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101.
We have acquired resolved images of Titan with the adaptive optics systems PUEO/KIR at the CFHT (Hawaii) and NAOS/CONICA at the VLT (Chile). We report here on images and maps (when data at several orbital phases are available) of Titan's surface from observations taken during the last 4 years (2001-2004) in all the methane windows between 1 and 2.5 μm (namely, at 1.08, 1.28, 1.6, and 2 μm). We present the only complete maps of Titan currently available at 1.3 μm, a spectral window where Titan appears particularly bright in spectroscopy, with a resolution of about 200 km at best on the ground. Our surface maps show the bright and dark regions sharing Titan's landscape with as much detail as possible from the ground and with high contrast in most cases. From the information gathered by comparing the maps at different wavelengths we derive constraints on the ground's composition. Our results could complete/optimize the return of the Cassini-Huygens mission. 相似文献
102.
We have analysed all the available high phase angle images of Titan limb taken by Voyager 1 and 2, in early 1980. For several different phase angles and wavelengths, we seek for a consistent set of haze parameters able to fit all data simultaneously. Our main purpose is to obtain an accurate estimate of the latitudinal variation of haze opacity at 200 km altitude at the time of the Voyager flyby's. We find that haze opacity at 200 km is about constant in the southern hemisphere and drops between equator and 60°N by about 30-50%, sharply increasing again beyond 60°N. The latter feature is clearly due to the north polarhood.This behaviour is opposite to total optical depth variations retrieved from IRIS observation, at the same epoch. The IRIS data refer to levels below 100 km altitude. A comparison of our results with calculations from a general circulation model, shows that (1) our results are realistic and can be considered as robust (2) the opacity variations at 200 km (this work) and at ground (IRIS data), although opposite, are not inconsistent with each other. 相似文献
103.
Models of Titan ionospheric chemistry have shown that ion densities depend strongly on the neutral composition. The turbulent diffusion transport conditions, as modeled by eddy coefficients, can spectacularly affect the uncertainty on predicted neutral densities. In order to evaluate the error budget on ion densities predicted by photochemical models, we perform uncertainty propagation of neutral densities by Monte Carlo sampling and assess their sensitivity to two turbulent diffusion profiles, corresponding to the extreme profiles at high altitudes described in the literature. A strong sensitivity of the ion density uncertainties to transport is observed, generally more important than to ion–molecule reaction parameters themselves. This highlights the necessity to constrain eddy diffusion profiles for Titan ionosphere, which should progressively be done thanks to the present and future measurements of the orbiter Cassini. 相似文献
104.
High-energy photons, electrons, and ions initiate ion-neutral chemistry in Titan's upper atmosphere by ionizing the major neutral species (nitrogen and methane). The Ion and Neutral Mass Spectrometer (INMS) onboard the Cassini spacecraft performed the first composition measurements of Titan's ionosphere. INMS revealed that Titan has the most compositionally complex ionosphere in the Solar System, with roughly 50 ions at or above the detection threshold. Modeling of the ionospheric composition constrains the density of minor neutral constituents, most of which cannot be measured with any other technique. The species identified with this approach include the most complex molecules identified so far on Titan. This confirms the long-thought idea that a very rich chemistry is actually taking place in this atmosphere. However, it appears that much of the interesting chemistry occurs in the upper atmosphere rather than at lower altitudes. The species observed by INMS are probably the first intermediates in the formation of even larger molecules. As a consequence, they affect the composition of the bulk atmosphere, the composition and optical properties of the aerosols and the flux of condensable material to the surface. In this paper, we discuss the production and loss reactions for the ions and how this affects the neutral densities. We compare our results to neutral densities measured in the stratosphere by other instruments, to production yields obtained in laboratory experiments simulating Titan's chemistry and to predictions of photochemical models. We suggest neutral formation mechanisms and highlight needs for new experimental and theoretical data. 相似文献
105.
