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金刚石中分子氢的赋存状态研究   总被引:1,自引:0,他引:1  
金刚石中分子氢的定向红外光谱研究表明在垂直于(100),(110)和(111)三个方向上所测得分子氢的浓度是不相同的,且不同样品中的变化趋势也不同,即分子氢在金刚石中的定向性不明显;MNDO法计算结果显示分子氢在金刚石中的稳定程度大小关系依次为沿〈111〉定向的键心与反键心组合(a.b+b.c)〉六角体空隙(H)〉四面体空隙(T1)〉菱形中心(C1=C2)〉四面体空隙(T2).  相似文献   
13.
美国城市搜索与救援体系是世界上最完善的体系之一,多年来在城市救灾和应对突发事件中发挥了重要作用,减轻了生命和财产的损失。文章概述了美国城市搜索与救援体系的组成、任务、运作原则和管理机构及支援机构。  相似文献   
14.
Despite the wealth of archaeological sites and excellent conditions for preservation, few phytolith investigations have been undertaken from the Arabian Gulf region. The results from the Sasanian and Islamic archaeological tell of Kush, Ras al-Khaimah, United Arab Emirates, are presented. Kush is situated just inside the Gulf on an important trade route. The occupation sequence dates from the 4th century A.D. until the 13th century A.D., recording the development of the site in the Sasanian period, followed by the arrival of Islam in the 7th century A.D. and the final abandonment of the site in the late 13th century when the nearby site of al-Mataf (Julfar) began to develop closer to the present day coastline. All the samples analyzed contained abundant phytoliths (short cells, elongated cells, and groups of elongated cells) of various types. They included date palm (Phoenix dactylifera), papillae (possibly from barley (Hordeum)), and hair cells possibly from species of canary grass (Phalaris spp.). Some researchers have suggested that groups of elongated cells may indicate the presence of irrigation in semiarid environments. The present results for this class of phytoliths appeared to imply that intensive irrigation was unlikely to have taken place around Kush.  相似文献   
15.
垃圾产生于社会的每一个角落,垃圾也反映了人类生活的各个方面。可是,直至最近,社会依然极少理会垃圾中真正蕴藏着些什么,以及垃圾能够告诉我们些什么。1973年美国图森市亚利桑那大学威廉·拉舍基博士(WilliamLRathje)及其同事们所建立并发展的垃级计划,标志着一门新科学──垃圾学的兴起,即垃圾的系统研究、垃圾产生、运移、利用和处置的机理以及相关的社会经济和环境问题。美国和其它少数国家的垃圾学研究所揭示的各种事实、定律和原理,正划时代地碰击着现代社会、社会心理学、市场和许多其它领域,大量的城市固体废物不仅意味着自然资源的巨大浪费,而且垃圾处理,无论焚化或者填埋,都对环境构成了严重污染的威胁,尤其是对地下水资源。垃圾的管理、再循环和处置费用是昂贵的,而且总是受到错综复杂的社会和法律冲突的挑战,纽约和美国东部其它人口稠密地区所面临的严峻形势就是最好的例证,解决现今进退维谷的垃圾问题,需要包括技术的、社会的、环境的、经济的、政治的、法律的和公共教育在内的多方面协作。中国正经历着令人振奋的经济发展时期。预计以现在的国民经济发展速度,以及因巨量人口而导致的社会消费的急剧增长,在未来10~20年内,很有可能导致严重的  相似文献   
16.
Analyses of mineral inclusions, carbon isotopes, nitrogen contents and nitrogen aggregation states in 29 diamonds from two Buffalo Hills kimberlites in northern Alberta, Canada were conducted. From 25 inclusion bearing diamonds, the following paragenetic abundances were found: peridotitic (48%), eclogitic (32%), eclogitic/websteritic (8%), websteritic (4%), ultradeep? (4%) and unknown (4%). Diamonds containing mineral inclusions of ferropericlase, and mixed eclogitic-asthenospheric-websteritic and eclogitic-websteritic mineral associations suggests the possibility of diamond growth over a range of depths and in a variety of mantle environments (lithosphere, asthenosphere and possibly lower mantle).

Eclogitic diamonds have a broad range of C-isotopic composition (δ13C=−21‰ to −5‰). Peridotitic, websteritic and ultradeep diamonds have typical mantle C-isotope values (δ13C=−4.9‰ av.), except for two 13C-depleted peridotitic (δ13C=−11.8‰, −14.6‰) and one 13C-depleted websteritic diamond (δ13C=−11.9‰). Infrared spectra from 29 diamonds identified two diamond groups: 75% are nitrogen-free (Type II) or have fully aggregated nitrogen defects (Type IaB) with platelet degradation and low to moderate nitrogen contents (av. 330 ppm-N); 25% have lower nitrogen aggregation states and higher nitrogen contents (30% IaB; <1600 ppm-N).

