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241.
242.
Numerical analysis of the hydrogeologic controls in a layered coastal aquifer system, Oahu, Hawaii, USA 总被引:3,自引:1,他引:2
Delwyn S. Oki William R. Souza Edward L. Bolke Glenn R. Bauer 《Hydrogeology Journal》1998,6(2):243-263
The coastal aquifer system of southern Oahu, Hawaii, USA, consists of highly permeable volcanic aquifers overlain by weathered
volcanic rocks and interbedded marine and terrestrial sediments of both high and low permeability. The weathered volcanic
rocks and sediments are collectively known as caprock, because they impede the free discharge of groundwater from the underlying
volcanic aquifers. A cross-sectional groundwater flow and transport model was used to evaluate the hydrogeologic controls
on the regional flow system in southwestern Oahu. Controls considered were: (a) overall caprock hydraulic conductivity; and
(b) stratigraphic variations of hydraulic conductivity in the caprock. Within the caprock, variations in hydraulic conductivity,
caused by stratigraphy or discontinuities of the stratigraphic units, are a major control on the direction of groundwater
flow and the distribution of water levels and salinity. Results of cross-sectional modeling confirm the general groundwater
flow pattern that would be expected in a layered coastal system. Groundwater flow is: (a) predominantly upward in the low-permeability
sedimentary units; and (b) predominantly horizontal in the high-permeability sedimentary units.
Received, October 1996 Revised, August 1997 Accepted, September 1997 相似文献
243.
Chlorine-36 is a radionuclide with a half-life of 3.01×105a. Most 36Cl in the hydrosphere originates from cosmic radiation interacting with atmospheric gases. Large amounts were also produced
by testing thermonuclear devices during 1952–58. Because the monovalent anion, chloride, is the most common form of chlorine
found in the hydrosphere and because it is extremely mobile in aqueous systems, analyses of both total Cl– as well as 36Cl have been important in numerous hydrologic studies. In almost all applications of 36Cl, a knowledge of the initial, or pre-anthropogenic, levels of 36Cl is useful, as well as essential in some cases. Standard approaches to the determination of initial values have been to:
(a) calculate the theoretical cosmogenic production and fallout, which varies according to latitude; (b) measure 36Cl in present-day precipitation and assume that anthropogenic components can be neglected; (c) assume that shallow groundwater
retains a record of the initial concentration; (d) extract 36Cl from vertical depth profiles in desert soils; (e) recover 36Cl from cores of glacial ice; and (f) calculate subsurface production of 36Cl for water that has been isolated from the atmosphere for more than one million years. The initial value from soil profiles
and ice cores is taken as the value that occurs directly below the depth of the easily defined bomb peak. All six methods
have serious weaknesses. Complicating factors include 36Cl concentrations not related to cosmogenic sources, changes in cosmogenic production with time, mixed sources of chloride
in groundwater, melting and refreezing of water in glaciers, and seasonal groundwater recharge that does not contain average
year-long concentrations of 36Cl.
Received, December 1996 · Revised, August 1997 · Accepted, August 1997 相似文献
244.
R. E. Jackson 《Hydrogeology Journal》1998,6(1):144-155
The migration, dissolution, and subsequent fate of spilled chlorinated solvents in the urban alluvial valleys of the southwestern
U.S. appear to be governed by a unique set of hydrogeologic and geochemical processes occurring within terrigeneous clastic
depositional systems. The alluvial and lacustrine fill of the basins, the trapping of solvents in fine-grained sediments beneath
the urbanized valley centers, the oxic conditions typical of the deeper alluvium, and the contaminant-transport patterns produced
by large-scale basin pumping combine to produce long aqueous-phase plumes derived from the dissolution of trapped chlorinated
solvents. Although of limited aqueous solubility, these dense solvents are sufficiently mobile and soluble in the southwestern
alluvial valleys to have produced aqueous plumes that have migrated several kilometers through the deeper alluvium and have
contaminated valuable water-supply well fields in California, Arizona, and New Mexico. The typical length of these plumes
and the presence of oxic groundwater indicate that it is unlikely that natural attenuation will be a practical remedial option
in the southwestern alluvial valleys or in other alluvial systems in which similar hydrogeologic and geochemical conditions
exist.
Received, December 1996 · Revised, October 1997 · Accepted, November 1997 相似文献
245.