Lauren C. Wye Howard A. Zebker Richard D. West Ralph D. Lorenz the Cassini RADAR Team 《Icarus》2007,188(2):367-385
We report regional-scale low-resolution backscatter images of Titan's surface acquired by the Cassini RADAR scatterometer at a wavelength of 2.18-cm. We find that the average angular dependence of the backscatter from large regions and from specific surface features is consistent with a model composed of a quasi-specular Hagfors term plus a diffuse cosine component. A Gaussian quasi-specular term also fits the data, but less well than the Hagfors term. We derive values for the mean dielectric constant and root-mean-square (rms) slope of the surface from the quasi-specular term, which we ascribe to scattering from the surface interface only. The diffuse term accommodates contributions from volume scattering, multiple scattering, or wavelength-scale near-surface structure. The Hagfors model results imply a surface with regional mean dielectric constants between 1.9 and 3.6 and regional surface roughness that varies between 5.3° and 13.4° in rms-slope. Dielectric constants between 2 and 3 are expected for a surface composed of solid simple hydrocarbons, water ice, or a mixture of both. Smaller dielectric constants, between 1.6 and 1.9, are consistent with liquid hydrocarbons, while larger dielectric constants, near 4.5, may indicate the presence of water-ammonia ice [Lorenz, R.D., 1998. Icarus 136, 344-348] or organic heteropolymers [Thompson, W.R., Squyres, S.W., 1990. Icarus 86, 336-354]. We present backscatter images corrected for angular effects using the model residuals, which show strong features that correspond roughly to those in 0.94-μm ISS images. We model the localized backscatter from specific features to estimate dielectric constant and rms slope when the angular coverage is within the quasi-specular part of the backscatter curve. Only two apparent surface features are scanned with angular coverage sufficient for accurate modeling. Data from the bright albedo feature Quivira suggests a dielectric constant near 2.8 and rms slope near 10.1°. The dark albedo feature Shangri-La is best fit by a Hagfors model with a dielectric constant close to 2.4 and an rms slope near 9.5°. From the modeled backscatter curves, we find the average radar albedo in the same linear (SL) polarization to be near 0.34. We constrain the total-power albedo in order to compare the measurements with available groundbased radar results, which are typically obtained in both senses of circular polarization. We estimate an upper limit of 0.4 on the total-power albedo, a value that is significantly higher than the 0.21 total albedo value measured at 13 cm [Campbell, D., Black, G., Carter, L., Ostro, S., 2003. Science 302, 431-434]. This is consistent with a surface that has more small-scale structure and is thus more reflective at 2-cm than 13-cm. We compare results across overlapping observations and observe that the reduction and analysis are repeatable and consistent. We also confirm the strong correlations between radar and near-infrared images. 相似文献
106.
Jason W. Barnes Robert H. Brown Christophe Sotin Stephane Le Mouèlic Roger Clark 《Icarus》2007,186(1):242-258
We present global-scale maps of Titan from the Visual and Infrared Mapping Spectrometer (VIMS) instrument on Cassini. We map at 64 near-infrared wavelengths simultaneously, covering the atmospheric windows at 0.94, 1.08, 1.28, 1.6, 2.0, 2.8, and 5 μm with a typical resolution of 50 km/pixel or a typical total integration time of 1 s. Our maps have five to ten times the resolution of ground-based maps, better spectral resolution across most windows, coverage in multiple atmospheric windows, and represent the first spatially resolved maps of Titan at 5 μm. The VIMS maps provide context and surface spectral information in support of other Cassini instruments. We note a strong latitudinal dependence in the spectral character of Titan's surface, and partition the surface into 9 spectral units that we describe in terms of spectral and spatial characteristics. 相似文献
107.
