Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

地层学的发展推动油气地质理论研究的进步   总被引：2，自引：0，他引：2  

许红  李思田  吴河勇 《海洋地质前沿》2002,18(2):17-21

自上个世纪50年代以来,地层学经历了彻底的变革,逐渐由“相模式”、“沉积体系”、“地震地层学”发展到目前的“层序地层学”,形成高分辨率层序地层学和事件地层学的理论体系和研究方法。文章围绕层序地层学、高分辨率层序地层学基本方法及理论体系,与含油气系统相关关系进行了讨论。  相似文献   

Circalittoral Macrobenthic Assemblages of Strymonikos Gulf (North Aegean Sea)   总被引：1，自引：0，他引：1  

Costas G.  Dounas Athanasios S.  Koukouras 《Marine Ecology》1992,13(2):85-99

Abstract. Six macrobenthic assemblages of the circalittoral zone found in Strymonikos Gulf, North Aegean Sea, are described and compared with the corresponding ones from other Mediterranean and Atlantic areas. For the delimination of these assemblages and the evaluation of the major environmental gradients governing their distribution, several numerical techniques were used.  相似文献   

Crustal Structures of the Northernmost South China Sea: Seismic Reflection and Gravity Modeling   总被引：2，自引：0，他引：2  

Yi-Ching Yeh  Shu-Kun Hsu 《Marine Geophysical Researches》2004,25(1-2):45-61

The South China Sea (SCS) is a marginal sea off shore Southeast Asia. Based on magnetic study, oceanic crust has been suggested in the northernmost SCS. However, the crustal structure of the northernmost SCS was poorly known. To elaborate the crustal structures in the northernmost SCS and off southwest Taiwan, we have analyzed 20 multi-channel seismic profiles of the region. We have also performed gravity modeling to understand the Moho depth variation. The volcanic basement deepens southeastwards while the Moho depth shoals southeastwards. Except for the continental margin, the northernmost SCS can be divided into three tectonic regions: the disturbed and undisturbed oceanic crust (8–12 km thick) in the southwest, a trapped oceanic crust (8 km thick) between the Luzon-Ryukyu Transform Plate Boundary (LRTPB) and Formosa Canyon, and the area to the north of the Formosa Canyon which has the thickest sediments. Instead of faulting, the sediments across the LRTPB have only displayed differential subsidence offset of about 0.5–1 s in the northeast side, indicating that the LRTPB is no longer active. The gravity modeling has shown a relatively thin crust beneath the LRTPB, demonstrating the sheared zone character along the LRTPB. However, probably because of post-spreading volcanism, only the transtension-shearing phenomenon of volcanic basement in the northwest and southeast ends of the LRTPB can be observed. These two basement-fractured sites coincide with low gravity anomalies. Intensive erosion has prevailed over the whole channel of the Formosa Canyon.  相似文献   

透射射线的非线性效应     

夏冬明  王修田  蒋卫焱 《中国海洋大学学报(自然科学版)》2006,36(5):705-708

根据Snell定律提出了透射射线的非线性效应的概念,从理论上证明了当地震射线的轨迹在1个界面上为1条直线时在另1个界面上可为1条曲线;并进一步通过射线追踪实验证明:当地下介质为非水平层状介质时,即使对应于地面同一条直线段上的接收点,来自地下同一个界面上的反射点的轨迹仍可为一条曲线。  相似文献   

An Application of Direct Ritz Method for Random Seismic Responses of Jacket Platforms     

韩晓双马骏  赵德有周波 《中国海洋工程》2006,20(4):673-679

1 .IntroductionNowadays tremendous efforts have been devotedtothe analysis of randomseismic responses .Forexample ,American PetroleumInstitute (API) has declared that the analysis of randomseismic re-sponsesis a useful tool for safety inspection. Owing to the complexity of platformand randomness ofload,it is difficult to carry out the randomresponse analysis of a jacket platform. The conventionalrandomvibration methods ,such as square root of the sumof squares (SRSS) and complete quadratic…  相似文献   

The Vema Transverse Ridge (Central Atlantic)     

Kastens  Kim  Bonatti  Enrico  Caress  David  Carrara  Gabriela  Dauteuil  Olivier  Frueh-Green  Gretchen  Ligi  Marco  Tartarotti  Paola 《Marine Geophysical Researches》1998,20(6):533-556

