Effect of agricultural land use on the chemistry of groundwater from basaltic aquifers, Jeju Island, South Korea   总被引：2，自引：0，他引：2  

Dong-Chan Koh  Kyung-Seok Ko  Yongje Kim  Seung-Gu Lee  Ho-Wan Chang 《Hydrogeology Journal》2007,15(4):727-743

Geochemical processes were identified as controlling factors of groundwater chemistry, including chemical weathering, salinization from seawater and dry sea-salt deposition, nitrate contamination, and rainfall recharge. These geochemical processes were identified using principal component analysis of major element chemistry of groundwater from basaltic aquifers in Jeju Island, South Korea, a volcanic island with intense agricultural activities. The contribution of the geochemical processes to groundwater chemistry was quantified by a simple mass-balance approach. The geochemical effects due to seawater were considered based on Cl contributions, whereas the effects due to natural chemical weathering were based on alkalinity. Nitrogenous fertilizers, and especially the associated nitrification processes, appear to significantly affect groundwater chemistry. A strong correlation was observed between Na, Mg, Ca, SO₄ and Cl, and nitrate concentrations in groundwater. Correspondingly, the total major cations, Cl, and SO₄ in groundwater were assessed to estimate relative effect of N-fertilizer use on groundwater chemistry. Cl originates more from nitrate sources than from seawater, whereas SO₄ originates mostly from rainwater. N-fertilizer use has shown the greatest effect on groundwater chemistry, particularly when nitrate concentrations exceed 6–7 mg/L NO₃–N. Nitrate contamination significantly affects groundwater quality and 18% of groundwater samples have contamination-dominated chemistry.  相似文献   

Recent Geochemical Variation of the Hot-Spring Gases from the Tianchi Volcano, Changbai Mountains, Northeast China   总被引：1，自引：0，他引：1  

Gao Ling 《中国地震研究》2007,21(2):179-188

Recent fluid monitoring work shows that the contents of mantle-derived CO_2,He and CH_4 increased anomalously in 2002 and 2003. The 3He/4He ratio of the deep-fault-type Jinjiang hot springs increased highly anomalously in 2003, and then decreased in 2004. The 3He/4He ratio from the thermal-reservoir-type Changbaijulong hot springs increased slowly in 2003, and the increase continued in 2004. The mantle-derived He content of the He released from the Changbaijulong springs increased obviously in 2004. The anomaly of the released gases and the isotopic He was consistent with the trends of seismic activities in the Tianchi volcanic area between 2002 and 2004. The abnormal release of the Jinjiang hot springs apparently decreased after the seismic activities ceased in the second half of 2004, while the abnormal release from the Changbaijulong increased significantly after these seismic activities. It shows that the abnormal release of magmas-derived gases from the thermal-reservoir-type springs lags behind that of the deep-fault-type springs. These characteristics may be of great significance for identifying deep magmatic activity and predicting volcanic earthquakes in the future.  相似文献   

Determining magma flow in sills,dykes and laccoliths and their implications for sill emplacement mechanisms     

Ken Thomson 《Bulletin of Volcanology》2007,70(2):183-201

Three-dimensional seismic data from the Faeroe-Shetland Basin provides detailed information on the relationships between sills, dykes, laccoliths and contemporaneous volcanic activity. The data shows that sills are predominantly concave upwards, being complete or partial versions of radially or bilaterally symmetrical forms that possess flat inner saucers connected to a flat outer rim by a steeply inclined sheet. Such morphologies are only partially modified by pre-existing faults. Sills can be sourced from dykes or the steep climbing portions of deeper sills. Both sills and dykes can provide magma to overlying volcanic fissures and sills can be shown to feed shallow laccoliths. Magma flow patterns, as revealed by opacity rendering, suggest that sills propagate upwards and outwards away from the magma feeder. As an individual sill can consist of several leaves emplaced at different stratigraphic levels, and as a sill or dyke can provide magma to volcanic fissures, other sills and laccoliths, the data suggests that neutral buoyancy concepts may not provide a complete explanation for the mechanism and level of sill emplacement. Instead, the data suggests that the presence of lithological contrasts, particularly ductile horizons such as overpressured shales may permit sill formation at any level below the neutrally buoyant level. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. Ken Thomson–deceased, April 2007  相似文献   