The combined evidence suggests two generations of diamond growth. Type II and Type IaB diamonds with ultradeep, peridotitic, eclogitic and websteritic inclusions crystallised from eclogitic and peridotitic rocks while moving in a dynamic environment from the asthenosphere and possibly the lower mantle to the base of the lithosphere. Mechanisms for diamond movement through the mantle could be by mantle convection, or an ascending plume. The interaction of partial melts with eclogitic and peridotitic lithologies may have produced the intermediate websteritic inclusion compositions, and can explain diamonds of mixed parageneses, and the overlap in C-isotope values between parageneses. Strong deformation and extremely high nitrogen aggregation states in some diamonds may indicate high mantle storage temperatures and strain in the diamond growth environment. A second diamond group, with Type IaA–IaB nitrogen aggregation and peridotitic inclusions, crystallised at the base of the cratonic lithosphere. All diamonds were subsequently sampled by kimberlites and transported to the Earth's surface.  相似文献   

17.
A mineral inclusion, carbon isotope, nitrogen content, nitrogen aggregation state and morphological study of 576 microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, was conducted. Mineral inclusion data show the diamonds are largely eclogitic (64%), followed by peridotitic (25%) and ultradeep (11%). The paragenetic abundances are similar to macrodiamonds from the DO27 kimberlite (Davies, R.M., Griffin, W.L., O'Reilly, S.Y., 1999. Diamonds from the deep: pipe DO27, Slave craton, Canada. In: Gurney, J.J., Gurney, J.L., Pascoe, M.D., Richardson, S.H. (Eds.), The J. B. Dawson Vol., Proc. 7th Internat. Kimberlite Conf., Red Roof Designs, Cape Town, pp. 148–155) but differ to diamonds from nearby kimberlites at Ekati (e.g., Lithos (2004); Tappert, R., Stachel, T., Harris, J.W., Brey, G.P., 2004. Mineral Inclusions in Diamonds from the Panda Kimberlite, S. P., Canada. 8th International Kimberlite Conference, extended abstracts) and Snap Lake to the south (Dokl. Earth Sci. 380 (7) (2001) 806), that are dominated by peridotitic stones.

Eclogitic diamonds with variable inclusion compositions and temperatures of formation (1040–1300 °C) crystallised at variable lithospheric depths sometimes in changing chemical environments. A large range to very 13C-depleted C-isotope compositions (δ13C=−35.8‰ to −2.2‰) and an NMORB bulk composition, calculated from trace elements in garnet and clinopyroxene inclusions, are consistent with an origin from subducted oceanic crust and sediments. Carbon isotopes in the peridotitic diamonds have mantle compositions (δ13C mode −4.0‰). Mineral inclusion compositions are largely harzburgitic. Variable temperatures of formation (garnet TNi=800–1300 °C) suggest the peridotitic diamonds originate from the shallow ultra-depleted and deeper less depleted layers of the central Slave lithosphere. Carbon isotopes (δ13C av.=−5.1‰) and mineral inclusions in the ultradeep diamonds suggest they formed in peridotitic mantle (670 km). The diamonds may have been entrained in a plume and subcreted to the base of the central Slave lithosphere.

Poorly aggregated nitrogen (IaA without platelets) in a large number of eclogitic (67%) and peridotitic (32%) diamonds, with similar nitrogen contents, indicates the diamonds were stored in the mantle at low temperatures (1060–<1100 °C) following crystallisation in the Archean. Type IaA diamonds have largely cubo-octahedral growth forms, and Type II and Type IaAB diamonds, with higher nitrogen aggregation states, mostly have octahedral morphologies. However, no correlation between these groups and their mineral inclusion compositions, C-isotopes, and N-contents rules out the possibility of unique source origins and suggests eclogitic and peridotitic diamonds experienced variable mantle thermal states. Variation in mineral inclusion chemistries in single diamonds, possible overgrowths of 13C-depleted eclogitic diamond on diamonds with peridotitic and ultradeep inclusions, and Type I ultradeep diamond with low N-aggregation is consistent with diamond growth over time in changing chemical environments.  相似文献   

18.
论述了正常钻进的条件,提出了合理岩屑规程是保证正常钻进的关键和设计钻头的主要依据之一,讨论了岩屑规程与金刚石钻头唇面工作状态、孔底表面粗糙度和岩屑粒度的关系,提出了相应的建议。  相似文献   
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EU-US (European Union-United States) interactions in relation to the regulation of genetically modified organisms (GMOs) have been examined in detail in recent years. To do this scholars have tended to focus on a small number of high profile processes, such as the formal complaint of the US to the World Trade Organisation regarding the regulation of GMOs in the Europe. It is important to analyse developments of this kind but overemphasis on them has also lead to a distorted view of the case and a failure to appreciate the significance of other, less visible, types of interaction. In this paper we focus instead on trying to understand the roles played by various EU-US transnational networks—The Transatlantic Business Dialogue, The Transatlantic Economic Partnership, The Transatlantic Consumer Dialogue, The Transatlantic Environmental Dialogue and the EU-US Consultative Forum on Biotechnology. These networks have been trying to shape the regulation of GMOs in both jurisdictions since the mid 1990s. By analysing them through a ‘governance lens’ we find that we can better understand EU-US interactions and the dynamics and influences around the regulation of GMOs. This gives us valuable insights into processes of contemporary governance.  相似文献   
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