Effect of monochloramine on isolated fulvic acid     

James N. Jensen  J. Donald Johnson  Jessica St Aubin  Russell F. Christman 《Organic Geochemistry》1985,8(1):71-76

Monochloramine is interesting both as a selective oxidant of fulvic acid and as a drinking water disinfectant. In this study, the controlled reaction of aquatic fulvic acid with monochloramine did not result in products detectable by ether extraction-gas chromatography-flame ionization detection techniques. Evidence of a reaction was shown by bleaching of the fulvic acid solution (decreased absorbance at 465 nm) and chlorine substitution. Chlorine-containing products were quantified by the total carbon adsorbable organic halide (TOX) parameter. Bleaching and organic chlorine formation were much less extensive than in the reaction of free chlorine with fulvic acid. Monochloramine was shown to produce an organic chlorine fraction more hydrophilic and with higher molecular size than that produced by chlorine and fulvic acid. Results suggest that monochloramine may be useful tool for the investigation of certain humic functionalities because it reacts rather selectively and to a small extent with aquatic fulvic acid.  相似文献   

X射线荧光光谱法测定地质样品中的氯和硫     

袁家义  白雪冰王卿 周长祥 《岩矿测试》2004,23(3):225-227

使用粉末压片-X射线荧光光谱法测定地质样品中的Cl和S，探讨了样品放置时间、环境以及建立真空的时间对测量结果的影响。Cl的精密度(RSD，n=6)小于10％，S的精密度(RSD，n=6)小于5％。Cl和S的方法检出限分别为14和11μg／g，采用国家标准物质分析验证方法，其结果与标准值相符。  相似文献   

氯盐溶液的拉曼光谱特征及测试探讨   总被引：3，自引：5，他引：3  

张鼐张大江  张水昌张蒂嘉 崔京钢 《岩矿测试》2005,24(1):40-42

常温下氯盐溶液水的拉曼包络线歪斜度受氯离子浓度和阳离子的影响,水拉曼包络线歪斜度很难准确评价复杂流体中的氯离子浓度,在-170℃下氯盐溶液的拉曼光谱研究表明,H2O和nCl-[H OH-]n的拉曼光谱峰能很好地分解并明显地显示,其中nCl-[H OH-]n的拉曼峰与H2O的拉曼峰比值与氯盐的浓度呈正相关,用nCl-[H OH-]n的拉曼特征峰强度(I3401～3413.18cm-1)与H2O的拉曼特征峰强度(I3088～3106cm-1)比值(InCl-[H -OH-]n/IH2O)为纵座标,作相关图,二者的相关性较好,可以应用于溶液中氯离子摩尔浓度测定。  相似文献   

煤中氯赋存形态的试验研究   总被引：6，自引：0，他引：6  

徐旭  蒋旭光  何杰  严建华  岑可法 《煤田地质与勘探》2002,30(4):3-6

采用艾氏卡熔样—硫氰酸钾滴定法,对我国41个煤中氯的含量进行测定,并研究了煤中氯含量与挥发分、固定碳、灰分以及碱金属的关系。结果表明,我国煤中氯含量普遍较低,一般为0.1%~0.2%;煤中氯含量与煤的煤化程度有明显关系,煤的变质程度越高,煤中氯的含量越少。煤中氯含量与煤中水分和氟的含量无关。随着煤中碱金属含量的增加,煤中氯含量呈下降趋势,煤中氯与碱金属(Na,K,Ca,Mg)等存在负相关性。煤中氯主要以有机形式存在。   相似文献   

An Isentropic Mass Circulation View on the Extreme Cold Events in the 2020/21 Winter     

Yueyue YU  Yafei LI  Rongcai REN  Ming CAI  Zhaoyong GUAN  Wei HUANG 《大气科学进展》2022,39(4):643-657

Three extreme cold events successively occurred across East Asia and North America in the 2020/21 winter.This study investigates the underlying mechanisms of these record-breaking persistent cold events from the isentropic mass circulation(IMC)perspective.Results show that the midlatitude cold surface temperature anomalies always co-occurred with the high-latitude warm anomalies,and this was closely related to the strengthening of the low-level equatorward cold air branch of the IMC,particularly along the climatological cold air routes over East Asia and North America.Specifically,the two cold surges over East Asia in early winter were results of intensification of cold air transport there,influenced by the Arctic sea ice loss in autumn.The weakened cold air transport over North America associated with warmer northeastern Pacific sea surface temperatures(SSTs)explained the concurrent anomalous warmth there.This enhanced a wavenumber-1 pattern and upward wave propagation,inducing a simultaneous and long-lasting stronger poleward warm air branch(WB)of the IMC in the stratosphere and hence a displacement-type Stratospheric Sudden Warming(SSW)event on 4 January.The WB-induced increase in the air mass transported into the polar stratosphere was followed by intensification of the equatorward cold branch,hence promoting the occurrence of two extreme cold events respectively over East Asia in the beginning of January and over North America in February.Results do not yield a robust direct linkage from La Ni?a to the SSW event,IMC changes,and cold events,though the extratropical warm SSTs are found to contribute to the February cold surge in North America.  相似文献   