西藏地热气体的地球化学特征及其地质意义   总被引：9，自引：3，他引：9  

赵平  谢鄂军等 《岩石学报》2002,18(4):539-550

西藏水热活动是青苦恼高原碰撞造山过程的产物，其成因类型、物质来源和时空分布与青藏高原的隆升过程密切相关，地热流体（气、液相）中携带有中上地壳乃至地幔物质的深部信息。西藏地热流体可以区分出CO2型和N2型两类气体，其中绝大多数的地热气体样品属于CO2型气体，而典型的N2型气体则较少。前者具有岩浆热源和深循环两种成因类型，后者都是深循环成因。西藏气体样品中的He含量变化范围非常宽，最高的可达到1．5％。在门士热泉，首次检测到地幔He组分，这说明西藏地壳深处有地幔物质侵位。根据He同位素组成推断，羊八井、谷露等处的地壳熔融体中约有3％的地幔组分。西藏地热气体中的N2和Ar组分主要是大气成因，CO2组分大多以海相碳酸盐岩成因为主，混有少量有机沉积物成因CO2。当Log(H2/Ar)处于－0．8－0．3的区间时，H2／Ar地热温度计可以良好地指示热储层的温度范围。实际调查表明：西藏水热活动区大多分布在斑公错－怒江链合带以南地区，高温水热活动区主要出现在雅鲁藏布缝合带和那曲－羊八井－亚东活动构造带沿线。  相似文献   

近50年火山喷发和太阳活动对我国气候影响的研究   总被引：8，自引：1，他引：8  

贾朋群  石广玉 《高原气象》2001,20(3):225-233

利用特征向量分析与时序叠加分析和谱分析相结合的方法，分析了近50a来我国地面气温和降水场中火山喷发和太阳活动的气候信号，强烈的火山喷发导致全国大部分地区降温，喷发1a多以后降温最明显，并能持续约半年。除这个主信号以外，青藏高原、东南沿海和东北地区都可能出现较为复杂的温度变化，温度变化与太阳活动之间的联系更多地反映在二者的振荡关系上。在降水场中的火山信号较弱，表现为火山喷发后的秋冬季节南方地区降水偏多。在青藏高原积雪和深层地温的变化中，没有发现火山和太阳活动信号。  相似文献   

Magmatic gas scrubbing: implications for volcano monitoring   总被引：1，自引：0，他引：1  

R. B. Symonds  T. M. Gerlach  M. H. Reed 《Journal of Volcanology and Geothermal Research》2001,108(1-4)

Despite the abundance of SO_2(g) in magmatic gases, precursory increases in magmatic SO_2(g) are not always observed prior to volcanic eruption, probably because many terrestrial volcanoes contain abundant groundwater or surface water that scrubs magmatic gases until a dry pathway to the atmosphere is established. To better understand scrubbing and its implications for volcano monitoring, we model thermochemically the reaction of magmatic gases with water. First, we inject a 915°C magmatic gas from Merapi volcano into 25°C air-saturated water (ASW) over a wide range of gas/water mass ratios from 0.0002 to 100 and at a total pressure of 0.1 MPa. Then we model closed-system cooling of the magmatic gas, magmatic gas-ASW mixing at 5.0 MPa, runs with varied temperature and composition of the ASW, a case with a wide range of magmatic–gas compositions, and a reaction of a magmatic gas–ASW mixture with rock. The modeling predicts gas and water compositions, and, in one case, alteration assemblages for a wide range of scrubbing conditions; these results can be compared directly with samples from degassing volcanoes. The modeling suggests that CO_2(g) is the main species to monitor when scrubbing exists; another candidate is H₂S_(g), but it can be affected by reactions with aqueous ferrous iron. In contrast, scrubbing by water will prevent significant SO_2(g) and most HCl_(g) emissions until dry pathways are established, except for moderate HCl_(g) degassing from pH<0.5 hydrothermal waters. Furthermore, it appears that scrubbing will prevent much, if any, SO_2(g) degassing from long-resident boiling hydrothermal systems. Several processes can also decrease or increase H_2(g) emissions during scrubbing making H_2(g) a poor choice to detect changes in magma degassing.We applied the model results to interpret field observations and emission rate data from four eruptions: (1) Crater Peak on Mount Spurr (1992) where, except for a short post-eruptive period, scrubbing appears to have drastically diminished pre-, inter-, and post-eruptive SO_2(g) emissions, but had much less impact on CO_2(g) emissions. (2) Mount St. Helens where scrubbing of SO_2(g) was important prior to and three weeks after the 18 May 1980 eruption. Scrubbing was also active during a period of unrest in the summer of 1998. (3) Mount Pinatubo where early drying out prevented SO_2(g) scrubbing before the climactic 15 June 1991 eruption. (4) The ongoing eruption at Popocatépetl in an arid region of Mexico where there is little evidence of scrubbing.In most eruptive cycles, the impact of scrubbing will be greater during pre- and post-eruptive periods than during the main eruptive and intense passive degassing stages. Therefore, we recommend monitoring the following gases: CO_2(g) and H₂S_(g) in precursory stages; CO_2(g), H₂S_(g), SO_2(g), HCl_(g), and HF_(g) in eruptive and intense passive degassing stages; and CO_2(g) and H₂S_(g) again in the declining stages. CO_2(g) is clearly the main candidate for early emission rate monitoring, although significant early increases in the intensity and geographic distribution of H₂S_(g) emissions should be taken as an important sign of volcanic unrest and a potential precursor. Owing to the difficulty of extracting SO_2(g) from hydrothermal waters, the emergence of >100 t/d (tons per day) of SO_2(g) in addition to CO_2(g) and H₂S_(g) should be taken as a criterion of magma intrusion. Finally, the modeling suggests that the interpretation of gas-ratio data requires a case-by-case evaluation since ratio changes can often be produced by several mechanisms; nevertheless, several gas ratios may provide useful indices for monitoring the drying out of gas pathways.  相似文献   

