The nature and distribution of fluids during amphibolite facies metamorphism, Naxos (Greece)   总被引：1，自引：0，他引：1  

I. S. BUICK  T. J. B. HOLLAND 《Journal of Metamorphic Geology》1991,9(3):301-314

On the basis of fluid inclusion evidence, pervasive influx of deep-seated CO₂-rich fluids has been invoked to account for mid- to upper amphibolite facies (M2_B) metamorphism on the island of Naxos (Cyclades, Greece). In this paper, mineral devolatilization and melt equilibria are used to constrain the composition of both syn- and post-peak-M2_B fluids in the deepest exposed levels of the metamorphic complex. The results indicate that peak-M2_B fluids were spatially and compositionally heterogeneous throughout the high-grade core of the complex, whereas post-peak-M2_B fluids were generally water-rich. The observed heterogeneities in syn-M2_B fluid composition are inconsistent with pervasive CO₂-flushing models invoked by previous workers on the basis of fluid inclusion evidence. It is likely that few CO₂-rich fluid inclusions on Naxos preserve fluids trapped under peak metamorphic conditions. It is suggested that many of these inclusions have behaved as chemically open systems during the intense deformation that accompanied the uplift of the metamorphic complex. A similar process may explain the occurrence of some CO₂-rich fluid inclusions in granulite facies rocks.  相似文献   

The Role of Pressure in Producing Compositional Diversity in Intraplate Basaltic Magmas   总被引：3，自引：0，他引：3  

Whitaker  M. L.; Nekvasil  H.; Lindsley  D. H.; Difrancesco  N. J. 《Journal of Petrology》2007,48(2):365-393

Basaltic magmas found in intraplate suites appear to followmore than one differentiation trend. Many ocean island suitesfollow the ocean island tholeiitic trend, with the basalts differentiatingfrom olivine tholeiite through basaltic andesite, andesite,and dacite to sodic rhyolite. Many continental intraplate magmaticregimes, such as those of the Snake River Plain and the plutonicsequences associated with massif anorthosites, follow the potassicsilica-saturated alkalic trend, in which basalt differentiatesfrom olivine tholeiite through ferrobasalt (jotunite or ferrodiorite),Fe-rich intermediate rocks (trachybasalt or monzonite), andtrachyte (syenite) to potassic rhyolites and granites. Crystallizationexperiments on an olivine tholeiite from the Snake River Plainshow that the basaltic portions of the ocean island tholeiitictrend and the potassic silica-saturated alkalic trend (whichleads to strong alkali, P, Ti, and Fe enrichment and silicadepletion) can arise from the same ‘dry’ tholeiiticparental magma. These compositional differences are inducedby changes in phase equilibria as a function of pressure, withthe ocean island tholeiitic series arising from crystal–liquiddifferentiation at low pressure and the potassic silica-saturatedalkalic series arising via differentiation at elevated pressures. KEY WORDS: tholeiite differentiation; experimental petrology; phase equilibria; ferrodiorite; ferrobasalt  相似文献   

Petrogenesis of impure dolomitic marble from the Dabie Mountains, central China   总被引：2，自引：0，他引：2  

S. Omori  J. G. Liou  R. Y. Zhang  & Y. Ogasawara 《Island Arc》1998,7(1-2):98-114

Petrogeneses of impure dolomitic marble and enclosed eclogite from the Xinyan area, Dabie ultrahigh-pressure (UHP) metamorphic terrane, central China were investigated with a special focus on fluid characteristics. Identified carbonate-bearing UHP assemblages are Dol + Coe ± Arg (or Mgs) ± Ap, Dol + Omp ± Coe ± Ap ± Arg (or Mgs), Phen + Omp + Coe + Dol ± Arg and Dol + Coe + Phen + Rt ± Omp ± Arg ± Ap. Retrograde assemblages are characterized by symplectitic replacement of Tr–Ab and Di–Ab after omphacite, and Phl–Pl symplectite after phengite. The P–T conditions of UHP metamorphism were estimated to be P > 2.7 GPa and T > 670 °C by the occurrence of coesite inclusions in garnet in enclosed eclogite and garnet–clinopyroxene geothermometer. The P–T conditions of initial amphibolitization were estimated to be 620 < T < 670 °C and 1.1 < P < 1.3 GPa by calcite–dolomite solvus thermometer and mineral parageneses. Phase relations in P–T– X CO ₂ space in the systems NaAl–CMSCH and KCMASCH were calculated in order to constrain fluid compositions. Compositions and parageneses of UHP-stage minerals suggest the presence of fluid in UHP and exhumation stages. Occurrence of retrograde low-variance assemblages indicates that fluid composition during amphibolitization was buffered. A metastable persistence of magnesite and very restricted occurrence of calcite, magnesite and dolomite suggest a low fluid content in the post-amphibolitization stage.  相似文献   

