the catchment scale of such spatially distributed upstream measures is inconclusive. However, it also remains an open question whether, under certain conditions, the individual impacts of a collection of flood mitigation interventions could combine to produce a detrimental effect on runoff response. A modelling framework is presented for evaluation of the impacts of hillslope and in‐channel natural flood management interventions. It couples an existing semidistributed hydrological model with a new, spatially explicit, hydraulic channel network routing model. The model is applied to assess a potential flood mitigation scheme in an agricultural catchment in North Yorkshire, United Kingdom, comprising various configurations of a single variety of in‐channel feature. The hydrological model is used to generate subsurface and surface fluxes for a flood event in 2012. The network routing model is then applied to evaluate the response to the addition of up to 59 features. Additional channel and floodplain storage of approximately 70,000 m3 is seen with a reduction of around 11% in peak discharge. Although this might be sufficient to reduce flooding in moderate events, it is inadequate to prevent flooding in the double‐peaked storm of the magnitude that caused damage within the catchment in 2012. Some strategies using features specific to this catchment are suggested in order to improve the attenuation that could be achieved by applying a nature‐based approach. 相似文献