Insights into operation of the subduction factory from the oxygen isotopic values of the southern Izu–Bonin–Mariana Arc     

Emi Ito  Robert J. Stern  Chuck Douthitt † 《Island Arc》2003,12(4):383-397

Abstract Oxygen is the most abundant element in the earth, and isotopic analysis of this element in island arc lavas potentially provides sensitive constraints on the proportion of oxygen recycled from subducted material, relative to that extracted from the mantle. Here we report on 225 new oxygen isotopic analyses of whole‐rock and glass samples, and clinopyroxene separates, from lavas collected from the southernmost 1500 km of the Izu–Bonin–Mariana (IBM) convergent margin. Whole‐rock samples clustered around a mean of 6.11 ± 0.47‰, whereas Mariana Trough glasses and mafic melts, calculated to be in equilibrium with mafic phenocrysts, clustered narrowly around a mean of 5.7‰. These data demonstrate that unequivocal identification of magmatic oxygen requires analysis of fresh glass or mafic minerals, and that the source of southern IBM Arc melts is entirely, or almost entirely, in equilibrium with normal mantle oxygen. If the elemental enrichments characteristic of the subduction component originate in subducted materials, these oxygen isotopic data are most consistent with the interaction of a small amount of sediment melt (<4%; mostly less than 1%) with mantle peridotite to yield the hybrid mantle that melts to form IBM Arc magmas.  相似文献   

Petrology of the greenstones of the Lower Sorachi Group in the Sorachi–Yezo Belt, central Hokkaido, Japan, with special reference to discrimination between oceanic plateau basalts and mid-oceanic ridge basalts     

Tohru Nagahashi  Sumio Miyashita 《Island Arc》2002,11(2):122-141

Abstract   The Lower Sorachi Group of the Sorachi–Yezo Belt in central Hokkaido, Japan is a peculiar accretionary complex characterized by numerous occurrences of greenstones (metabasalts and diabases), which are mostly composed of aphyric basalts. Clinopyroxene-rich phenocryst assemblage in phyric basalts is different from olivine–plagioclase assemblage in mid-oceanic ridge basalts (MORB). The greenstones are geochemically uniform, and show a lower-Ti trend than MORB in an FeO*/MgO-TiO₂ diagram, mostly plotting on the island arc tholeiite (IAT) field in a TiO₂−10MnO−10P₂O₅ diagram. In a MORB-normalized spider diagram, the greenstones show a flat pattern from P to Y, which are lower than those of normal mid-oceanic ridge basalt (N-MORB). These indicate that the greenstones were derived by a higher degree of partial melting from a depleted mantle similar to a N-MORB source, and experienced olivine–clinopyroxene fractional crystallization. However, a positive spike of Nb in the spider diagram cannot be explained, and may be attributed to mantle heterogeneity. These characteristics are analogous to those of oceanic plateau basalts (OPB) such as in Ontong Java Plateau, Manihiki Plateau and Nauru Basin, suggesting that the greenstones in the Lower Sorachi Group are of oceanic plateau origin. The present study proposes new field divisions to distinguish OPB from MORB in the conventional FeO*/MgO–TiO₂ and TiO₂−10MnO−10P₂O₅ diagrams.  相似文献   

The mineralogy of the Kokchetav ‘lamproite’: implications for the magma evolution     

Yongfeng Zhu  Yoshihide Ogasawara  T. Ayabe 《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Kokchetav ‘lamproite’ occurs in the east end of Kokchetav massif and consists of phenocryst (mainly clinopyroxene) and matrix (mainly feldspar). The compositions of clinopyroxene, magnetite and biotite phenocryst were determined using wavelength dispersive spectrometry on a JEOL Super-probe 8900 electron microprobe for the purpose of revealing the process of magma evolution. Analyses revealed a core–rim variation, which is consistent with three stages of magmatic evolution: Mg-rich clinopyroxene cores (diopside) and biotite cores (phlogopite) crystallized in a deep magma chamber (stage I); Fe-rich clinopyroxene rim (salite) and biotite rim crystallized at low pressure in a shallow magma chamber (stage II); Magnetite phenocryst core also crystallized in a shallow magma chamber, and co-exists with Fe-rich clinopyroxene rim and biotite rim. The magnetite rims probably formed during magma eruption at the same time when groundmass crystallized (stage III). The calculated temperatures for ilmenite–magnetite pair range from 679 to 887°C, log fO₂ values range from −11.1 to −14.9 log units. These values represent the latest conditions of magma as ilmenite exsolution in magnetite probably occurred during magma eruption from the shallow chamber to surface.  相似文献   