大气动力学方程组的定性理论及其应用   总被引：9，自引：2，他引：7  

李建平  丑纪范 《大气科学》1998,22(4):443-453

基于完整的湿大气动力学方程组,利用无穷维动力系统的新理论和新方法,系统讨论了强迫耗散的非线性大气系统的定性理论及其应用。将完整的强迫耗散非线性湿大气动力学方程组化为Hilbert空间中一个等价的算子方程,研究了算子的性质及其物理意义,在此基础上得到湿大气系统全局吸引子的存在性定理,揭示出系统向外源的非线性适应特征,并把结果推广到有地形动力作用和非定常外源强迫的情形。同时探讨了大气方程组惯性流形的存在,大气多平衡态产生的根源以及强迫、耗散和非线性对系统解的渐近行为的影响。在理论结果的基础上,提出强迫耗散的非线性动力系统中存在三类时间边界层、方程组简化准则、分解算法的算子约束原则以及支撑吸引子基底的少数自由度的构造方法,探讨了理论在非线性发展方程差分格式的设计和计算稳定性分析、多平衡态的数值分析、数值模式延伸预报的改进、短期气候预测以及一类中尺度系统分析与预测中的应用,指出描述长期过程动力学模式的必备条件,给出初值与模式相协调的合理解释。最后,对今后的研究方向作了展望。  相似文献   

Constraining peak P–T conditions in UHP eclogites: calculated phase equilibria in kyanite‐ and phengite‐bearing eclogite of the Tromsø Nappe,Norway     

M. JANÁK  E. J. K. RAVNA  K. KULLERUD 《Journal of Metamorphic Geology》2012,30(4):377-396

Kyanite‐ and phengite‐bearing eclogites have better potential to constrain the peak metamorphic P–T conditions from phase equilibria between garnet + omphacite + kyanite + phengite + quartz/coesite than common, mostly bimineralic (garnet + omphacite) eclogites, as exemplified by this study. Textural relationships, conventional geothermobarometry and thermodynamic modelling have been used to constrain the metamorphic evolution of the Tromsdalstind eclogite from the Tromsø Nappe, one of the biggest exposures of eclogite in the Scandinavian Caledonides. The phase relationships demonstrate that the rock progressively dehydrated, resulting in breakdown of amphibole and zoisite at increasing pressure. The peak‐pressure mineral assemblage was garnet + omphacite + kyanite + phengite + coesite, inferred from polycrystalline quartz included in radially fractured omphacite. This omphacite, with up to 37 mol.% of jadeite and 3% of the Ca‐Eskola component, contains oriented rods of silica composition. Garnet shows higher grossular (X_Grs = 0.25–0.29), but lower pyrope‐content (X_Prp = 0. 37–0.39) in the core than the rim, while phengite contains up to 3.5 Si pfu. The compositional isopleths for garnet core, phengite and omphacite constrain the P–T conditions to 3.2–3.5 GPa and 720–800 °C, in good agreement with the results obtained from conventional geothermobarometry (3.2–3.5 GPa & 730–780 °C). Peak‐pressure assemblage is variably overprinted by symplectites of diopside + plagioclase after omphacite, biotite and plagioclase after phengite, and sapphirine + spinel + corundum + plagioclase after kyanite. Exhumation from ultrahigh‐pressure (UHP) conditions to 1.3–1.5 GPa at 740–770 °C is constrained by the garnet rim (X_Ca^Grt = 0.18–0.21) and symplectite clinopyroxene (X_Na^Cpx = 0.13–0.21), and to 0.5–0.7 GPa at 700–800 °C by sapphirine (X_Mg = 0.86–0.87) and spinel (X_Mg = 0.60–0.62) compositional isopleths. UHP metamorphism in the Tromsø Nappe is more widespread than previously known. Available data suggest that UHP eclogites were uplifted to lower crustal levels rapidly, within a short time interval (452–449 Ma) prior to the Scandian collision between Laurentia and Baltica. The Tromsø Nappe as the highest tectonic unit of the North Norwegian Caledonides is considered to be of Laurentian origin and UHP metamorphism could have resulted from subduction along the Laurentian continental margin. An alternative is that the Tromsø Nappe belonged to a continental margin of Baltica, which had already been subducted before the terminal Scandian collision, and was emplaced as an out‐of‐sequence thrust during the Scandian lateral transport of nappes.  相似文献   