Allan Kolker Mark A. Engle William H. Orem Joseph E. Bunnell Harry E. Lerch David P. Krabbenhoft Mark L Olson Jamey D. McCord 《Geostandards and Geoanalytical Research》2008,32(3):279-293
Compliance with U.S. air quality regulatory standards for atmospheric fine particulate matter (PM2.5) is based on meeting average 24 hour (35 μ m?3) and yearly (15 μg m?3) mass‐per‐unit‐volume limits, regardless of PM2.5 composition. Whereas this presents a workable regulatory framework, information on particle composition is needed to assess the fate and transport of PM2.5 and determine potential environmental/human health impacts. To address these important non‐regulatory issues an integrated approach is generally used that includes (1) field sampling of atmospheric particulate matter on filter media, using a size‐limiting cyclone, or with no particle‐size limitation; and (2) chemical extraction of exposed filters and analysis of separate particulate‐bound fractions for total mercury, trace elements and organic constituents, utilising different USGS laboratories optimised for quantitative analysis of these substances. This combination of sampling and analysis allowed for a more detailed interpretation of PM2.5 sources and potential effects, compared to measurements of PM2.5 abundance alone. Results obtained using this combined approach are presented for a 2006 air sampling campaign in Shenandoah National Park (Virginia, USA) to assess sources of atmospheric contaminants and their potential impact on air quality in the Park. PM2.5 was collected at two sampling sites (Big Meadows and Pinnacles) separated by 13.6 km. At both sites, element concentrations in PM25 were low, consistent with remote or rural locations. However, element/Zr crustal abundance enrichment factors greater than 10, indicating anthropogenic input, were found for Hg, Se, S, Sb, Cd, Pb, Mo, Zn and Cu, listed in decreasing order of enrichment. Principal component analysis showed that four element associations accounted for 84% of the PM2.5 trace element variation; these associations are interpreted to represent: (1) crustal sources (Al, REE); (2) coal combustion (Se, Sb), (3) metal production and/or mobile sources (Mo, Cd, Pb, Cu, Zn) and (4) a transient marine source (Sr, Mg). Concentrations of Hg in PM2.5 at background levels in the single pg m?3 were shown by collection and analysis of PM2.5 on filters and by an automated speciation analyser set up at the Big Meadows air quality site. The speciation unit revealed periodic elevation of reactive gaseous mercury (RGM) that co‐occurred with peaks in SO2, indicating an anthropogenic source. GC/MS total ion current chromatograms for the two sites were quite similar indicating that organic signatures were regional in extent and/or that the same compounds were present locally at each site. Calculated carbon preference index values for n‐alkanes indicated that plant waxes rather than anthropogenic sources, were the dominant alkane source. Polycyclic aromatic hydrocarbons (PAHs) were detected, with a predominance of non‐alkylated, and higher molecular weight PAHs in this fraction, suggestive of a combustion source (fossil fuel or forest fires). 相似文献
246.
Anne G. Hereford Elizabeth H. Keating George D. GuthrieJr Chen Zhu 《Environmental Geology》2007,52(5):965-977
Reactions and reaction rates within aquifers are fundamental components of critical hydrological processes. However, reactions
simulated in laboratory experiments typically demonstrate rates that are much faster than those observed in the field. Therefore,
it is necessary to conduct more reaction rate analyses in natural settings. This study of geochemical reactions in the regional
aquifer in the Pajarito Plateau near Los Alamos, New Mexico combines modeling with petrographic assessment to further knowledge
and understanding of complex natural hydrologic systems. Groundwater geochemistry shows marked evolution along assumed flow
paths. The flow path chosen for this study was evaluated using inverse mass balance modeling to calculate the mass transfer.
X-ray diffraction and field emission gun scanning electron microscopy were used to identify possible reactants and products.
Considering the mineralogy of the aquifer and saturation indices for the regional water refined initial interpretations. Calculations
yielded dissolution rates for plagioclase on the order of 10−15 mol s−1 m−2 and for K-feldspar on the order of 10−17 mol s−1 m−2, orders of magnitude slower than laboratory rates. While these rates agree with other aquifer studies, they must be considered
in the light of the uncertainty associated with geometric surface area estimates, 14C ages, and aquifer properties. 相似文献
247.
This study documents hydrological changes resulting from urbanization of the upper sub-basin of White Rock Creek watershed
in Collin and Dallas counties, Texas. The 172-km2 watershed was transformed from 87% rural in 1961 to 95% urban in 2002, following construction of the Dallas suburbs of Richardson,
Addison, Plano and Frisco. The objective of the study was to investigate changes in the storm response of White Rock Creek
in terms of peak storm flow, storm flow volume and lag time. The approach employed to compare pre- and post-urbanization hydrology
was to develop average unit hydrographs for each time period and use them to generate the creek’s storm flow response to a
set of six hypothetical precipitation events. The results suggest that substantial hydrological changes have occurred. The
average infiltration capacity of the watershed was reduced by about 60% so that storm flow was generated at lower precipitation
intensities in the post-urbanization period. Storm flow peak discharge and volume were more than doubled for a hypothetical
10-year precipitation event. Average lag time was about 49 min shorter in the post-urbanization period. Urbanization has significantly
impacted the storm response of the creek and increased the potential for flooding. It is anticipated that similar hydrological
changes will occur in other rapidly urbanizing watersheds in the Dallas-Fort Worth Metropolitan region. Watershed managers
should take likely changes in storm response into account when planning future storm water management needs. 相似文献
248.