甘肃金川Ⅱ号岩体辉石化学特征及其地质意义   总被引：3，自引：0，他引：3  

陈列锰  宋谢炎  聂晓勇  周国富  刘世荣  郑文勤  李士彬 《矿物岩石》2008,28(1):88-96

金川Ⅱ号岩体主要由二辉橄榄岩和硫化物橄榄岩构成,单斜辉石和斜方辉石为岩相中主要造岩矿物,单斜辉石含量一般高于斜方辉石.矿物间的结构关系表明主要造岩矿物的结晶顺序为:橄榄石-斜方辉石-单斜辉石-斜长石.单斜辉石的TiO2,Al2O3,Cr2O3和Na2O质量分数依次为:0.29%～1.26%、3.17%～3.59%、0.86%～1.14%、0.29%～0.57%,斜方辉石的TiO2,Al2O3,Cr2O3和Na2O质量分数普遍低于单斜辉石,依次为:0.16%～0.40%、1.85%～2.38%、0.48%～0.68%、0.03%～0.10%.元素间的相关关系显示辉石的类质同像置换方式为:M1Fe2 2 Si=M1Ti 2IV Al,M1Fe2 Si=M1Fe3 IVAl,Fe3 和Ti进入矿物晶格置换Fe2 来平衡Al置换Si产生的正电价差.两种辉石较低的TiO2,Al2O3和Na2O质量分数显示出母岩浆为拉斑玄武岩浆的特征.二辉石温度计和单辉石温度计算表明斜方辉石的结晶温度下限和单斜辉石结晶温度上限大致在1146℃～1166℃之间,单斜辉石的结晶一直持续到1032℃或者更低.金川Ⅱ号岩体单斜辉石演化明显表现出向透辉石端员偏离,暗示岩浆在结晶分异过程中,可能与富钙质围岩发生了同化混染作用.  相似文献   

四川木里混杂带海山玄武岩辉石斑晶中的熔体包裹体：甘孜-理塘古特提斯洋内热点与洋中脊相互作用的记录     

周斌  闫全人  邓莉  江文  侯泉林  程南南  赵腾格 《岩石学报》2020,36(3):925-947

川西木里混杂带位于扬子板块西缘,向西与甘孜-理塘弧前混杂带相接,位于一个大地构造上十分重要的部位。我们详细野外地质调查揭示,木里混杂带由不同类型的大洋板片地层组成,其中海山岩石组合保存相对完整,枕状熔岩与上覆碳酸盐岩帽接触关系以及海山斜坡滑塌堆积组合完整清晰。海山枕状玄武岩具斑状结构,主要斑晶矿物相为单斜辉石,少量基性斜长石,基质为微晶斜长石和辉石。原生熔体包裹体主要寄存于单斜辉石斑晶中,形状不规则,大小20～50μm。熔体包裹体内部组成和结构简单清晰,主要为不透明玻璃质,有的熔体包裹体含圆形-椭圆形收缩气泡,个别熔体包裹体壁可见子矿物结晶析出。对单斜辉石斑晶及其中熔体包裹体的地球化学分析结果揭示,木里混杂带中保留了OIB和E-MORB两类海山玄武岩,其原始岩浆源区为石榴子石二辉橄榄岩低程度熔融。其中,OIB型海山玄武岩(样品HS5)是地幔柱轴部岩浆活动的产物,而E-MORB型海山玄武岩(样品HS2)是某种程度的热点(地幔柱)与洋中脊相互作用的产物。磷灰石U-Pb测年结果和古生物化石证据表明,木里混杂带中的海山形成于石炭纪末-二叠纪初(302±11Ma)。这表明甘孜-理塘(松潘-甘孜)古特提斯分支洋在石炭纪末或更早时期就已经发育。在该分支洋盆内发育地幔柱以及地幔柱(热点)与洋中脊的相互作用。  相似文献   

