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浩婷  王曦  周颜  吴燕 《岩土力学》2015,36(11):3187-3192
采用自主改装的变压头黏土渗透仪,模拟疏浚淤泥脱水过程中水分在淤泥颗粒多孔介质中的迁移运动过程,通过测定疏浚淤泥脱水过程中渗透系数与过滤常数、渗水量与滤液量、泥饼含水率与孔隙率,探究了负载压力为100 kPa时,不同负载方式(负载时间及负载压力梯度变化)对疏浚淤泥脱水过程中过滤和渗流规律的影响。研究发现:负载下的过滤和渗流同时进行,负载1 h期间,前期0~40 min内过滤占主导地位,后期40~60 min内渗流起关键作用。负载压力梯度由原来1 h内间隔变化1次,变为以20 kPa为梯度递增变化5次,随着压力变化梯度减小,渗透系数、过滤常数增加,淤泥脱水性能得到较明显的改善,并且前期负载压力越小,脱水效果越好。  相似文献   
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In this work, the treatment of actual agro‐industrial wastewaters (IWW) by a UV/H2O2 process has been investigated. The aqueous wastes were received from industrial olive oil mills and then treated by laboratory scale physicochemical methods, i. e., coagulation using ferrous and aluminum sulfate, decantation, filtration and adsorption on activated carbon. These wastes are brown colored effluents and have a residual chemical oxygen demand (COD) in the range of 1800 to 3500 mgO2 L–1, which cannot be further eliminated with physicochemical processes. The UV/H2O2 treatments were carried out under monochromatic irradiation at 254 nm using a thermostated reactor equipped with a mercury vapor lamp located in an axial position. The effects of initial H2O2 concentration, initial COD, pH and temperature have been studied in order to determine the optimum conditions for maximum color and COD removals. The experimental results reveal the suitability of the UV/H2O2 process for both removal of high levels of COD and effectively decolorizing the solution. In particular, 95% of color removal and 90% of COD removal were obtained under conditions of pH = 5 and 32°C using 2.75 g H2O2 g–1 COD L–1 during 6 h of UV‐irradiation. The treatment is unaffected by pH over the range 2 to 9. In addition, the COD removal is improved by increasing the temperature, whereas the color removal has not been affected by this parameter. The results show that the hydroxyl radicals generated from the catalytic decomposition of H2O2 by UV‐irradiation of the solution could be successfully used to mineralize the organics contained in IWW. The mineralization of the organics seems to occur in three main sequential steps: the first is the rapid decomposition of tannins leading to aromatic compounds, which are confirmed by the decolorization of the IWW; the second step corresponds to the oxidation of aromatics leading to aliphatic intermediates, which occurs by the cleavage of an aromatic ring, and is established by the removal of aromatics, and the final step is the slow oxidation of the aliphatic intermediates, which is measured by the COD removal.  相似文献   
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The present work investigated the biosorption of nickel from synthetic and electroplating industrial effluents using a green marine algae Ulva reticulata. Preliminary batch results imply that pH 4.5 was optimum for nickel uptake and the isotherm experiments conducted at this pH condition indicated that U. reticulata can biosorb 62.3 mg g–1 nickel ions from synthetic solutions, according to the Langmuir model. Desorption was effective and practical using 0.1 M CaCl2 (pH 2.5, HCl) and the biomass was regenerated and reused for three cycles. Continuous biosorption experiments were performed in an upflow packed column (2 cm I.D and 35 cm height). Among the two electroplating effluents used, effluent‐1 is characterized by excess co‐ions and high nickel ion content. This influenced the column nickel uptake with U. reticulata exhibiting 52.1 mg g–1 in the case of effluent‐1 compared to 56.5 mg g–1 in the case of synthetic solution. On the other hand U. reticulata performed well in effluent‐2 with uptakes of 53.3 and 54.3 mg g–1 for effluent‐2 and synthetic solution, respectively. Mathematical modeling of column experimental data was performed using nonlinear forms of the Thomas‐ and modified dose‐response models, with the latter able to simulate breakthrough curves with high correlation coefficients.  相似文献   
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