火山地区二维自然电位异常反演   总被引：2，自引：0，他引：2       下载免费PDF全文

张贵宾 Aubert  M 《地球物理学报》1996,39(6):835-844

将线性反演理论与正则化法相结合，提出一个火山地区二维自然电位（ＳＰ）异常反演方法．地下岩浆活动（对流体）是引起自电异常的极化源，反演的目的是计算地下视极化强度分布和极化源中心位置．可以通过用已知的各种资料改变地下极化源区域（简称源区）的方式来进行多次反演，以便获得一个比较合理的地下视极化强度分布模型．最后，分别给出意大利和墨西哥的两个火山地区的自然电位异常分析结果．  相似文献   

Pyroclastic flows and surges over water: an example from the 1883 Krakatau eruption     

S. Carey  H. Sigurdsson  C. Mandeville  S. Bronto 《Bulletin of Volcanology》1996,57(7):493-511

Pyroclastic deposits from the 1883 eruption of Krakatau are described from areas northeast of the volcano on the islands of Sebesi, Sebuku, and Lagoendi, and the southeast coast of Sumatra. Massive and poorly stratified units formed predominantly from pyroclastic flows and surges that traveled over the sea for distances up to 80 km. Granulometric and lithologic characteristics of the deposits indicate that they represent the complement of proximal subaerial and submarine pyroclastic flow deposits laid down on and close to the Krakatau islands. The distal deposits exhibit a decrease in sorting coefficient, median grain size, and thickness with increasing distance from Krakatau. Crystal fractionation is consistent with the distal facies being derived from the upper part of gravitationally segregated pyroclastic flows in which the relative amount of crystal enrichment and abundance of dense lithic clasts diminished upwards. The deposits are correlated to a major pyroclastic flow phase that occurred on the morning of 27 August at approximately 10 a.m. Energetic flows spread out away from the volcano at speeds in excess of 100 km/h and traveled up to 80 km from source. The flows retained temperatures high enough to burn victims on the SW coast of Sumatra. Historical accounts from ships in the Sunda Straits constrain the area affected by the flows to a minimum of 4x10³ km². At the distal edge of this area the flows were relatively dilute and turbulent, yet carried enough material to deposit several tens of centimeters of tephra. The great mobility of the Krakatau flows from the 10 a.m. activity may be the result of enhanced runout over the sea. It is proposed that the generation of steam at the flow/seawater interface may have led to a reduction in the sedimentation of particles and consequently a delay in the time before the flows ceased lateral motion and became buoyantly convective. The buoyant distal edge of these ash-and steam-laden clouds lifted off into the atmosphere, leading to cooling, condensation, and mud rain.  相似文献   

五大连池火山构造地震空间分布及其构造含义   总被引：3，自引：0，他引：3  

张凤鸣  张守国 《东北地震研究》1996,12(4):17-22

在对五大连池地震台１９８３年以来观测到的五大连池火山区的地震记录复核的基础上，测定了火山构造地震的空间分布状态。研究结果表明该地区地震活动均为壳内地震。受火山构造环境影响，地震活动存在着外围边缘强，震源深度分布深；内部弱，震源深度分布浅的差异。火山区内部地震深度分布优势在５ｋｍ—８ｋｍ，有３个地震分布密集区，震中分布呈明显的沿火山构造断层成带分布特性。在地震条带交汇处，震源深度起伏变化大，是火山构造活动强烈部位  相似文献   

火山气溶胶的辐射影响   总被引：2，自引：1，他引：2  

汪宏七  赵高祥 《大气科学》1992,16(6):755-760

本文应用辐射传输计算研究了火山气溶胶,特别是大的火山爆发后短时期及火山周围地区内的火山气溶胶,对到达地面的向下的总的太阳辐射通量、行星反照率及大气加热率的可能影响.  相似文献