Empirical calibration of the silica–Ca-tschermak's–anorthite (SCAn) geobarometer     

T. C. MCCARTHY  & A. E. PATIÑO DOUCE 《Journal of Metamorphic Geology》1998,16(5):675-686

The pressure-sensitive equilibrium among anorthite, quartz and the Ca-tschermak component in clinopyroxene (CaAl₂SiO₆; CaTs), CaAl₂SiOCpx6+SiOQtz2=CaAl₂Si₂OPl8 (SCAn) ,can be used as a geobarometer in granulites with the proper assemblage, and has been calibrated using mineral composition data from partial melting experiments of natural assemblages and from phase equilibrium experiments on the end-member CMAS system. The experimental data cover the P – T  range 4–32  kbar and 900–1400  °C. Linear least-squares regression analysis of the experimental data resulted in the following empirical expressions for pressure in terms of composition and temperature: P = 5.066 [±0.760]+ 1300 [±800] T  −ln K 276 [±16] · T  [±2.5  kbar]or P = 6.330 [±0.116]−ln K 301 [±9]· T  [±1.0  kbar] ,where K = a PlAn a CpxCaTs  .The first equation incorporates an enthalpy term, but is less accurate than the second equation, in which the enthalpy of reaction is ignored. Application of these expressions to natural and experimental equilibrium mineral assemblages demonstrates that the empirical barometers are applicable over a wide range of pressures (≥4  kbar), temperatures (≥700  °C) and bulk compositions (Mg#≥32.5).  相似文献   

Megacrysts in the Cenozoic basalt of the Tuoyun Basin,Southwest Tianshan   总被引：2，自引：1，他引：2  

L YongJun  LUO ZhaoHua  REN ZhongBao & LIANG Tao State Key Laboratory of Geological Processes  Mineral Resources  China University of Geosciences  Beijing  China 《中国科学D辑(英文版)》2007,50(1):55-66

Abundant megacrysts of clinopyroxene, amphibole, anorthoclase, and phlogopite are found together with deep-seated xenoliths in the Cenozoic basalt of the Tuoyun Basin, Southwest Tianshan. The megacrysts are mainly in the cone sheet formed at the early stage of the volcanic activity. Clinopyrox-ene megacrysts are located in the lower part of the profile, with amphibole and phlogopite megacrysts in the middle part and anorthoclase megacrysts in the upper part. The crystal integrity, absence of de-formation fabric and their relation to the host basalt suggest that they were crystallized from the host magma and quickly transported to the surface. The mineralogical studies imply that the clinopyroxene megacrysts are of Al-augite with higher Al2O3 (>9%). Amphibole megacrysts are kaersutite rich in TiO2 (>4.5%). Sulfide inclusions such as pyrrhotite occur in some clinopyroxene and amphibole megacrysts. Thermodynamic calculations reveal that pyroxene megacrysts formed under the temperature of 1185.85―1199.85℃ and the pressure between 1.53 and 1.64 GPa comparable to the crust-mantle boundary and amphibole megacrysts crystallized under the pressure of around 0.85 GPa, temperature about 1000℃ comparable to the depth of 30 km. Anorthoclase megacrysts crystallized under the pressure between 0.8―1 GPa,temperature about 900℃.The absence of Ti-rich inclusions such as rutile can be considered as an evidence of quick magma ascending. The P-T conditions estimated via py-roxene megacrysts and phenocrysts compose a P-T path with a steep slope. It can be considered as another evidence of quick magma ascending. However, the estimated temperatures for amphibole megacrysts are markedly lower than those for pyroxene megacrysts given the same pressure. It probably shows that the amphiboles have crystallized at the vanguard of magma and under the vola-tile-rich condition. Thus, we can conclude that the Cenozoic basalts are produced in an extensional tectonic setting and the processes governing crystallization and ascending of the megacrysts are very complex.  相似文献   