Transverse ridges are elongate reliefs running parallel and adjacent to transform/fracture zones offsetting mid-ocean ridges. A major transverse ridge runs adjacent to the Vema transform (Central Atlantic), that offsets the Mid-Atlantic Ridge by 320 km. Multibeam morphobathymetric coverage of the entire Vema Transverse ridge shows it is an elongated (300 km), narrow (<30 km at the base) relief that constitutes a topographic anomaly rising up to 4 km above the predicted thermal contraction level. Morphology and lithology suggest that the Vema Transverse ridge is an uplifted sliver of oceanic lithosphere. Topographic and lithological asymmetry indicate that the transverse ridge was formed by flexure of a lithospheric sliver, uncoupled on its northern side by the transform fault. The transverse ridge can be subdivided in segments bound by topographic discontinuities that are probably fault-controlled, suggesting some differential uplift and/or tilting of the different segments. Two of the segments are capped by shallow water carbonate platforms, that formed about 3–4 m.y. ago, at which time the crust of the transverse ridge was close to sea level. Sampling by submersible and dredging indicates that a relatively undisturbed section of oceanic lithosphere is exposed on the northern slope of the transverse ridge. Preliminary studies of mantle-derived ultramafic rocks from this section suggest temporal variations in mantle composition. An inactive fracture zone scarp (Lema fracture zone) was mapped south of the Vema Transverse ridge. Based on morphology, a fossil RTI was identified about 80 km west of the presently active RTI, suggesting that a ridge jump might have occurred about 2.2 m.a. Most probable causes for the formation of the Vema Transverse ridge are vertical motions of lithospheric slivers due to small changes in the direction of spreading of the plates bordering the Vema Fracture Zone.  相似文献   

Annual Anthropogenic Carbon Transport into the North Pacific Intermediate Water through the Kuroshio/Oyashio Interfrontal Zone: An Estimation from CFCs Distribution     

Tsuneo Ono  Yutaka W. Watanabe  Katsuyuki Sasaki 《Journal of Oceanography》2000,56(6):675-689

Vertical distribution of anthropogenic carbon content of the water (exDIC) in the Oyashio area just outside of the Kuroshio/Oyashio Interfrontal Zone (K/O Zone) was estimated by the simple 1-D advection-diffusion model calibrated by the distribution of chlorofluorocarbons (CFCs). The average concentration of exDIC for = 26.60–27.00 is multiplied by the volume transport of Oyashio water into the North Pacific Intermediate Water (NPIW) to estimate the annual transport of exDIC into NPIW through K/O Zone. The estimated transport of exDIC was 0.018–0.020 GtC/y, which corresponds to 15% of the whole total exDIC accumulation in the temperate North Pacific. A simple assessment using the NPIW 1-box model indicates that the current study explains at least 70% of the total annual transport of exDIC into NPIW, and that small exDIC sources for NPIW still exists in addition to K/O Zone.  相似文献   

威海地区高压岩石组合及其成因演化     

韩宗珠  王来明  张希道  毛振业 《中国海洋大学学报(自然科学版)》1993,(3)

利用矿物地质温压计估算变质高峰期温压条件、退变质作用温压条件。研究表明,本区为鲁苏构造带的北延部分,代表本区晚元古代华南陆块与华北陆块的碰撞及三叠纪华北陆块向华南陆块推覆事件的发生和演化。  相似文献   

福建深沪湾潮间带全新世有孔虫及其环境意义   总被引：2，自引：1，他引：2  

王绍鸿  俞鸣同  唐丽玉  赵希涛  王雪梅  黄向华 《台湾海峡》2002,21(1):6-11

本文对深沪湾西部潮间带表层沉积物和两个钻孔岩芯共30个样品的有孔虫组成进行了定性和定量分析。结果表明，表层沉积物中有孔虫群分布规律明显，随着离岸向海越远，水深越大，有孔虫娄量从1倍数上升到5位数，种数为9-69种，多变度V31-44，复合分异度H（s)3.25-3.25。从钻孔岩芯中的全新世有孔虫群特征可看出，中全新世以来海面升降和海洋环境可分为2个阶段：（1）海水初到钻孔位置，有孔虫数量和种数较少，分异度不高，海相性程度较低。（2）后期（埋深1.8m和2.0m以浅），海面有所升高，变为潮间带（高潮位→中潮位→低潮位）环境。  相似文献