《地学前缘(英文版)》2023,14(3):101531
This study analyzes the impact of biomass energy, financial development, and economic growth on environmental quality using the novel Fourier autoregressive distributed lag (ARDL) approach on annual data for the period 1965–2018 in the United States (USA). The study analyzes the impact of related variables on the load capacity factor (LCF) as well as on indicators of environmental degradation such as carbon dioxide emissions and ecological footprint. The LCF is one of the most comprehensive environmental indicators to date, encompassing both biocapacity and ecological footprint. In this regard, this study contributes to the environmental economics literature by examining, for the first time, the impact of biomass energy on the LCF. The results of the cointegration test show that there is only a long-run relationship between the LCF and the independent variables. According to the Fourier ARDL results, biomass energy improves the environmental quality, while financial development has no effect on the LCF. Moreover, the increase in per capita income reduces the LCF. Furthermore, since the income elasticity is larger in the long run than in the short-run, the environmental Kuznets curve is validated. Therefore, the United States government should encourage the use of biomass and investment in this form of energy. 相似文献
249.
In this study, we assessed importance of sediment-associated trace metals in structuring benthic macroinfaunal assemblages along multiple environmental gradients in chronically polluted salt marshes of the Arthur Kill - AK (New York, USA). More than 90% of benthic macroinfaunal communities at the northern AK sites consisted of a considerably large number of only a few polychaete and oligochaete species. Approximately 70% of among-site variances in abundance and biomass of benthic macroinfaunal communities was strongly associated with a few environmental variables; only sediment-associated mercury consistently contributed to a significant proportion of the explained variances in species composition along natural environmental gradients (e.g., salinity). Although sediment-associated copper, lead, and zinc were substantially elevated at some of the AK sites, their ecological impacts on benthic macroinfaunal communities appeared to be negligible. These findings suggest that cumulative metal-specific impacts may have played an important role in structuring benthic macroinfaunal communities in chronically polluted AK ecosystems. 相似文献
250.
Sediment transport and the potential for erosion or deposition have been investigated on the Palos Verdes (PV) and San Pedro shelves in southern California to help assess the fate of an effluent-affected deposit contaminated with DDT and PCBs. Bottom boundary layer measurements at two 60-m sites in spring 2004 were used to set model parameters and evaluate a one-dimensional (vertical) model of local, steady-state resuspension, and suspended-sediment transport. The model demonstrated skill (Brier scores up to 0.75) reproducing the magnitudes of bottom shear stress, current speeds, and suspended-sediment concentrations measured during an April transport event, but the model tended to underpredict observed rotation in the bottom-boundary layer, possibly because the model did not account for the effects of temperature–salinity stratification. The model was run with wave input estimated from a nearby buoy and current input from four to six years of measurements at thirteen sites on the 35- and 65-m isobaths on the PV and San Pedro shelves. Sediment characteristics and erodibility were based on gentle wet-sieve analysis and erosion-chamber measurements. Modeled flow and sediment transport were mostly alongshelf toward the northwest on the PV shelf with a significant offshore component. The 95th percentile of bottom shear stresses ranged from 0.09 to 0.16 Pa at the 65-m sites, and the lowest values were in the middle of the PV shelf, near the Whites Point sewage outfalls where the effluent-affected layer is thickest. Long-term mean transport rates varied from 0.9 to 4.8 metric tons m−1 yr−1 along the 65-m isobaths on the PV shelf, and were much higher at the 35-m sites. Gradients in modeled alongshore transport rates suggest that, in the absence of a supply of sediment from the outfalls or PV coast, erosion at rates of ∼0.2 mm yr−1 might occur in the region southeast of the outfalls. These rates are small compared to some estimates of background natural sedimentation rates (∼5 mm yr−1), but do not preclude higher localized rates near abrupt transitions in sediment characteristics. However, low particle settling velocities and strong currents result in transport length-scales that are long relative to the narrow width of the PV shelf, which combined with the significant offshore component in transport, means that transport of resuspended sediment towards deep water is as likely as transport along the axis of the effluent-affected deposit. 相似文献