We describe a model for crater populations on planets and satellites with dense atmospheres, like those of Venus and Titan. The model takes into account ablation (or mass shedding), pancaking, and fragmentation. Fragmentation is assumed to occur due to the hydrodynamic instabilities promoted by the impactors’ deceleration in the atmosphere. Fragments that survive to hit the ground make craters or groups thereof. Crater sizes are estimated using standard laws in the gravity regime, modified to take into account impactor disruption. We use Monte Carlo methods to pick parameters from appropriate distributions of impactor mass, zenith angle, and velocity. Good fits to the Venus crater populations (including multiple crater fields) can be found with reasonable values of model parameters. An important aspect of the model is that it reproduces the dearth of small craters on Venus: this is due to a cutoff on crater formation we impose, when the expected crater would be smaller than the (dispersed) object that would make it. Hydrodynamic effects alone (ablation, pancaking, fragmentation) due to the passage of impactors through the atmosphere are insufficient to explain the lack of small craters. In our favored model, the observed number of craters (940) is produced by ∼5500 impactors with masses , yielding an age of (1-σ uncertainty) for the venusian surface. This figure does not take into account any uncertainties in crater scaling and impactor population characteristics, which probably increase the uncertainty to a factor of two in age.We apply the model with the same parameter values to Titan to predict crater populations under differing assumptions of impactor populations that reflect present conditions. We assume that the impactors (comets) are made of 50% porous ice. Predicted crater production rates are ≈190 craters . The smallest craters on Titan are predicted to be in diameter, and ≈5 crater fields are expected. If the impactors are composed of solid ice (density ), crater production rates increase by ≈70% and the smallest crater is predicted to be in diameter. We give cratering rates for denser comets and atmospheres 0.1 and 10 times as thick as Titan's current atmosphere. We also explicitly address leading-trailing hemisphere asymmetries that might be seen if Titan's rotation rate were strictly synchronous over astronomical timescales: if that is the case, the ratio of crater production on the leading hemisphere to that on the trailing hemisphere is ≈4:1. 相似文献
108.
109.
We report the three-dimensional fluorescence spectra of Titan tholins in water and acetonitrile, and separate some of the fluorescent components of tholins using two-dimensional thin layer chromatography. In acetonitrile, tholins exhibit a broad fluorescence with a maximum at 471 nm, and an excitation maximum at 410 nm. The fluorescence spectrum of a water extraction displays a more complicated spectrum with multiple peaks. TLC results indicate the presence of at least three distinct fluorescent species. In addition, we obtained the two-dimensional fluorescence spectrum of tholins in water ice at 77 K, close to the surface temperature of Titan. The fluorescence of tholins in a 77 K ice matrix is red-shifted in comparison to a water solution, and undergoes a further red-shift when the water solution is heated prior to freezing. These results suggest that a simple fluorescence probe could be used on the surface of Titan to identify sites where tholins have been mixed with water, and possibly reveal information about the extent of heating the tholin-water mixture has undergone. This would be useful for a future mission with the goal of examining the organic chemistry of Titan. 相似文献
110.
Simon Petrie 《Icarus》2004,171(1):199-209
We report results of quantum chemical calculations of Mg+/ligand bond dissociation energies involving ligands identified as major constituents of Titan's upper atmosphere. Trends identified in these results allow elucidation of the important bimolecular and termolecular reactions of Mg+, and of simple molecular ions containing Mg+, arising from meteoric infall into Titan's atmosphere. Our study highlights, and includes calculated rate coefficients for, crucial ligand-switching and ligand-stripping reactions which ensure that a dynamic equilibrium exists between atomic and molecular ions of Mg+. Neutralization of ionized meteoric Mg is expected to produce the radical MgNC in high yield. The highly polar MgNC radical should provide an excellent nucleation site for condensation of polar (e.g., HCN, CH3CN, and HC3N) and highly unsaturated (e.g., C2H2, C4H2, and C2N2) neutrals at comparatively high altitude, leading to precipitation of Mg-doped tholin-like material. The implications for Titan's prebiotic chemical evolution, of the surface deposition of such material (which may feasibly contain magnesium porphyrins, or other bioactive Mg-containing complexes) remain to be assessed. 相似文献