首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1100篇
  免费   123篇
  国内免费   165篇
测绘学   88篇
大气科学   171篇
地球物理   233篇
地质学   340篇
海洋学   140篇
天文学   313篇
综合类   67篇
自然地理   36篇
  2024年   7篇
  2023年   27篇
  2022年   73篇
  2021年   53篇
  2020年   35篇
  2019年   46篇
  2018年   15篇
  2017年   22篇
  2016年   50篇
  2015年   37篇
  2014年   46篇
  2013年   31篇
  2012年   43篇
  2011年   55篇
  2010年   59篇
  2009年   71篇
  2008年   81篇
  2007年   67篇
  2006年   81篇
  2005年   80篇
  2004年   58篇
  2003年   53篇
  2002年   61篇
  2001年   42篇
  2000年   43篇
  1999年   37篇
  1998年   29篇
  1997年   13篇
  1996年   10篇
  1995年   10篇
  1994年   11篇
  1993年   9篇
  1992年   11篇
  1991年   1篇
  1990年   5篇
  1989年   2篇
  1988年   3篇
  1987年   2篇
  1986年   1篇
  1985年   2篇
  1984年   1篇
  1981年   2篇
  1976年   1篇
  1954年   1篇
  1900年   1篇
排序方式: 共有1388条查询结果,搜索用时 15 毫秒
11.
The variation in the orbital period of the W UMa type contact binary V502 Oph is analyzed. The orbital period exhibits a wavelike variation with a periodicity of 23.0 years and an amplitude of △P = 1.24×10~(-6) days superimposed on secular decrease of dP/dt = 1.68×10-7 day per year. The long-term decrease may be accompanied by the contraction of the secondary at a rate of 83 m per year and a mass transfer rate from the primary to the secondary of 4.28×10~8 M per year. The short-term oscillation may be explained by the presence of a third component. Orbital elements of the third body and its possible mass are presented.  相似文献   
12.
This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.
Luigi Marini (Corresponding author)Email:
  相似文献   
13.
以1,4—苯二酚和不同的短链脂肪酸为基本原料,经溴代、加成、形成酰卤和酰化等反应,合成了六种新的溴化脂肪酸—2,3,5,6—四溴—1,4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析,以及红外吸收光谱和氢核磁共振谱的研究,验证了化合物的结构。  相似文献   
14.
The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters.  相似文献   
15.
“大洋一号”勘查技术体系的设计与建设   总被引:1,自引:0,他引:1  
周宁 《海洋学研究》2005,23(4):61-65
介绍了"大洋一号"远洋科学考察船在近1年的改装施工后所建立的现代化船舶勘查技术体系.由于引进了世界先进的调查设备,自主研发和改造了深海浅地层岩芯钻等大型调查设备,自主设计并完成了网络信息集成系统,同时对实验室、住舱等工作、生活环境进行了改造,"大洋一号"远洋科学考察船已集成了具有高精度水下定位、全覆盖地形地貌、可视化海底取样、地球物理(重、磁、震、浅地层)、深拖(声学、光学)、成矿环境(水文、化学)和生物等专业设备的联合探测分析系统,实现了各系统的科学同步作业和信息融合,大大提高了我国海洋科学考察工作的效率和管理水平,使我国的深海探测技术和方法基本实现了与国际接轨.  相似文献   
16.
用6-DMAP抑制受精卵第二极体排放的方法诱导缢蛏三倍体的试验.结果表明:6-DMAP在100~500μmol/dm^3处理浓度范围内均可以诱导出三倍体,随着药物处理浓度和处理时间的提高,三倍体倍化率和D形幼虫畸形率有不同程度的提高,而D形幼虫孵化率会随之下降.综合来看,在30%卵子受精并出现第一极体,6-DMAP浓度为300μmol/dm^3和处理持续时间为20min时的处理组的处理效果优于其他处理组组合.  相似文献   
17.
不同生长期坛紫菜多糖中组分含量的变化   总被引:3,自引:0,他引:3  
于1990-1991年,运用^13C-NMR和化学分析方法研究南方产和移植北方养殖的不同生长发育阶段坛紫菜多糖的组分变化,结果表明,随着藻体生长发育,坛紫菜琼胶中3,6-内醚-L-半乳糖和6-OCH3-D-半乳糖的含量逐渐增加,而硫酸基的含量呈现先增加后减少的规律;北移坛紫菜琼胶中3,6-内醚-L-半乳糖的含量高于南方坛紫菜,而硫酸基和6-OCH3-D-半乳糖的含量低于南方坛紫菜。  相似文献   
18.
用m-氨基苯甲酸作原料,经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤,合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯,即;双(2,4,6-三溴苯甲酸)-2',3',5',6'-四溴-1',4'-苯二酯,2,4,6-三溴苯甲酸-2',3',4',5',6'-五溴苯酯,2,4,6-三溴苯甲酸-2',4',6'-三溴苯酯,2,4,6-三溴苯甲酸-4'-溴苯酯,2,4,6-三溴苯甲酸-4'-甲基苯酯和2,4,6-三溴苯甲酸苯酯.通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究,验证了合成产物的结构。  相似文献   
19.
以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。  相似文献   
20.
As a new method, the ultraviolet spectrum technique is applied to studying the connectivity of biode-gradable heavy oil reservoirs. The similarity of crude oils can be judged according to the extinction coefficient (E) because aromatic hydrocarbons and non-hydrocarbons have conjugated bonds and obvious absorption in the ultraviolet range, and different materials have different characteristics and additives. The relationship diagram is made in terms of the extinction coefficients (E) of the samples by taking E as the Y-axis and wavelength as the X-axis. The connectivity of oil reservoirs is estimated according to the curve positions and characteristic fingerprints of the sampies. The connectivity of part of the reservoirs in the western part of the QHD32-6 oilfield was studied with this method. The results showed that the connectivity of samples from wells F7 and F8 in the Nm-2 oil reservoir zone is good, that of samples from wells F17 and F20 in the Nm-1 oil reservoir zone also is good, and that of samples from wells F17, F19, and F20 is poor.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号