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11.
以双功能褐藻胶裂解酶 (Pseudoalteromonas sp.strain No. 2 72 )分别降解均聚古罗糖醛酸(PG)和均聚甘露糖醛酸 (PM) ,经 Bio- Gel- P6和 POROS- HQ2 0分离得到 2种三糖纯品 ,经 ESI- MS,1 H- NMR,1 3 C- NMR,1 H- 1 H COSY,1 H- 1 3 C HMQC确定其结构为 Δ4,5-古罗糖醛酸 - α(1→ 4 ) - L-古罗糖醛酸 -α(1→ 4 ) - L -古罗糖醛酸 (简写为Δ GG)和Δ4,5-甘露糖醛酸 -β (1→ 4 ) - D-甘露糖醛酸 -β (1→ 4 ) - D-甘露糖醛酸 (ΔMM) ,为进一步从事构效关系研究提供结构信息。 相似文献
12.
26S蛋白酶体是真核生物中一种具有ATP依赖性的蛋白酶复合体,主要通过泛肽途径选择性降解细胞内与代谢调控、细胞周期有关的功能蛋白及异常蛋白,参与多种细胞活动的调控过程。26S蛋白酶体由具有催化活性的20S亚复合体和一个具有调节作用的19S亚复合体组成,其中19S亚复合体中的ATP酶亚基是调节26S蛋白酶体活性的重要组件。本通过简并引物PCR手段,从软体动物合浦珠母贝(Pinctada fucata)中扩增到参与构成19S亚复合体的S4和S7(MSS1)两个亚基的基因片段。这两个基因片段所编码的ATP酶组件包含有Gx4GKT,DEID,SAT和H/QRxGRxxR等26S蛋白酶体ATP酶亚基的共同功能基序。这是首次在软体动物中报道26S蛋白酶体的ATP酶亚基基因序列,为研究软体动物中26S蛋白酶体的结构与功能奠定了分子基础。 相似文献
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Elizabeth B. Kujawinski Rossana Del Vecchio Neil V. Blough Geoffrey C. Klein Alan G. Marshall 《Marine Chemistry》2004,92(1-4):23
Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems. 相似文献
14.
GPS、GLONASS、GALILEO三大系统间时间系统以及坐标系统的转换 总被引:2,自引:0,他引:2
在当今的三大定位导航系统中,它们各自用着自己的时间标准和坐标框架,这使得我们在进行多样数据处理与数据融合时很不方便。这就需要我们对此三个系统的时间系统以及坐标系统进行有效的转换,本文就是基于这样的需求,详细介绍并分析了此三大系统中各自的时间系统与坐标系统,通过对多方资料的综合、推证与计算,综合得出GPS、GLONASS以及GALILEO三大系统间的时间转换方法及坐标转换模型与公式。而且,这些转换公式与方法所得出的结果是完全能满足绝大多数用户的精度需求的。 相似文献
15.
I. D. L. Foster T. M. Mighall H. Proffitt D. E. Walling P. N. Owens 《Journal of Paleolimnology》2006,35(4):881-895
We present 137Cs profiles for three low lying coastal lagoons in Southwest England that show a decline in activity with sediment depth.
137Cs inventories are lower than expected by comparison with local reference inventories despite the fact that sampling was undertaken
in the deep-water zone of each lake where sediment and 137Cs focusing would be expected. At all three locations, lake sediment 7Be and unsupported 210Pb (210Pbun) inventories are not significantly lower than the local reference inventory. 137Cs inventories in the study cores range from 38 to 95% of local reference inventories. The standing water level and mud: water
interface at two sites are below maximum tide level and, at all three sites, salinity increases significantly in the water
columns between low and high tide and in the pore waters of the underlying sediments. We suggest that the difference in hydrostatic
pressure between sea level and standing water levels in the lagoons forces salt water up through the sediment column and that
monovalent cations (especially Na+ and K+) replace 137Cs on exchange sites leading to the upward migration and loss of 137Cs. Rising sea levels may therefore contribute to remobilisation and release of 137Cs to the aquatic environment from the sediments of coastal lagoons. 相似文献
16.
《Journal of Geochemical Exploration》2002,76(3)
Many studies have shown systematic correlations between the composition of plutons worldwide and the metal content of associated skarns. This is the first report of similar correlations between the composition of Çelebi granitoid and skarns of the Çelebi district in Central Anatolia, Turkey. The Çelebi district is well known for its polymetallic Fe–W and Cu vein ores. These are hosted by calcic skarn zones. Both exoskarns (pyroxene–garnet) and endoskarns (epidote–pyroxene) occur in the district formed mainly along the granitoid contacts and along the fractures within the marble. Based on mineralogy, petrology and geochemistry, two different igneous rocks were recognized in the Çelebi granitoid, referred to as leucocratic (felsic) and mesocratic (intermediate) Çelebi granitoid. The leucocratic Çelebi occurs as dominant rock type, and is classified as granite. The mesocratic Çelebi is not widespread and is classified as adamellite, tonalite, quartz monzonite and quartz monzodiorite. The mesocratic Çelebi has I-type characteristics, and have subalkaline, calc-alkaline and metaluminous characteristics like most worldwide skarn granitoids.A post-collisional tectonic setting is proposed on the basis of field evidence, the relative timing of intrusions with respect to metamorphic and obducted ophiolitic rocks and trace element geochemistry. The high abundance of La and Ce and the enrichment of V in mafic components suggest that Çelebi granitoids are formed by partial melting of mantle rocks, but have been contaminated by interaction with continental crust involving possible magma mixing processes (i.e. mixing of coexisting felsic and mafic magmas). In the district, the mesocratic type and mafic microgranular enclaves (MME) mainly within leucocratic type represent a mafic underplating magma that was mixed with and/or injected into felsic magma of the leucocratic type.The present study shows that Fe mineralization is associated with mesocratic Çelebi type, whereas W mineralization is associated with leucocratic type. Mesocratic Çelebi granitoid is significantly different from the worldwide average of plutons associated with Fe skarns. In particular, MgO vs. SiO2, FeOt+CaO+Na2O/K2O vs. SiO2, Fe2O3/Fe2O3+FeO vs. SiO2 and V vs. Ni vary from typical values (are lower than values typical for plutons associated with Fe skarns) for plutons associated with Fe skarns. Instead, it resembles the geochemical characteristics of plutons associated with worldwide Cu and possibly Au skarns. This suggests new exploration possibilities for copper and gold in the Çelebi district. 相似文献
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建立了HF—HN03密封酸溶以及Na2O2熔融处理样品,乙醇增强灵敏度,电感耦合等离子体质谱直接测定地质样品中微量和超痕量碲的方法。样品溶液中加入乙醇(φ=4%),在0.85L/min的载气流速下,碲信号可增强2.5倍以上。碲的方法检出限(100,DF=1000)为0.02μg/g。用土壤和水系沉积物国家一级标准物质验证了方法的准确度,标准物质的绝大多数分析结果与标准值的误差在允许范围内。分析了大洋多金属结核样品及深海沉积物样品中的微量碲,结果与其他方法相符,精密度试验RSD(n=3)<10%。 相似文献
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