大陆玄武岩原始水含量的测定及其对源区组分的制约     

夏群科  刘佳  陈欢  刘少辰  冯敏 《岩石矿物学杂志》2015,34(3):371-381

理解大陆板内玄武岩的源区组成和成因是认识地幔动力学过程和化学不均一性的重要途径。由于不同地幔端员具有不同的水含量及水与其它不相容元素的比值(如H2O/Ce),原始水含量的测定对于认识玄武岩的源区组成将会提供新的信息。玄武岩玻璃和斑晶中的熔体包裹体是获得海洋玄武岩原始水含量的主要样品,但是不适合于大陆玄武岩,因为大陆玄武岩玻璃由于强烈的去气作用不能反映真实水含量,而大陆玄武岩斑晶中的熔体包裹体少而小,不易获得足量、准确的数据。本文介绍一种最近发展起来的推断大陆玄武岩原始水含量的方法,即利用红外光谱测定玄武岩中单斜辉石斑晶的水含量,然后结合水在单斜辉石与玄武质熔体中的分配系数来反演与斑晶平衡的熔体水含量,进而估计原始玄武质岩浆的水含量。文中详细叙述了方法的适用性、误差的估计以及具体的操作流程,并通过东北双辽和华北太行山新生代玄武岩的研究实例,展示了玄武岩水含量对于源区组成的有力制约。  相似文献   

滇西剑川苦橄玢岩中单斜辉石的矿物学特征及其地质意义   总被引：1，自引：0，他引：1       下载免费PDF全文

寇彩化  张招崇  廖宝丽  李宏博  侯通 《岩石矿物学杂志》2011,30(3):449-462

利用电子探针对滇西剑川的二龙和满元两个地区苦橄玢岩和苦橄质堆晶岩中的单斜辉石进行了详细的矿物学研究,结果表明绝大多数单斜辉石属于普通辉石,具有贫硅、贫碱、高钙和低氧逸度的特征。在单斜辉石形成过程中,阳离子间普遍发生类质同像替代。单斜辉石温压计算结果显示,二龙和满元苦橄玢岩的形成温度(1 324~1 428℃)和压力(1.5~2.9 GPa)明显低于满元苦橄质堆晶岩的温度(1 439~1 462℃)和压力(3.0~3.2 GPa),二龙和满元苦橄玢岩的形成深度也比满元苦橄质堆晶岩的深度(99~106 km)浅,整体看来,剑川苦橄玢岩形成的温度和压力较高,来源较深,可能是软流圈沿断裂带上涌导致上地幔部分熔融的结果,也可能是地幔柱活动所导致。  相似文献   

长江中下游地区蝌蚪山早白垩世玄武岩中单斜辉石的矿物学研究及其地质意义     

文施华  侯通 《矿物岩石》2011,31(3)

长江中下游地区繁昌火山盆地在早白垩世先后发育3个喷发旋回:中分村旋回、赤沙旋回和蝌蚪山旋回。其中蝌蚪山旋回下段以凝灰质粉砂岩为主,中段为玄武岩和流纹质凝灰岩互层,上段以流纹岩为主。蝌蚪山玄武岩中的辉石既存在斑晶中也存在于基质中,这两种辉石在成分上有明显的差异,从斑晶辉石的核部到边部再到基质的核部,化学成分由富镁向富铁演化,显示出拉斑玄武岩系列的特点,辉石成因的判别图解表明其寄主岩浆为板内拉斑玄武岩,但其化学成分的变化趋势又表明岩浆在结晶分异的过程中向着碱性系列演化。根据单斜辉石与熔体平衡原理计算出玄武岩形成时的温度约为1 100℃,压力约为400MPa,相应的深度约为15km,证明岩浆在地壳中有过短暂的停留,并在上地壳部位发生分离结晶作用后喷出地表快速冷凝形成蝌蚪山玄武岩。  相似文献