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151.
The development and first tests of a novel method for the direct, sensitive, selective, and fast detection of gaseous nitric acid in air are described. The detection method is based on the laser-photolysis fragment-fluorescence (LPFF) method using 193 nm (ArF) laser light. The photolysis process yielding OH fluorescence has been thoroughly investigated. Up to now, the method has been found to be practically free of interferences. The mixing ratio for nitric acid is measured on-line with a detection limit of about 0.1 ppbv for an accumulation time of the signal of 10–15 min. A number of tests and field measurements were performed to demonstrate the feasibility and limits of the described detection method. 相似文献
152.
乳砷铅铜石的发现与研究 总被引:2,自引:0,他引:2
乳砷铅铜石发现于1984年,在广西德保和平桂等矿区的硫化物型矿床的氧化带铁帽中.对该矿物的物理、化学和X射线粉晶分析、红外光谱分析以及差热分析等方面进行了测试研究,其结果与国外已知数据基本一致.矿物呈淡黄绿或深绿色,细粒状或葡萄状,硬度H=4,比重D=5.35,透明,二轴晶负光性,2V大,Ng=1.9817,Nm=1.9703,NP=1.9584.化学成分为PbO 35.19,CuO 30.64,As_2O_5 30.09,FeO 0.28,ZnO 0.05,H_2O 4.10(%).相应的化学分子式为Cu_(2.96)Pb_(1.21)(AsO_4)_(2.01)(OH)_(2.31)·0.59H_2O.X射线粉晶数据与JCPDS26~1410卡基本一政,衍射强线为3.14(10),3.24(8),2.92(8),2.55(8),2.74(7),2.49(7),2.27(7),4.51(6),4.94(5),2.66(4),1.902(4),1.817(4).计算的晶胞参数为a=10.236(?).b=5.904(?),C=14.213(?),β=106.39°,z=4,单斜晶系;空间群为A2/a.红外吸收光谱波数为3440、1640、870、820、775、465和1100、590、557(cm~(-1));差热分析吸收峰为580、773、812、889、898(℃). 相似文献
153.
154.
155.
A. Waltrop S. K. Mitra A. I. Flossmann H. R. Pruppacher 《Journal of Atmospheric Chemistry》1991,12(1):1-17
An experimental study involving the Mainz vertical wind tunnel is described where the rate of SO2 removed from the air by freely suspended water drops was measured for SO2 concentrations in the gas phase ranging between 50 and 500 ppb, and for various H2O2 concentrations in the liquid phase. In a first set of experiments, the pH inside the SO2 absorbing drops was monitored by means of colour pH indicators added to the drops. In a second set of experiments, the amount of SO2 scavenged by the drops was determined as sulfate by an ionchromatograph after the drops had been removed from the vertical air stream of the wind tunnel after various times of exposure to SO2. The results of our experimental study were compared with the theoretical gas diffusion model of Walcek and Pruppacher which was reformulated for the case of SO2 concentrations in the ppbv(v) range for which the main resistance to diffusion lies in the gas phase surrounding the drop. Excellent agreement between experiment and theory was obtained. Encouraged by this agreement, the theory was used to investigate the rate of sulfate production inside a drop as a function of pH. The sulfate production rate, which includes transport and oxidation, was compared with the production rate based on bulk equilibrium, as cited in the literature. 相似文献
156.
William R. Stockwell 《Journal of Atmospheric Chemistry》1994,19(3):317-329
The rates and mechanisms of both gas and liquid phase reactions for the oxidation of sulfur dioxide play an important role in the production of atmospheric acids and aerosol particles. Rhodeet al. (1981) concluded that sulfate production rates were highly non-linear functions of sulfur dioxide emission rates. Their modelling study used an HO
x
termination mechanism for the HO—SO2 reaction in the gas-phase. Stockwell and Calvert (1983) determined that one of the products of the overall reaction of HO with sulfur dioxide was an HO2 radical. The National Research Council (1983) using a version of the Rhodeet al. (1981) model modified to include HO2 production from the HO—SO2 reaction concluded that sulfate production becomes much more linear with respect to reductions in sulfur dioxide emissions. However, the cause of this increased linearity was not explained by the National Research Council report. It is demonstrated that the increased linearity is due to the coupling of gas-phases and aqueous phase chemistry. The gas-phase sulfur dioxide oxidation mechanism has a very significant effect on hydrogen perodide production rates. 相似文献
157.
158.
A South Australian Tertiary brown coal is fractionated into humic acid and kerogen fractions. These related samples are then subjected to a number of different analytical techniques including infrared and13C-Nuclear Magnetic Resonance spectroscopies and pertrifluoroacetic acid oxidation. Structural conclusions are drawn from an integrated consideration of the data. Brown coal aliphatic structure is concentrated in the kerogen and the solvent soluble polar acid fractions. The humic acids are the most aromatic and contain a high degree of hydrogen bonding. Only very minor amounts of long polymethylene chain structures are observed in the humic acids, in complete contrast to the kerogen fraction. Different organic detrital origins are proposed for the coal fractions. 相似文献
159.
The concentrations of lipids were determined in atmospheric particle, gas and rain samples collected from the tropical North Pacific to assess lipid sources, transport mechanisms and fluxes to the ocean surface. Four lipid compound classes (aliphatic hydrocarbons, fatty alcohols, fatty acid esters, and salts) all unequivocally show a terrestrial vascular plant source. These aerosol lipids originate from wind erosion of Asian and American soils and direct emission from vegetation. The major fluxes result from rain rather than dry deposition. These fluxes are large enough to have a major potential impact on the inventory of terrestrially derived lipid material found in deep-sea sediments. This has been showm for n-alkanes, fatty alcohols, fatty acids, total lipids and for organic carbon. By comparing atmospheric and sediment trap fluxes with sediment accumulation rates, it is suggested that some biogenic terrestrial material is more protected from degradation than marine-derived material. 相似文献
160.
长春市北西或北北西向扭性断裂或断裂带是客观存在,它对长春市深部地下水循环与循存起控制作用,是深部基岩裂隙水的主要导水通道,且大都为富水带。原北东向压扭性断裂或断裂带起阻水作用,二者相得益彰。笔者于长春北郊贫水区,利用这一新理论,在水文地质调查基础上,结合多种水文物探手段布孔凿井,打出一口水量丰富的优质矿泉水井,进而验证了北西向富水说,了箕市深部地下水赋存规律的新认识,此说不但对长春市供水有实际意义 相似文献