GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物   总被引：2，自引：2，他引：2  

何淼  饶竹  苏劲  黄毅 《岩矿测试》2007,26(2):101-104

采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2，4-二氯酚、2，4，6-三氯酚、五氯酚等6种酚类化合物，以乙腈作为洗脱剂，选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明，方法检出限为0．01-0．05mg／L，IL水的平均加标回收率为82．5％-95．0％，精密度（RSD，n=7）为3．6％-9．2％。方法用于实际地表水中痕量酚类化合物的检测，操作简单，有机溶剂用量少，分析效率高；萃取小柱可多次重复使用，分析成本低。  相似文献   

3维模型检索的特征提取技术分析     

XU Min  ZHANG Yong-sheng 《测绘学院学报》2007,(Z1)

首先介绍了一个完整的3维模型检索系统的研究内容,然后对其中的关键技术3维模型特征提取方法中的统计特征提取方法、骨架提取方法、基于几何学的提取方法进行了分析比较。最后提出了3维模型检索技术今后需要研究的一些问题。  相似文献   

遥感影像植被信息提取方法研究及思考   总被引：3，自引：0，他引：3  

张海霞  卞正富 《地理空间信息》2007,5(6):65-67

从植被光谱特征出发,对植被信息提取的方法和现状进行了综述,其中主要介绍了几种具有代表性的植被提取方法,如:植被指数提取法、NDVI与波段合成法、HIS融合法、分级分类提取法、基于知识库提取法等,对各种方法的原理、特点、优势与限制进行了分析、对比、思考,并展望了下一步研究方向。  相似文献   

多源遥感影像配准技术分析     

禄丰年 《测绘学院学报》2007,(4)

图像配准技术是近年来发展迅速的图像处理技术之一,是图像融合、目标提取与定位、变化监测、高分辨率影像重建等处理工作不可缺少的步骤。首先给出了多源遥感影像配准的概念和基本过程,然后着重从匹配基元、转换函数、相似性测度、匹配策略4个方面对国内外现有的影像配准技术和方法进行了分析和评述,最后指出了影像配准技术所面临的主要难题和发展方向。  相似文献   

基于规则格网数据断面极值法的一种改进方法     

刘梅余  鲍峰  欧建良 《现代测绘》2007,30(3):11-12

在研究基于规则格网数据地形特征提取过程中,主要有断面极值法和流水模拟法.在断面极值法中,针对传统断面极值法生成的特征线存在零碎、并行交叉等缺点,我们改进了传统的局部断面极值法,在特征线连接过程中增加了“将特征点邻域内其它候选特征点设置为已被引用、根据特征线长度与范围阈值筛选特征线“等条件,以克服生成的特征线存在的零碎和并行交叉问题.  相似文献   

Analytical perspective on trace element species of interest in exploration   总被引：1，自引：0，他引：1  

Gwendy E. M. Hall 《Journal of Geochemical Exploration》1998,61(1-3)

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   

Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea     

Jin-Soo Lee  Hyo-Taek Chon  Kyoung-Woong Kim 《Journal of Geochemical Exploration》1998,65(1):61-78

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.  相似文献   

基于栅格数字高程模型自动提取黄土地貌沟沿线技术研究   总被引：36，自引：2，他引：34  

闾国年  钱亚东 《地理科学》1998,18(6):567-573

从数字高程模型中提取具有精确定位特征的连续的沟沿线是构建黄土沟壑丘陵地区土壤侵蚀,泥沙搬运和径流过程的空间分布式机理－过程模型的关键技术。本文提出了基于地貌形态学特征的地貌提取技术,在提取具有代表性的黄土丘陵沟壑区山西离石王家沟流域汇流网络的基础上,自动提取了该流域完整的沟沿线,得到了满意的结果。  相似文献   

航空物探剖面图数据提取法     

邢俊兵 《黄金地质》1998,4(2):55-57

我国的主要成矿区带上有着丰富的航空物探资料,而这些资料多以模拟方式进行记录,所以,我们在日常工作中所收集到的资料多是平面剖面图或平面等值线图。提供一种用数字化对平面剖面图进行数据提取的方法,为平面剖面图的二次利用提供了条件。  相似文献   

超临界萃取技术在生物资源开发和有机废水处理中的应用研究   总被引：1，自引：0，他引：1  

刘华 《矿物岩石地球化学通报》1998,(1)

超临界萃取技术在生物资源开发和有机废水处理中的应用研究＠刘华￥中国科学院地球化学研究所超临界ＣＯ＿２萃取,有机废水处理,珊瑚姜油,辣椒色素超临界萃取技术在生物资源开发和有机废水处理中的应用研究刘华（中国科学院地球化学研究所,贵阳５５０００２）收稿日期：１９...  相似文献