Chloritoid–glaucophane schist in the north Qilian orogen, NW China: phase equilibria and P–T path from garnet zonation     

C. J. WEI  S. G. SONG 《Journal of Metamorphic Geology》2008,26(3):301-316

Chloritoid–glaucophane‐bearing rocks are widespread in the high‐pressure belt of the north Qilian orogen, NW China. They are interbedded and cofacial with felsic schists originated from greywackes, mafic garnet blueschists and low‐T eclogites. Two representative chloritoid–glaucophane‐bearing assemblages are chloritoid + glaucophane + garnet + talc + quartz (sample Q5‐49) and chloritoid + glaucophane + garnet + phengite + epidote + quartz (sample Q5‐12). Garnet in sample Q5‐49 is coarse‐, medium‐ and fine‐grained and shows two types of zonation patterns. In pattern I, X_grs is constant as X_py rises, and in pattern II X_grs decreases as X_py rises. Phase equilibrium modelling in the NC(K)MnFMASH system with Thermocalc 3.25 indicates that pattern I can be formed during progressive metamorphism in lawsonite‐stable assemblages, while pattern II zonation can be formed with further heating after lawsonite has been consumed. Garnet growth in Q5‐49 is consistent with a continuous progressive metamorphic process from ～14.5 kbar at 470 °C to ～22.5 kbar at 560 °C. Garnet in sample Q5‐12 develops with pattern I zonation, which is consistent with a progressive metamorphic process from ～21 kbar at 540 °C to ～23.5 kbar at 580 °C with lawsonite present in the whole garnet growth. The latter sample shows the highest P–T conditions of the reported chloritoid–glaucophane‐bearing assemblages. Phase equilibrium calculation in the NCKFMASH system with a recent mixing model of amphibole indicates that chloritoid + glaucophane paragenesis does not have a low‐pressure limit of 18–19 kbar as previously suggested, but has a much larger pressure range from 7–8 to 27–30 kbar, with the low‐pressure part being within the stability field of albite.  相似文献   

The Metastable Phase Equilibria of the MeX-MgCl_2-H_2O Systems     

ZENG Ying  YU Xudong  MU Pengtao  FENG Shan 《《地质学报》英文版》2014,88(Z1):398-398

正1 Introduction The Pingluoba brine,which characterized as high concentration with sodium,potassium,boron,lithium,and rubidium,possess great development value.The main composition of the brine can be summarized to the  相似文献   

Phase Equilibria Constraints on the Chemical and Physical Evolution of the Campanian Ignimbrite   总被引：5，自引：1，他引：4  

Fowler  Sarah J.; Spera  Frank J.; Bohrson  Wendy A.; Belkin  Harvey E.; De Vivo  Benedetto 《Journal of Petrology》2007,48(3):459-493

The Campanian Ignimbrite is a > 200 km³ trachyte–phonolitepyroclastic deposit that erupted at 39·3 ± 0·1ka within the Campi Flegrei west of Naples, Italy. Here we testthe hypothesis that Campanian Ignimbrite magma was derived byisobaric crystal fractionation of a parental basaltic trachyandesiticmelt that reacted and came into local equilibrium with smallamounts (5–10 wt%) of crustal rock (skarns and foid-syenites)during crystallization. Comparison of observed crystal and magmacompositions with results of phase equilibria assimilation–fractionationsimulations (MELTS) is generally very good. Oxygen fugacitywas approximately buffered along QFM + 1 (where QFM is the quartz–fayalite–magnetitebuffer) during isobaric fractionation at 0·15 GPa ( 6km depth). The parental melt, reconstructed from melt inclusionand host clinopyroxene compositions, is found to be basaltictrachyandesite liquid (51·1 wt% SiO₂, 9·3 wt%MgO, 3 wt% H₂O). A significant feature of phase equilibria simulationsis the existence of a pseudo-invariant temperature, 883 °C,at which the fraction of melt remaining in the system decreasesabruptly from 0·5 to < 0·1. Crystallizationat the pseudo-invariant point leads to abrupt changes in thecomposition, properties (density, dissolved water content),and physical state (viscosity, volume fraction fluid) of meltand magma. A dramatic decrease in melt viscosity (from 1700Pa s to 200 Pa s), coupled with a change in the volume fractionof water in magma (from 0·1 to 0·8) and a dramaticdecrease in melt and magma density acted as a destabilizingeruption trigger. Thermal models suggest a timescale of 200kyr from the beginning of fractionation until eruption, leadingto an apparent rate of evolved magma generation of about 10^–3km³/year. In situ crystallization and crystal settling in density-stratifiedregions, as well as in convectively mixed, less evolved subjacentmagma, operate rapidly enough to match this apparent volumetricrate of evolved magma production. KEY WORDS: assimilation; Campanian Ignimbrite; fractional crystallization; magma dynamics; phase equilibria  相似文献   