环境示踪剂（3H、Cl）在干旱半干旱区地下水补给研究中的应用          下载免费PDF全文

马宝强  王潇  汤超 《山东国土资源》2021,37(11)

地下水补给资源估算是地下水资源可持续开发利用的重要依据,传统地下水资源评价工作往往是采取水均衡法或达西定律等评价地下水补给资源,很少采用环境示踪剂方法。环境示踪剂在地下水补给研究中具有重要价值,特别是在干旱半干旱地区是一种非常简单可靠的评价方法。本文介绍了两种常见的环境示踪剂（3H、Cl）方法氚峰法和氯质量平衡法的基本原理及其在地下水补给研究中的主要应用,其中氯质量平衡法不仅可以估算地下水的补给量,而且可以研究植被覆盖变化对地下水补给影响和示踪地下水补给历史及气候变化。  相似文献   

鄂尔多斯白垩系盆地地下水的形成与演化：来自Cl及其同位素36Cl的证据   总被引：1，自引：0，他引：1  

杨郧城  沈照理  文冬光  侯光才  佘宏全  赵振宏  王冬  李进文 《地质学报》2011,85(4):586-595

鄂尔多斯自垩系地下水盆地地处中国西部干旱-半干旱地区,其南部和北部分别被黄土和沙漠覆盖,地下水水化学组成在区域上差异显著,北部以淡水为主,南部以微咸-半咸水为主.在沙漠区和黄土区的深层含水层中(埋深大于400 m)分别采集了5组和3组水化学同位素样品.T和14C的分析结果表明,地下水的滞留时间在20343 a内,并且未...  相似文献   

Effects of residual chlorine on the mortality, grazing and respiration of Labidocera euchaeta (Copepoda)     

MA Zengling  LIN Hongping  GU Xiaolian  XU Zhaoli 《海洋学报(英文版)》2011,30(2):96-102

In this study,the authors investigated the effects of residual chlorine on mortality,grazing and respiration of Labidocera euchaeta in laboratory.The grazing rate was evaluated by subtraction method of food concentration and respiration rate was measured using oxygen electrode.It was found that the lethal effect of residual chlorine on L.euchaeta increased with enhanced concentration and prolonged duration.The medium lethal concentration (LC 50 ) of chlorine for L.euchaeta in 24 h was about 0.58 mg/L and the safe concentration was about 0.21 mg/L.However,the grazing and respiration of L.euchaeta decreased by 32.6% and 18.9% when exposed to 0.2 mg/L residual chlorine for 4 h.It indicated that the physiological activities of zooplankton could be suppressed by the residual chlorine less than the safety concentration.Therefore,both survival and physiological activities of the organisms living in the thermal (nuclear) power plant discharging waters should be considered when carrying out the ecological risks assessment.  相似文献   

The role of submicrometer aerosols and macromolecules in H₂ formation in the titan haze     

E.L.O. Bakes  S.ébastien Lebonnois  Christopher P. McKay 《Icarus》2003,161(2):468-473

Previous studies of the photochemistry of small molecules in Titan’s atmosphere found it difficult to have hydrogen atoms removed at a rate sufficient to explain the observed abundance of unsaturated hydrocarbons. One qualitative explanation of the discrepancy nominated catalytic aerosol surface chemistry as an efficient sink of hydrogen atoms, although no quantitative study of this mechanism was attempted. In this paper, we quantify how haze aerosols and macromolecules may efficiently catalyze the formation of hydrogen atoms into H₂. We describe the prompt reaction model for the formation of H₂ on aerosol surfaces and compare this with the catalytic formation of H₂ using negatively charged hydrogenated aromatic macromolecules. We conclude that the PRM is an efficient mechanism for the removal of hydrogen atoms from the atmosphere to form H₂ with a peak formation rate of ∼ 70 cm⁻³ s⁻¹ at 420 km. We also conclude that catalytic H₂ formation via hydrogenated anionic macromolecules is viable but much less productive (a maximum of ∼ 0.1 cm⁻³ s⁻¹ at 210 km) than microphysical aerosols.  相似文献   

Two decades of polar ozone research via airborne science investigations: Addressing a NASA mandate in atmospheric composition     

《Comptes Rendus Geoscience》2018,350(7):341-346

The comprehensive investigation of polar ozone photochemistry and dynamics has required data obtained from as full a complement of available platforms as possible (ground-based, balloon, aircraft, and satellites). Perhaps the most detailed process studies have been conducted using measurements from aircraft, taking advantage of their targeting capabilities coupled with the potential for enabling measurements at high spatial and temporal resolution. The US National Aeronautics and Space Administration (NASA) conducted the first airborne science investigation of polar ozone in an effort to establish the causes of the recurring seasonal depletion of the Earth's stratospheric ozone layer over Antarctica that was identified in the mid-1980s. Subsequent airborne studies in the polar regions of both hemispheres benefitted from extensive successful collaborations among international scientists and the integration of the aircraft measurements with those obtained using ground-based, balloon-borne, and satellite instruments. This article provides an historical perspective of NASA's utilization of its airborne assets to advance our understanding of the chemical and physical processes that control the abundance of stratospheric ozone in both the Antarctic and Arctic.  相似文献