Tracing exhumation record in high-pressure micaschists: A new tectonometamorphic model of the evolution of the eastern part of the Fore Sudetic Block,Kamieniec Metamorphic Belt,NE Bohemian Massif,SW Poland     

Jacek Szczepański  Marcin Goleń 《Chemie der Erde / Geochemistry》2022,82(1):125859

The Kamieniec Metamorphic Belt comprises a volcano-sedimentary succession exposed within a collision zone between the Saxothuringian and Brunovistulian crustal domains of the European Variscides. The studied rocks recorded two metamorphic episodes. The first episode, M₁, occurred at conditions of c. 485 ± 25 °C and 18 ± 1.8 kbar related to burial within a subduction zone. The subsequent episode, M₂, was linked to the final phases of exhumation to mid-crustal level, associated with pressure and temperature (P–T) conditions ranging from c. 520 ± 26 °C and 6 ± 0.6 kbar through 555 ± 28 °C and 7 kbar ± 0.7 to ~590 ± 30 °C and 3–4 ± 0.4 kbar. The documented deformation record is ascribed to three events, D₁ to D₃, interpreted as related to the burial and subsequent exhumation of the Kamieniec Metamorphic Belt. The D₁ event must have witnessed the subduction of the Kamieniec Metamorphic Belt rock succession whereas the D₂ event was associated with the exhumation and folding of the Kamieniec Metamorphic Belt in an E-W-directed shortening regime. A subsequent folding related to the D₂ event was initiated at HP conditions, however, the planar fabric produced during a late stage of the D₂ event, defined by a low-pressure mineral assemblage M₂, indicates that the D₂ final stage was synchronous with the onset of the M₂ episode. Consequently, the entire D₂ event seems to have been associated with the exhumation of the Kamieniec Metamorphic Belt to mid crustal level. The third deformation event D₃, synchronous with the M₂ episode, marked the last stage of the exhumation, and was linked to emplacement of granitoid veins and lenses. The latter resulted in heating and rheological weakening of the entire rock succession and in the formation of non-coaxial shear zones.  相似文献   

Grampian migmatites in the Buchan Block,NE Scotland   总被引：1，自引：0，他引：1       下载免费PDF全文

T. E. Johnson  C. L. Kirkland  S. M. Reddy  S. Fischer 《Journal of Metamorphic Geology》2015,33(7):695-709

Rocks exposed along the Scottish coast between Fraserburgh and Inzie Head contain information critical to understanding the evolution of the Buchan Block, the type locality for low‐P, high‐T regional metamorphism, and its relationship with the rest of the Grampian terrane, one of the major tectonostratigraphic components of the Scottish Caledonides. The ~8 km long section traverses a regional network of shear zones and, at the highest grades around Inzie Head, passes into the core of the Buchan Anticline, a large‐scale open fold that is commonly regarded as a late structure, post‐dating metamorphism. The metasedimentary rocks increase in grade from upper amphibolite to granulite facies and preserve unequivocal evidence for partial melting. The diatexite migmatites around Inzie Head, along with other gneissose units within the Buchan Block, have been regarded as allochthonous Precambrian basement rocks that were thrust into their current position during the Grampian orogenesis. However, field observations show that the onset of in situ partial melting in metapelitic rocks, which was associated with the formation of garnet‐bearing aplites and associated pegmatites, occurred around Fraserburgh, where shear fabrics are absent. Thus, the rocks preserve a continuous metamorphic field gradient that straddles the shear zone network. This observation supports an alternative interpretation that anatexis was the result of mid‐Ordovician (Grampian) metamorphism, rather than an older tectonothermal event, and that the Inzie Head gneisses are autochthonous. Using an average mid‐Dalradian pelite as a plausible representative protolith, phase equilibria modelling satisfactorily reproduces the observed appearance and disappearance of key minerals providing that peritectic garnet produced with the first formed melts (represented by the garnet‐bearing aplites) depleted the source rocks in Mn. The modelled metamorphic field gradient records a temperature increase of at least 150 °C (from ~650 °C near Fraserburgh to in excess of 800 °C at Inzie Head) but is isobaric at pressures of 2.7–2.8 kbar, suggesting the Buchan Anticline developed synchronous with partial melting. The Buchan Anticline is likely an expression of crustal thinning and asthenospheric upwelling, which produced voluminous gabbroic intrusions that supplied the heat for Buchan metamorphism.  相似文献